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    • 69. 发明专利
    • Method for forming metal oxide particulate layer onto electrically conductive base material
    • 将金属氧化物颗粒层形成电导体基材的方法
    • JP2007332451A
    • 2007-12-27
    • JP2006169258
    • 2006-06-19
    • Catalysts & Chem Ind Co Ltd触媒化成工業株式会社
    • KINO KATSUHIROMIZUNO TAKAYOSHIKOYANAGI TSUGUO
    • C25D15/00
    • C25D13/02
    • PROBLEM TO BE SOLVED: To provide a method for extremely easily forming a uniform metal oxide particulate layer having excellent adhesion, wear resistance, strength or the like compared with the conventional plating method, CVD method, coating liquid method, electrodeposition method or the like.
      SOLUTION: Regarding the method for forming a metal oxide particulate layer onto an electrically conductive base material, an electrically conductive base material is immersed into a dispersion liquid of metal oxide particulates and fibrous particulates, and DC voltage is applied to the electrically conductive base material and the dispersion liquid. In the fibrous particulates, the length (L) lies in the range of 50 nm to 10 μm; the diameter (D) lies in the range of 10 nm to 2 μm, and the aspect ratio (L)/(D) lies in the range of 5 to 1,000. The content of the fibrous particulates in the dispersion liquid lies in the range of 0.1 to 20 wt.% of the metal oxide particulates as a solid component. The dispersion liquid further comprises colloidal particles in which the average particle diameter lies in the range of 2 to 300 nm.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题提供一种与常规电镀方法,CVD法,涂布液法,电沉积法或电沉积法相比,极易形成均匀金属氧化物颗粒层的方法,其具有优异的粘附性,耐磨性,强度等 类似。 解决方案:关于在导电基材上形成金属氧化物颗粒层的方法,将导电基材浸入金属氧化物颗粒和纤维颗粒的分散液中,并将直流电压施加到导电 基材和分散液。 在纤维状颗粒中,长度(L)在50nm至10μm的范围内; 直径(D)在10nm〜2μm的范围内,纵横比(L)/(D)在5〜1000的范围内。 分散液中的纤维状微粒的含量在作为固体成分的金属氧化物微粒的0.1〜20重量%的范围内。 分散液还含有平均粒径在2〜300nm范围内的胶体粒子。 版权所有(C)2008,JPO&INPIT
    • 70. 发明专利
    • Honeycomb catalyst for carbon monoxide methanation, manufacturing method of the catalyst, and methanation method of carbon monoxide using the catalyst
    • 用于一氧化碳甲烷的蜂窝状催化剂,催化剂的制造方法和使用催化剂的一氧化碳的甲烷化方法
    • JP2007252991A
    • 2007-10-04
    • JP2006077604
    • 2006-03-20
    • Catalysts & Chem Ind Co Ltd触媒化成工業株式会社
    • MIZUNO TAKAYOSHIKINO KATSUHIROKOYANAGI TSUGUO
    • B01J23/89B01J37/02C10K3/04H01M8/06H01M8/10
    • Y02E60/521
    • PROBLEM TO BE SOLVED: To provide a honeycomb catalyst capable of stably and highly efficiently removing carbon monoxide in a hydrogen-containing gas, and to provide the manufacturing method of the honeycomb catalyst. SOLUTION: The honeycomb catalyst for carbon monoxide methanation is characterized in that a catalyst layer is formed on the surface of a honeycomb base material made of metal or ceramic and comprises a metal and a metal oxide. The metal oxide is at least one kind of oxide or multiple oxide selected from ZrO 2 , CeO 2 , NiO, CoO, Co 3 O 4 , Al 2 O 3 , TiO 2 and SiO 2 , and the metal is at least one kind of metal selected from 4B group, 6A group, 7A group and 8 group. The invention is related to the honeycomb catalyst for carbon monoxide methanation in a hydrogen-containing gas, the manufacturing method of the catalyst and the methanation method of carbon monoxide using the catalyst. COPYRIGHT: (C)2008,JPO&INPIT
    • 解决的问题:提供一种能够稳定高效地除去含氢气体中的一氧化碳的蜂窝体催化剂,提供蜂窝状催化剂的制造方法。 解决方案:用于一氧化碳甲烷化的蜂窝体催化剂的特征在于,在由金属或陶瓷制成的蜂窝基材的表面上形成催化剂层,并且包含金属和金属氧化物。 金属氧化物是选自ZrO 2,SBO 2,SBO 2,NiO,CoO,Co 3 S 3 O 3中的至少一种氧化物或多种氧化物, SB> 4 ,Al 2 3 ,TiO 2 和SiO 2 是选自4B组,6A组,7A组和8组中的至少一种金属。 本发明涉及含氢气体中的一氧化碳甲烷化用蜂窝催化剂,催化剂的制造方法和使用该催化剂的一氧化碳的甲烷化法。 版权所有(C)2008,JPO&INPIT