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41. 发明专利

JPH03215849A SILVER HALIDE COLOR PHOTOGRAPHIC SENSITIVE MATERIAL 失效
公开(公告)号：JPH03215849A
公开(公告)日：1991-09-20
申请号：JP1096490
申请日：1990-01-19
申请人： KONISHIROKU PHOTO IND
发明人： KIMURA TOSHIHIKO , SHIMAZAKI HIROSHI , SHINBA SATORU , YAMADA YOSHITAKA
IPC分类号： G03C7/20 , G03C1/06 , G03C7/305
摘要： PURPOSE:To improve red color reproducibility and particularly the red color reproducibility in the graded part of leg parts by setting the sensitivity of the DIR photosensitive layer contg. a compd. (DIR compd.) which releases a development restrainer and the spectral sensitivity distribution thereof to specific values. CONSTITUTION:The DIR photosensitive layer of the silver halide color photographic sensitive material has the sensitivity equal to or higher than the sensitivity of the red sensitive silver halide emulsion layer and the max. of the spectral sensitivity distribution of the DIR photosensitive layer is set the same as the max. of the red sensitive silver halide emulsion layer or longer than the same. Various means of forming the silver halide of the DIR photosensitive layer to the particles larger than the particles of the silver halide of the red sensitive silver halide emulsion layer, increasing the degree of chemical maturation, increasing the color sensitivity, etc., may be used in order to make the sensitivity of the DIR photosensitive layer equal to or higher than the sensitivity of the red sensitive silver halide emulsion layer. Means for replacing a part or the whole of the sensitizing dyes used for the red sensitive silver halide emulsion with the sensitizing dyes of the longer waves, etc., are usable for forming the DIR layer to the spectral sensitivity distribution longer in wave than the spectral sensitivity distribution of the red sensitive silver halide emulsion layer.

42. 发明专利

JPH02113243A SILVER HALIDE COLOR PHOTOGRAPHIC SENSITIVE MATERIAL 失效
公开(公告)号：JPH02113243A
公开(公告)日：1990-04-25
申请号：JP26686588
申请日：1988-10-21
申请人： KONISHIROKU PHOTO IND
发明人： IRIE KOJI , SHIMAZAKI HIROSHI
IPC分类号： G03C7/305 , G03C7/32
摘要： PURPOSE:To obtain the photosensitive material which is improved in sharpness and color reproducibility by constituting at least one of photographic constituting layers including blue-, green- and red-sensitive emulsion layers of a single layer and incorporating specific couplers into at least one layer of the photographic constituting layers. CONSTITUTION:This photosensitive material has the photographic constituting layers contg. the blue-, green- and red-sensitive emulsion layer on a base and at least one of the respective layers consist of the single layer. At least one kind of the couplers which are the couplers bonded directly or via timing group to the active position of the reaction of the dyes or the precursors thereof released by reacting with the oxidant of an arom. primary amine color developing agent and are shifted in the absorption max. wavelength of the dyes formed from the released dyes or the precursors thereof to the short wavelength side before release are incorporated into at least one layer of the photographic constituting layers. The photosensitive material which is improved in the sharpness and is improved in the color reproducibility as well is obtd. in such a manner.

43. 发明专利

JPH02106739A SILVER HALIDE COLOR PHOTOGRAPHIC SENSITIVE MATERIAL WITH IMPROVED GRAININESS 失效
公开(公告)号：JPH02106739A
公开(公告)日：1990-04-18
申请号：JP25999288
申请日：1988-10-15
申请人： KONISHIROKU PHOTO IND
发明人： SHIMAZAKI HIROSHI , SHINBA SATORU , ISHII FUMIO
IPC分类号： G03C1/035 , G03C7/26 , G03C7/30
摘要： PURPOSE:To obtain the subject material with improved graininess by incorporating a monodisperse silver halide emulsion having a specified mean particle size in each of color sensitive layers which exist at a position most far from a substrate respectively, and specifying the mean iodine content of the silver halide emulsion to a prescribed amount. CONSTITUTION:The silver halide emulsion (A) having

