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    • 49. 发明专利
    • PRODUCTION OF POLYMER DISPERSION
    • JPH107722A
    • 1998-01-13
    • JP16749496
    • 1996-06-27
    • HYMO CORP
    • MIYAJIMA TORU
    • C08J3/03C08F6/06C08F6/12C08F8/12C08F26/00C08F220/42C08F220/48C08F226/02C08J3/075
    • PROBLEM TO BE SOLVED: To obtain a polymer dispersion useful for sludge coagulation by dissolving a product of acid hydrolysis of an N-vinylformamide/acrylonitrile copolymer in an aqueous sodium nitrate solution at high temperature and cooling the resulting solution under agitation to deposit microparticles. SOLUTION: A solution prepared by dissolving a product of acid hydrolysis of an N-vinylformamide/acrylonitrile copolymer in an aqueous sodium nitrate solution at temperature of as high as about 70 deg.C is cooled under agitation to a temperature of below about 30 deg.C to make a polymer dispersion containing the copolymer deposited in the form of microparticles. The sodium nitrate concentration of the aqueous sodium nitrate solution is in the range of 15-45wt.%. The stability of this dispersion can be improved by adding 0.1-1wt.%, based on the dispersion, sulfate thereto. It is desirable that the coagulation of this dispersion is prevented by adding 0.05-1wt.%, based on the dispersion, nonionic surfactant and 2-10wt.%, based on the dispersion, oily liquid (e.g. kerosene) thereto. This dispersion can be conveniently used and is useful in the coagulation of sewage sludge and as a dehydrating agent of a dehydrator.