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31. 发明专利

JP2001254074A PHOTOCHROMIC MOLECULE MATERIAL 失效
公开(公告)号：JP2001254074A
公开(公告)日：2001-09-18
申请号：JP2000065426
申请日：2000-03-09
申请人： IRIE MASAHIRO
发明人： IRIE MASAHIRO
IPC分类号： G02B5/23 , C09K9/02
摘要： PROBLEM TO BE SOLVED: To provide a photochromic molecular material wherein the fluorescence intensity is greatly changed by light control. SOLUTION: The photochromic molecular material is represented by formula [I] (wherein ring A is a hydrocarbon ring or a heterocyclic ring; and ring B and ring C are each a 5-membered aromatic heterocyclic group, provided that ring B and/or ring C has a fluorescent substituent comprising a (non)substituted anthracene residue, an imidazole residue, an indole residue, a terphenyl residue, a fluorene residue or a pyrene residue).

32. 发明专利

JPH11256146A PHOTOCHROMIC MATERIAL 失效
公开(公告)号：JPH11256146A
公开(公告)日：1999-09-21
申请号：JP6273398
申请日：1998-03-13
申请人： IRIE MASAHIRO
发明人： IRIE MASAHIRO
IPC分类号： C09K9/02
摘要： PROBLEM TO BE SOLVED: To obtain a photochromic material that can attain freer color development than conventional ones in no need of mixed photochromic materials. SOLUTION: A photochromic material that can develop colors which have been impossible to be developed with one conventional material or that can change the shade or the like in multi-steps is obtained by introducing 2 or more kinds of arylethene groups into one molecule. For example, the photochromic material is typified by a compound represented by the formula (R1 -R10 are each indepenciently an alkyl group or hydrogen atom; (n) is 0 or 1; R is a divalent organic residual group).

33. 发明专利

JPH10101802A PHOTOCHROMIC ORGANOPOLYSILOXANE AND ITS PRODUCTION 失效
公开(公告)号：JPH10101802A
公开(公告)日：1998-04-21
申请号：JP27555296
申请日：1996-09-26
申请人： DOW CORNING TORAY SILICONE , IRIE MASAHIRO
发明人： NAKAJIMA HISATAKA , IRIE MASAHIRO
IPC分类号： G03C1/73 , C08G77/392
摘要： PROBLEM TO BE SOLVED: To obtain the subject compound useful for an optical memory, etc., capable of causing change in molecular structure followed by change in spectrum by irradiation with ultraviolet light and restoring the molecular structure to its original state by irradiation with visible light, by bonding a specific photochromic organic group to silicon in the molecule. SOLUTION: This photochromic organopolysiloxane is obtained by bonding an organic group of formula I [R is H or a monofunctional organic group (Z ) which is an alkyl, an aryl, etc., or a bifunctional organic group (Z ) which is a group containing an alkylene chain and an arylene (X ), an ester bond (X ), an amide bond (X ) or an ether bond (X ) or is an alkylene and one or more R s are Z ; (n) is 3 or 4] to Si in a polyorganosiloxane molecule. The compound is obtained by reacting a polyorganosiloxane containing H bonded to Si in the molecule with a compound of formula II [R is a monofunctional organic group (Z ) which is a group containing an alkenyl (X ) and X , X , X or X or is X or Z and one or more R s are Z in the presence of a catalyst for a hydrosilylating reaction.

34. 发明专利

JPH1045732A DIARYLETHENE DERIVATIVE AND PHOTOCHROMIC MATERIAL USING THE SAME 失效
公开(公告)号：JPH1045732A
公开(公告)日：1998-02-17
申请号：JP21907396
申请日：1996-08-02
申请人： IRIE MASAHIRO , TOMOEGAWA PAPER CO LTD
发明人： IRIE MASAHIRO , UCHIDA KINGO , ISHIKAWA TAKAYUKI
IPC分类号： C07D277/22 , C07D277/20 , C07D277/34 , C09K9/02
摘要： PROBLEM TO BE SOLVED: To obtain a new compound having a highly efficient ring closing reaction by light, photochromic properties excellent in durability of repetition of coloring and decoloring, useful as a reversible recording material in the field of photonics such as optical switching element. SOLUTION: This compound is shown by formula I (R and R are each an alkyl, an alkoxy or an aryl) such as 1,2-bis(5-ethoxy-2-methylthiazole) hexafluorocyclopentene. The compound of formula I is obtained by lithiating a thiazole halide derivative of formula II (X is Br or I) to give a thiazolelithium derivative and reacting the derivative with octafluorocyclopentene (pentafluorocyclopentene).