44. 发明专利

JPH0219843A SILVER HALIDE COLOR PHOTOGRAPHIC SENSITIVE MATERIAL 失效
公开(公告)号：JPH0219843A
公开(公告)日：1990-01-23
申请号：JP17012888
申请日：1988-07-07
申请人： KONISHIROKU PHOTO IND
发明人： YOSHIMOTO HIROSHI , NAKAGAWA SATOSHI , SHIMAZAKI HIROSHI
IPC分类号： G03C7/305 , G03C7/34
摘要： PURPOSE:To improve the sharpness of the title material, and to obtain a cyan pigment picture having high optical density even at the time of processing the photosensitive material with a fatigued bleaching solution by incorporating at least one kind of coupler in which the max. absorption wavelength of the released pigment, etc., shifts to a short wavelength side before being released the pigment, and a specified coupler in the photosensitive material, respectively. CONSTITUTION:At least one kind of the coupler in which the max. absorption wavelength of the released pigment or the pigment formed from the precursor of said pigment shifts to the short wavelength side before being released the pigment, and at least one kind of the coupler shown by formula I are incorporated in the photosensitive material. In formula I, R is -CONR R or -NHOR , etc., R and R are each hydrogen atom or a substituting group, X is hydrogen atom or a group capable of being released by allowing it to react with the oxidant of an aromatic primary amine developing agent, (l) is 0 or 1, (m) is 0-3, R and R are each hydrogen atom or an aliphatic group. Thus, the sharpness of the photosensitive material at a high and a low frequency sides is improved, and the stable optical density of the cyan pigment picture is obtd., even at the time of processing the photosensitive material with the exhaused bleaching solution.

45. 发明专利

JPH0219842A SILVER HALIDE COLOR PHOTOGRAPHIC SENSITIVE MATERIAL 失效
公开(公告)号：JPH0219842A
公开(公告)日：1990-01-23
申请号：JP17012788
申请日：1988-07-07
申请人： KONISHIROKU PHOTO IND
发明人： HAGA YOSHIHIRO , SHIMAZAKI HIROSHI , EZAKI ATSUO , SHIGETOMI YOSHIRO
IPC分类号： G03C7/20 , G03C1/76 , G03C1/95 , G03C7/30 , G03C7/333 , G03C7/34 , G03C7/38
摘要： PURPOSE:To improve the anti-sticking property and the picture quality of the title material by specifying the total amount of coated silver of the photosensi tive material, and mounting at least one layer of red, green, and blue photosensi tive layers on a supporting body, respectively, and incorporating an alkali sol uble mat agent in the uppermost layer of the photosensitive material. CONSTITUTION:The total amount of the coated silver of the photosensitive material is specified to 15-45mg/dm , and at least one layer of the red, the green and the blue photosensitive layers is mounted on the supporting body respectively. And, a masking cyan coupler is incorporated in at least one layer of the red photosensitive layers, and a masking magenta coupler is incorporated in at least one layer of the green photosensitive layers and the alkali-soluble mat agent is incorporated in the uppermost layer of the photosensitive material. And, the layers which does not sensitize substantially, may be interposed among each of the photosensitive layers respectively. Thus, the deterioration of the picture quantity is lessened, in spite of the less amount of the coated silver, and the anti-sticking property of a film is improved.

46. 发明专利

JPH0218551A SILVER HALIDE PHOTOGRAPHIC SENSITIVE MATERIAL HAVING IMPROVED SHARPNESS 失效
公开(公告)号：JPH0218551A
公开(公告)日：1990-01-22
申请号：JP16813088
申请日：1988-07-06
申请人： KONISHIROKU PHOTO IND
发明人： FUKAZAWA FUMIYOSHI , NAKAGAWA SATOSHI , SHIMAZAKI HIROSHI , YAGI TOSHIHIKO
IPC分类号： G03C7/305 , G03C1/015 , G03C1/07 , G03C7/26 , G03C7/30
摘要： PURPOSE:To improve the sharpness in the entire frequency region of the photosensitive material by using a specific silver halide emulsion and shift coupler in combination. CONSTITUTION:The planar silver halide particles which are monodisperse and of which 50% of the total projection area has >=3 average value of the grain size/particle thickness are incorporated into >=1 layers of the silver halide emulsion layers of the title photosensitive material. The coupler which is shifted in the absorption max. wavelength of the dye released and formed by reaction with the oxidant of an arom. primary amine color developing agent to a short wavelength side prior to releasing is incorporated into >=1 layers of the emulsion layers. The compd. expressed by formula I, etc., are usable as the above- mentioned dye and the compd. expressed by formula II is usable for the above- mentioned shift coupler. In formulas, X' denotes O, S; W denotes a substituent; (q) denotes 0-2; (s) denotes 0-3; B1-B4 denotes H, substituent.

