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31. 发明专利

JP2011153186A Cobalt-ketoiminate complex and method for producing polycarbonate using the complex 审中-公开
标题翻译：钴 - 酮酸复合物和使用复合物生产聚碳酸酯的方法
公开(公告)号：JP2011153186A
公开(公告)日：2011-08-11
申请号：JP2010014562
申请日：2010-01-26
申请人： Keio Gijuku , Univ Of Tokyo , 国立大学法人東京大学 , 学校法人慶應義塾
发明人： NAKANO KOJI , NOZAKI KYOKO , NISHIOKA SEIJI , YAMADA TORU , KIKUCHI SATORU , OKADA ATSUSHI
IPC分类号： C08G64/34 , C07C251/12 , C07F15/06 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To provide a complex showing high catalytic activity in a synthesis of polycarbonate and to provide a method for producing polycarbonate using the complex. SOLUTION: The complex is a cobalt-ketoiminate complex expressed by formula (I) or formula (II), wherein at least one of groups represented by R 3 , R 4 and R 5 is a group containing an onium moiety such as ammonium and phosphonium. The present invention also provides a method for copolymerizing an epoxide compound and carbon dioxide by use of the above complex. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供在聚碳酸酯的合成中显示高催化活性的配合物，并提供使用该络合物生产聚碳酸酯的方法。络合物是由式（I）或式（II）表示的钴 - 酮亚胺酸盐络合物，其中由R 3表示的至少一个基团，R 4， SP>和R 5 是含有鎓部分如铵和鏻的基团。本发明还提供了通过使用上述络合物使环氧化合物和二氧化碳共聚的方法。版权所有（C）2011，JPO＆INPIT

32. 发明专利

JP2008088247A Method for producing norbornene polymer having fluorosulfonyl group, polymer having sulfonic acid group and electrolyte membrane for fuel cell by using the polymer 审中-公开
标题翻译：生产具有氟聚醚类的正戊烯聚合物的方法，使用聚合物的燃料电池的磺酸类聚合物和电解质膜的制备方法
公开(公告)号：JP2008088247A
公开(公告)日：2008-04-17
申请号：JP2006269306
申请日：2006-09-29
申请人： Asahi Glass Co Ltd , Univ Of Tokyo , 国立大学法人東京大学 , 旭硝子株式会社
发明人： MUROTANI EISUKE , NOZAKI KYOKO , YAMASHITA MAKOTO
IPC分类号： C08F32/08 , H01B1/06 , H01M8/02 , H01M8/10
CPC分类号： Y02E60/523
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a norbornene polymer having a fluorosulfonyl group, and an electrolyte membrane for a fuel cell by using the polymer.
SOLUTION: This method for obtaining a polymer containing a unit expressed by formula (a) is provided by polymerizing a compound expressed by formula (A) by using an organometallic complex catalyst. In the formula, X is methylene, methylmethylene, dimethylmethylene, O or S; Q
F is a polyfluoro divalent organic group; R is H, F or a polyfluoro monovalent organic group; and (k) is 0, 1 or 2.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：待解决的问题：提供一种通过使用聚合物制备具有氟磺酰基的降冰片烯聚合物的方法和用于燃料电池的电解质膜。解决方案：通过使用有机金属配合物催化剂聚合由式（A）表示的化合物，获得含有式（a）表示的单元的聚合物的方法。在该式中，X是亚甲基，甲基亚甲基，二甲基亚甲基，O或S; Q F 是多氟二价有机基团; R是H，F或多氟一价有机基团; （k）为0，1或2.版权所有（C）2008，JPO＆INPIT

33. 发明专利

JP2007238639A Synthesis of polytrithiocarbonate by alternating copolymerization of episulfide and carbon disulfide 审中-公开
标题翻译：通过改变EPISULFIDE和CARBON DISULFIDE的共聚合来合成聚异丁酸
公开(公告)号：JP2007238639A
公开(公告)日：2007-09-20
申请号：JP2006058500
申请日：2006-03-03
申请人： Univ Of Tokyo , 国立大学法人東京大学
发明人： NOZAKI KYOKO , NAKANO KOJI
IPC分类号： C08G75/28
摘要： PROBLEM TO BE SOLVED: To develop a novel preparation method capable of realizing a high polymerization activity, a highly alternating property and control of molecular weight distribution and regioregularity using, as a raw material, carbon disulfide that can be easily synthesized from carbon and sulfur, and to provide a novel trithiocarbonate alternating copolymer that could not be conventionally prepared. SOLUTION: The polytrithiocarbonate alternating copolymer of formula (1) having a number average molecular weight of 1,000 or larger is prepared by the preparation method of the polytrithiocarbonate alternating copolymer wherein episulfide is polymerized with carbon disulfide in the presence of a nucleophilic reagent and a Lewis acid metal compound. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：为了开发一种能够实现高聚合活性，高交替性和控制分子量分布和区域规整性的新型制备方法，使用可以容易地从碳上合成的二硫化碳作为原料和硫，并提供不能常规制备的新型三硫代碳酸酯交替共聚物。解决方案：通过聚亲二硫化碳交替共聚物的制备方法制备数均分子量为1,000或更大的式（1）的聚二硫代碳酸酯交替共聚物，其中在亲核试剂存在下使二硫化碳与二硫化碳聚合，路易斯酸金属化合物。版权所有（C）2007，JPO＆INPIT

