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    • 31. 发明专利
    • Thermosetting resin composition for forming protective film, protective film, and method for forming protective film
    • 用于形成保护膜的热固性树脂组合物,保护膜和形成保护膜的方法
    • JP2010222503A
    • 2010-10-07
    • JP2009072951
    • 2009-03-24
    • Jsr CorpJsr株式会社
    • UEDA JIROMAKIUCHI NAOMASAITO YUKIKO
    • C09D157/10C09D4/02C09D7/12C09D163/00G02B5/20G02F1/1333
    • PROBLEM TO BE SOLVED: To provide a thermosetting resin composition capable of forming a protective film for a crystal display device on a substrate, the protective film having a high flatness, and moreover good adhesiveness, transparency, surface hardness and the like. SOLUTION: The thermosetting resin composition to form a protective film for a crystal display device comprises [A] a copolymer prepared by copolymerizing monomers containing (a1) an epoxy group-containing unsaturated compound and (a2) a radically polymerizable unsaturated compound, and [B] at least one selected from the group consisting of ethylene oxide- or propylene oxide-modified multifunctional (meth)acrylate compounds. The (a2) component is preferably selected from the group consisting of unsaturated carboxyl acids and unsaturated polycarboxylic anhydrides, and further preferably contains a polymerizable unsaturated compound having a structure of an acetal ester of a carboxylic acid, a structure of a 1-alkylcycloalkyl ester of a carboxylic acid, or the like in the molecule. COPYRIGHT: (C)2011,JPO&INPIT
    • 解决问题:为了提供能够在基板上形成用于晶体显示装置的保护膜的热固性树脂组合物,该保护膜具有高的平整度,并且还具有良好的粘合性,透明度,表面硬度等。 形成用于晶体显示装置的保护膜的热固性树脂组合物包括:[A]通过共聚含有(a1)含环氧基的不饱和化合物和(a2)可自由基聚合的不饱和化合物的单体制备的共聚物, 和[B]选自环氧乙烷或环氧丙烷改性的多官能(甲基)丙烯酸酯化合物中的至少一种。 (a2)成分优选选自不饱和羧酸和不饱和多羧酸酐,进一步优选含有具有羧酸缩醛的结构的可聚合不饱和化合物,1-烷基环烷基酯的结构 分子中的羧酸等。 版权所有(C)2011,JPO&INPIT
    • 34. 发明专利
    • Water-based coating composition for can
    • 用于CAN的水基涂料组合物
    • JP2008038101A
    • 2008-02-21
    • JP2006217606
    • 2006-08-10
    • Kansai Paint Co Ltd関西ペイント株式会社
    • HIDAKA TAKAHIROYOKOI HIDEOTAMURA KOICHI
    • C09D157/10C09D5/02C09D7/12
    • PROBLEM TO BE SOLVED: To provide a water-based coating composition for a can, having excellent finishability because of good wettability on a wet ink, having water resistance resisting to retort treatment, being hardly scratched in a transportation process of the can because of a high-hardness coated film, and providing a coated film having excellent slipperiness at processing.
      SOLUTION: The water-based coating composition for the can contains (A) a carboxy group-containing vinyl copolymer resin, (B) a crosslinking agent comprising at least one kind selected from a melamine resin and a benzoguanamine resin, and an oxazoline group-containing compound, (C) a silicone-based additive and (D) a wax, wherein the contents of the specific silicone-based additive (C) and the wax (D) are 0.1-10 pts.mass and 0.01-10 pts.mass respectively based on 100 pts.mass of the total of the solid components of the carboxy group-containing vinyl copolymer resin (A) and the crosslinking agent (B).
      COPYRIGHT: (C)2008,JPO&INPIT
    • 要解决的问题:为了提供一种罐用水性涂料组合物,由于在湿油墨上具有良好的润湿性,具有耐水蒸气处理的耐水性,在罐的运输过程中难以划伤,具有优异的整理性 因为具有高硬度的涂膜,并且提供了在加工时具有优异的滑爽性的涂膜。 解决方案:罐用水性涂料组合物含有(A)含羧基的乙烯基共聚物树脂,(B)包含选自三聚氰胺树脂和苯并胍胺树脂中的至少一种的交联剂,和 含有恶唑啉基的化合物,(C)硅氧烷类添加剂和(D)蜡,其中特定的硅氧烷类添加剂(C)和蜡(D)的含量为0.1-10质量% 基于含羧基的乙烯基共聚物树脂(A)和交联剂(B)的固体成分的总共100个聚碳酸酯,分别为10重量份。 版权所有(C)2008,JPO&INPIT
    • 36. 发明专利
    • Acid anhydride group-containing vinylic polymer and method for producing the same
    • 含酸酐基的含氟聚合物及其制备方法
    • JP2007297548A
    • 2007-11-15
    • JP2006128215
    • 2006-05-02
    • Mitsubishi Rayon Co Ltd三菱レイヨン株式会社
    • OBAYASHI MINAYAJIMA SHIGE
    • C08F22/04C09D157/10
    • PROBLEM TO BE SOLVED: To provide an acid anhydride group-containing vinylic polymer affording a coated film having good thermal yellowing resistance even when used in an acid/epoxy curing-based clear coating and to provide a method for production according to a method for continuous polymerization using an inexpensive monomer.
      SOLUTION: The method for producing the acid anhydride group-containing vinylic polymer having 2,000-6,000 mass-average molecular weight is provided. The method comprises a first step of continuously feeding a raw material mixture comprising a vinylic monomer containing a vinylic monomer having an α,β-dicarboxylic acid anhydride group and a radical polymerization initiator and a solvent to a continuous tank type first reactor, polymerizing the vinylic monomer so as to afford 50-99% rate of polymerization under conditions of 160-195°C polymerization temperature and 2-30 min residence time and producing a solution of a reaction intermediate mixture and a second step of feeding a polymerization initiator and the solution of the reaction intermediate mixture to a second reactor and further carrying out polymerization under conditions of 100-160°C polymerization temperature and 10-240 min residence time so as to provide ≥80% rate of polymerization.
      COPYRIGHT: (C)2008,JPO&INPIT
    • 待解决的问题:为了提供含酸酐基的乙烯基聚合物,其即使在酸/环氧固化型透明涂料中使用时也提供具有良好耐热黄变性的涂膜,并提供根据 使用廉价单体的连续聚合方法。 解决方案:提供具有2,000-6,000质量平均分子量的含酸酐基的乙烯基聚合物的制备方法。 该方法包括将包含含有α,β-二羧酸酐基团和自由基聚合引发剂的乙烯基单体的乙烯基单体和溶剂的原料混合物连续供给到连续罐型第一反应器的第一步骤, 单体,以在160-195℃聚合温度和2-30分钟停留时间的条件下提供50-99%的聚合速率,并产生反应中间体混合物的溶液,并且第二步进料聚合引发剂和溶液 的反应中间体混合物加入到第二反应器中,并进一步在聚合温度为100-160℃和停留时间为10-240分钟的条件下进行聚合,从而提供≥80%的聚合速率。 版权所有(C)2008,JPO&INPIT