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    • 63. 发明专利
    • Copolymer containing fluorine and its preparation
    • 含有共聚物的氟化物及其制备方法
    • JPS57117512A
    • 1982-07-22
    • JP351281
    • 1981-01-13
    • Japan Atom Energy Res Inst
    • WATANABE MITSUTAKAMATSUDA OSAMUISHIGAKI ISAOTABATA YONEHOOKAMOTO JIROU
    • C08F16/00C08F16/08C08F18/00C08F18/18C08F20/00C08F20/22C08F30/00C08F30/02C08F216/02C08F218/16C08F220/22C08F228/04C08F230/02
    • PURPOSE: To obtain a polymer containing fluorine, and having improved heat and chemical resistance, by mixing a trifluoroacrylic acid (TFA) or an ester thereof with a specific allylic compound, and copolymerizing the resultant mixture by irradiation with gamma rays.
      CONSTITUTION: 5W95mol% trifluoroacrylic acid (TFA) expressed by formulaI (n is an integer 0W2), e.g. trifluoroacrylic acid or methyl trifluoroacrylate, is mixed with 95W5mol% allylic compound, e.g. allyl alcohol or allyl formate, having 1W3 groups expressed by formula II, and the resultant mixture is then disoxidized and copolymerized in the presence of a polymerization initiating source, preferably irradiation with gamma rays, preferably at -5W+150°C to precipitate and separate the aimed copolymer containing fluorine.
      USE: Useful as an ion exchanger base material.
      COPYRIGHT: (C)1982,JPO&Japio
    • 目的:通过将三氟丙烯酸(TFA)或其酯与特定的烯丙基化合物混合,并通过用γ射线照射使所得混合物共聚,从而获得含氟的聚合物并具有改善的耐热和耐化学性。 构成:由式I表示的5-95mol%三氟丙烯酸(TFA)(n为整数0-2),例如 三氟丙烯酸或三氟丙烯酸甲酯与95-5mol%的烯丙基化合物,例如 烯丙醇或甲酸烯丙酯,其具有1-3个由式II表示的基团,然后将所得混合物在聚合引发源存在下进行脱氧和共聚,优选用γ射线照射,优选在-5 + 150℃ 以沉淀并分离含有氟的目标共聚物。 用途:用作离子交换器基材。