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    • 52. 发明专利
    • PRODUCTION OF TIN-FREE STEEL FOR RETORT CAN
    • JPS61264195A
    • 1986-11-22
    • JP10467385
    • 1985-05-16
    • KAWASAKI STEEL CO
    • KATO HISAKATSUYOKOYAMA TOSHIOKOKADO FUMIO
    • C25D11/38C25D9/10C25D11/18
    • PURPOSE:To produce a tin-free steel having excellent retort treatment resistance by subjecting a steel sheet to a cathodic treatment in an electrode for reverse electrolysis, Cr plating treatment, reverse electrolytic treatment and electrolytic Cr acid treatment. CONSTITUTION:The steel sheet as a cathode is subjected to the cathodic treatment at 7A/dm current density in an aq. Cr acid soln. in the electrode for the reverse electrolytic treatment. The cold rolled steel sheet is successively immersed for 10sec in a 5% NaOH soln. at 70 deg.C and 8A/dm current density and is then washed. Such steel sheet is subjected to the cathodic treatment for 1.2sec in a plating soln. contg. CrO3 and H2SO4 at 80A/dm and further the steel sheet as an anode is subjected to the reverse electrolytic treatment for 0.2sed at 3.5A/dm and is then immersed in a plating soln. contg. CrO3 and is electrolytically treated with the Cr acid by the cathodic treatment at 10 Coulomb/dm quantity of electricity. The steel sheet is cathodically treated for the cathodic treatment and is used as the electrode for the reverse electrolysis for the anodic treatment in the electrode for the reverse electrolysis for the cathodic treatment, by which the uniform Cr oxide film is formed and the tin-free steel having the stable quality is produced.