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    • 45. 发明专利
    • METHOD FOR MANUFACTURING SUPER HIGH-PURITY OXYGEN AND NITROGEN
    • JPH09184681A
    • 1997-07-15
    • JP12469396
    • 1996-05-20
    • TEISAN KK
    • YAMAMOTO TAKAOTOMITA SHINJIDEN AKIRA
    • F25J3/04
    • PROBLEM TO BE SOLVED: To provide a device capable of performing a concurrent manufacturing of liquid nitrogen of super-high purity and liquid oxygen of super-high purity. SOLUTION: An inner side of a first refining tower 6 is divided into an upper refining section 12, an intermediate refining section 13 and a lower refining section 14. To the upper section of the upper refining section is connected a nitrogen condenser 8. A second refining tower 7 is provided with a re-boiler 24 at the lower part of the refining section 22. Liquid nitrogen of super-high purity is recovered from between the upper refining section 12 of the first refining tower 6 and the intermediate refining section 13. Liquid air not containing substance of high boiling point recovered from between the intermediate refining section 13 and the lower refining section 14 is reduced in its pressure by an expansion valve 32, thereafter the air is supplied to the upper section of the refining section 22 of the second refining tower 7, contacted in a counter-flow state with gas gasified by a reboiler 24 arranged at a lower part of the refining section so as to separate the substance of low boiling point and then liquid oxygen of super-high purity is recovered from the lower part of the refining section 22 of the second refining tower 7.
    • 46. 发明专利
    • METHOD AND APPARATUS FOR PRODUCING ULTRAHIGH-PURITY NITROGEN
    • JPH0933166A
    • 1997-02-07
    • JP18593395
    • 1995-07-21
    • TEISAN KK
    • NAGAMURA TAKASHIYAMAMOTO TAKAOTOMITA SHINJI
    • B01D53/04B01D53/86F25J3/04F25J3/08
    • PROBLEM TO BE SOLVED: To produce ultrahigh-purity nitrogen at a high yield. SOLUTION: Carbon dioxide, water, and catalyst poison of an oxidation catalyst in the air fed as raw material are removed by a decarbonization-desiccation device 4 and the resulting air is led into a low-pressure rectifying column 6 where carbon dioxide, water, and catalyst poison are removed further from the air by crude rectification. Next the crude nitrogen gas obtained at the lowpressure rectifying column 6 is led into an oxidation tower 8 where carbon monoxide in the crude nitrogen gas is turned into carbon dioxide and, after turning hydrogen into water, the crude nitrogen gas is led into an adsorption tower 10 where carbon dioxide and water are removed therefrom by adsorption and a crude nitrogen gas is obtained as raw material. This crude nitrogen gas as raw material is further led into a medium-pressure rectifying column 11 for rectification. Nitrogen gas obtainable from the top part of the medium-pressure rectifying column is condensed by a reboil condenser 6RC into a high-purity liquid nitrogen, then returned to the medium-pressure rectifying column 11, and part of the high-purity liquid nitrogen is made to flow as a refluxed liquid and the rest of it is drawn as an end product which is ultrahigh-purity nitrogen gas or ultrahigh-purity liquid nitrogen from a rectification stage positioned several stages below the top rectification stage of the medium-pressure rectifying column.
    • 47. 发明专利
    • METHOD AND APPARATUS FOR QUICK FREEZING BY USE OF LIQUID NITROGEN
    • JPH08296938A
    • 1996-11-12
    • JP12561395
    • 1995-04-27
    • TEISAN KK
    • OGURO TAKASHI
    • F25D3/10
    • PURPOSE: To enable easy change of the degree of cooling by providing a cooling device for maintaining an interior of a container for containing goods to be frozen at a slightly low temperature and a liquid nitrogen type quick freezing means capable of lowering temperature in the interior of the container to temperatures within the range of cryogenic temperatures. CONSTITUTION: In a freezing operation, first an interior of a container l is cooled to a weak low temperature e.g. around -40 deg.C by a chlorofluoro carbon refrigerating device 5 and the container is charged with packs 3 of goods to be frozen such as chocolate and the like. Then, chlorofluoro carbon gas in an evaporator 6 is collected by a built-in pump in the chlorofluoro carbon cooling device 5. Drops of liquid nitrogen are made to fall from a liquid nitrogen source 4 through a pipe 7 toward an agitating fan 2 in the container so as to be evaporated in the container 1 and the interior of the container 1 is cooled to a cryogenic temperature of e.g. -80 deg.--100 deg.C and the state is maintained for a period of time, e.g. 10 minutes. After that, introduction of the liquid nitrogen is stopped, the nitrogen gas within the container 1 is discharged through an exhaust pipe 8 and the chlorofluoro carbon cooling device 5 is operated again to maintain temperature in the container 1 at a specified temperature.