34. 发明专利

JP2007046032A Metal compound, catalyst composition for polymerizing vinylic monomer and use for polymerization of vinylic monomer using the same composition 有权
标题翻译：金属化合物，用于聚合乙烯基单体的催化剂组合物和用于使用相同组合物聚合乙烯基单体
公开(公告)号：JP2007046032A
公开(公告)日：2007-02-22
申请号：JP2005365543
申请日：2005-12-19
申请人： Kuraray Co Ltd , Univ Of Tokyo , 国立大学法人東京大学 , 株式会社クラレ
发明人： NOZAKI KYOKO , KAWACHI TAKUYA , IDA HIROSHI
IPC分类号： C08F4/80 , C07C211/06 , C07F9/50 , C07F15/00 , C07F19/00 , C08F4/70 , C08F10/00 , C08F12/00 , C08F16/00 , C08F20/00 , C08F36/00
摘要： PROBLEM TO BE SOLVED: To polymerize a vinylic monomer having a functional group in the side chain under milder conditions.
SOLUTION: The vinylic monomer is polymerized by using a composition composed of a component containing at least one kind selected from the group consisting of a metal compound. Furthermore, the metal compound has a phosphinesulfonic acid ligand represented by formula (I) (wherein, R
1 to R
7 represent each a hydrogen, a 1-20C aliphatic hydrocarbon group which may have a substituent, a 6-20C aromatic hydrocarbon group which may have a substituent, an alkoxy group or an aryloxy group; X represents a hydrogen, a 1-20C aliphatic hydrocarbon group which may have a substituent, a 6-20C aromatic hydrocarbon group which may have a substituent, a 5-20C nitrogen-containing aromatic compound which may have a substituent, a halogen, a trifluoromethanesulfonyl group or a perchloro; and M represents a group 10 element of the periodic table).
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：待解决的问题：在更温和的条件下聚合侧链中具有官能团的乙烯基单体。解决方案：通过使用由含有选自金属化合物中的至少一种的组分组成的组合物聚合乙烯基单体。此外，金属化合物具有由式（I）表示的膦磺酸配位体（其中，R 1 至R 7 各自表示氢，1-20C脂族烃基可以具有取代基的6-20C芳族烃基，烷氧基或芳氧基; X表示氢，可以具有取代基的1-20C脂族烃基，6-20C芳族可以具有取代基的烃基，可以具有取代基的5-20C含氮芳香族化合物，卤素，三氟甲磺酰基或全氯; M表示周期表的第10族元素）。版权所有（C）2007，JPO＆INPIT

35. 发明专利

JP2006241325A Catalyst composition for vinyl monomer polymerization and use thereof in vinyl monomer polymerization 有权
标题翻译：用于乙烯单体聚合的催化剂组合物及其在乙烯单体聚合中的应用
公开(公告)号：JP2006241325A
公开(公告)日：2006-09-14
申请号：JP2005059697
申请日：2005-03-03
申请人： Kuraray Co Ltd , Univ Of Tokyo , 国立大学法人東京大学 , 株式会社クラレ
发明人： NOZAKI KYOKO , YAMASHITA MAKOTO , IDA HIROSHI , UOZUMI TOSHIYA
IPC分类号： C08F4/62
摘要： PROBLEM TO BE SOLVED: To polymerize a vinyl monomer bearing a functional group in its side chain under a milder condition.
SOLUTION: At least one catalyst selected from the group consisting of metal compounds represented by formulae (I), (II) and (III) (wherein R
1 , R
2 , R
3 , R
4 , R
5 and R
6 are each a specific hydrocarbon group; X
1 , X
2 , X
3 and X
4 are each a specific group; and M
1 and M
2 are each a group 10 element in the periodic table) is used.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：待解决的问题：在较温和的条件下，使其侧链上具有官能团的乙烯基单体聚合。解决方案：选自由式（I），（II）和（III）表示的金属化合物（其中R 1，R 2，R 2， SB>，R SB 3，R SB 4，R SB 5和R SB 6各自是特定的烃基; X 1 ，X 2 ，X 3 和X 分别是特定组; M < ＆lt; / SB＆gt;和M＆lt; SB＆gt; 2＆lt; / SB＆gt;各为元素周期表中的10族元素）。版权所有（C）2006，JPO＆NCIPI

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