47. 发明专利

JPH01237544A PROCESSING METHOD OF SILVER HALIDE COLOR PHOTOGRAPHIC SENSITIVE MATERIAL 失效
公开(公告)号：JPH01237544A
公开(公告)日：1989-09-22
申请号：JP6417188
申请日：1988-03-17
申请人： KONISHIROKU PHOTO IND
发明人： FUKAZAWA FUMIYOSHI , SHIMAZAKI HIROSHI
IPC分类号： G03C7/42 , G03C1/06 , G03C7/392
摘要： PURPOSE:To shorten a processing stage and to improve a desilvering property by confining the total processing time of a bleach processing stage and the processing stage having fixability to within 3min and 45sec and incorporating specific compds. into the photosensitive material. CONSTITUTION:The total processing time of the bleaching stage and the processing stage having the fixability in the processing method of the photosensi tive material is fined within 3min and 45sec and at least one kind the compds. expressed by formula I are incorporated into the photosensitive material. In formula I, Z2 denotes the atom. group necessary for forming the heterocycle having directly or indirectly at least one of the groups selected from -SO3M1, -COOR2, -CONHR4, -OH, and -NHR3; M and M1 denote a hydrogen atom, alkali metal or -NH4 group; R2 denotes a hydrogen atom, alkali metal or alkyl group of 1-6C; R3 denotes a hydrogen atom, alkyl group of 1-6C, -COR4, -COOR4 or -SO2R4; R4 denotes a hydrogen atom, aliphat. group or arom. group. The rapid processing is thereby enabled and the desilvering property is improved.

48. 发明专利

JPH01191847A SILVER HALIDE COLOR PHOTOGRAPHIC SENSITIVE MATERIAL HAVING EXCELLENT PROCESSING STABILITY 失效
公开(公告)号：JPH01191847A
公开(公告)日：1989-08-01
申请号：JP1760688
申请日：1988-01-28
申请人： KONISHIROKU PHOTO IND
发明人： FUKAZAWA FUMIYOSHI , SHIMAZAKI HIROSHI
IPC分类号： G03C1/04 , G03C1/34 , G03C7/396
摘要： PURPOSE:To impart excellent developability and high density to a silver halide color photographic sensitive material and to decrease an increase of fogging by rapid processing by incorporating argyrophil polymer having >=100,000 weight average mol. weight and the repeating structural unit expressed by general formula into said material and further, incorporating a polymer having =100,000 weight average mol. weight and the repeating structural unit expressed by general formula I are incorporated into the silver halide color photographic sensitive material. Further, the polymer having denotes a hydrogen atom or alkyl group; Z denotes an atom group necessary for forming a lactam ring, oxazolidone ring or pyrrolidone ring with an N atom and C atom. A denotes a mere combination means, -CO-, -COO(CH2)n- or -CONR (CH)n; R denotes a hydrogen atom or alkyl group; (n) denotes integer in the range of 1-6.

49. 发明专利

JPH0120417B2 失效
公开(公告)号：JPH0120417B2
公开(公告)日：1989-04-17
申请号：JP13729383
申请日：1983-07-26
申请人： KONISHIROKU PHOTO IND
发明人： IKEUCHI SATORU , INABA YOSHIHIRO , SHIMAZAKI HIROSHI , KOBAYASHI TATSUHIKO
IPC分类号： C08F12/00 , C08F12/26 , C08F20/00 , C08F20/34 , C08F20/52 , C08F20/60 , G03C7/00 , G03C8/56

50. 发明专利

JPS63142352A SILVER HALIDE COLOR PHOTOGRAPHIC SENSITIVE MATERIAL ENSURING IMPROVED GRAININESS AND SHARPNESS 失效
公开(公告)号：JPS63142352A
公开(公告)日：1988-06-14
申请号：JP28964386
申请日：1986-12-04
申请人： KONISHIROKU PHOTO IND
发明人： IWAMURO MASAO , SHIMAZAKI HIROSHI , SAKAMOTO HIDEKAZU
IPC分类号： G03C7/26 , G03C7/392
摘要： PURPOSE:To improve the graininess and sharpness of an image by incorporating a diffusible DIR compd. and a specified compd. into a silver halide emulsion layer other than a silver halide emulsion layer having the maximum sensitivity. CONSTITUTION:A diffusible DIR compd. is incorporated into a silver halide emulsion layer other than a silver halide emulsion layer having the maximum sensitivity and a compd. represented by formula I is further incorporated into the emulsion layer by 20-150mg per 1mol silver halide in the emulsion layer. In the formula I, Z is a group of atoms required to form a 5- or 6-membered hetero ring consisting of C and N, O, S or Se, e.g., hetero ring compd. is pyridine, pyrimidine, imidazole, benzimidazole or naphthimidazole, e.g., and the hetero ring may be a condensed hetero ring and M is H, an alkali metal atom or ammonium. A silver halide color photographic sensitive material ensuring superior graininess and sharpness is obtd.

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