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    • 66. 发明专利
    • PRODUCTION OF IMPROVED ACRYL TYPE RUSHLIKE FABRIC
    • JPS5655435A
    • 1981-05-16
    • JP13200579
    • 1979-10-13
    • SUMITOMO CHEMICAL CO
    • KOBASHI TOSHIYUKIOZAKI MASAHIKOSHIODA HIROTAKA
    • C08F2/00C08F2/10C08F2/44C08F20/44C08J9/12
    • PURPOSE:To obtain titled fabric which bears a closer resemblance to natural rushes, by adding an inorganic salt to a polymer composition obtained by polymerizing acrylonitrile at a high temperature and an elevated pressure in the presence of water with the aid of an organic radical initiator and foam-melt-extruding the resulting mixture. CONSTITUTION:The rushlike fabric is obtained by adding (D) 0.5-5%, based on the weight of acryl type polymer, of an inorganic salt such as KNO3, having a solubility in water at 100 deg.C (g/100g solution), of at least 35 to a molten acryl type polymer composition obtained by charging a reaction vessel with (A) 97-50wt% of acrylonitrile or a mixture thereof with other ethylenically unsaturated compounds, (B) 3-50wt% of water and (C) an organic radical initiator, and polymerizing the reaction mixture at an autogenous pressure or higher and at a temperature of 80 deg.C or higher, then foam-melt-extruding the composition through a nozzle to a low- pressure zone and stretching the extrudate. EFFECT:It is possible to carry out with good stability for a long time, the production of a synthetic rush in a form of foam having a smooth surface and bearing a closer resemblance to natural rushes.