35. 发明专利

JPH09241254A AMORPHOUS PHOTOCHROMIC MATERIAL AND OPTICAL RECORDING MEDIUM USING THE SAME 失效
公开(公告)号：JPH09241254A
公开(公告)日：1997-09-16
申请号：JP5159396
申请日：1996-03-08
申请人： IRIE MASAHIRO
发明人： IRIE MASAHIRO
IPC分类号： G03C1/73 , C07D333/54 , C07D333/64 , C09K9/02 , G11B7/24 , G11B7/244
摘要： PROBLEM TO BE SOLVED: To obtain an amorphous photochromic material which comprises a specific diheteroarylethene, can form a photochromic membrane in no need of a polymer medium and is used as an optical recording medium. SOLUTION: This photochromic material comprises a diheteroarylethene having at least one of adamantyl group-substituted hetero-fivemembered ring, preferably pyrrole ring, thiophene ring, furan ring or selenophene ring in the heteroaryl moiety. The objective compound is preferably represented by the formula (R is an alkyl, an alkoxy; R is H, an alkyl), typically 1-[2- methylbenzo[b]thiophen-3yl]-2-[2-(2-adamantyl)-3,5-dimethylthiophen-4- yl]perfluorcyclopentene or the like.

36. 发明专利

JPH07248570A PHOTOCHROMIC OPTICAL RECORDING MATERIAL 失效
公开(公告)号：JPH07248570A
公开(公告)日：1995-09-26
申请号：JP4085994
申请日：1994-03-11
申请人： IRIE MASAHIRO
发明人： IRIE MASAHIRO
IPC分类号： G03C1/73 , C09K9/02 , G11B7/24 , G11B7/244
摘要： PURPOSE:To provide a photochromic optical recording material having nondestructive readout function. CONSTITUTION:The photochromic optical recording material containing a naphthopyrane deriv. represented by the formula and having one or more electron withdrawing groups as substituents on the naphthalene or benzene ring is obtained. By introducing the electron withdrawing groups, the naphthopyrane deriv. which has two-photon photochromic reactivity, in which absorption wavelength is shifted to the longer wavelength side and which shows a sufficient color change effective to this photochromic optical recording material, is obtained.

37. 发明专利

JPH07248569A PHOTOCHROMIC OPTICAL RECORDING MATERIAL 失效
公开(公告)号：JPH07248569A
公开(公告)日：1995-09-26
申请号：JP4085894
申请日：1994-03-11
申请人： IRIE MASAHIRO , MITSUBISHI CHEM CORP
发明人： IRIE MASAHIRO , NAKAMURA SHINICHIRO
IPC分类号： G03C1/73 , C09K9/02 , G11B7/24 , G11B7/244
摘要： PURPOSE:To obtain a photochromic optical recording material having thermal stability and sensitivity in a long wavelength region. CONSTITUTION:This photochromic optical recording material contains an ethylene deriv. obtd. by bonding substituents each having a pi-conjugated chain to carbon at the 1-position of an ethylene bond and to carbon at the 2-position. The pi-conjugated chain is a 5-membered heterocyclic chain and at least one of the substituents has two or more 5-membered hetero rings. Since a relatively long pi-conjugated chain extending to the entire molecule is formed by the 5-membered polyheterocyclic chain, absorption wavelength is shifted to the longer wavelength side and sensitivity to semiconductor laser beams is ensured.

38. 发明专利

JPH07248568A OPTICAL RECORDING MATERIAL 失效
公开(公告)号：JPH07248568A
公开(公告)日：1995-09-26
申请号：JP3730894
申请日：1994-03-08
申请人： SANYO ELECTRIC CO , IRIE MASAHIRO , KOBE TENNENBUTSU KAGAKU KK
发明人： TATSUZONO FUMIO , HARADA TOSHIO , IRIE MASAHIRO , OBARA SHU
IPC分类号： C09K9/02 , G03C1/73 , G11B7/244 , G11B7/24
摘要： PURPOSE:To obtain an optical recording material liable to a considerable change in reflectance and excellent in resistance to repeated coloring and decoloring. CONSTITUTION:This optical recording material contains a photochromic compd. represented by the formula, wherein A is O or optionally substd. N, B is an optionally substd. thiophene, benzo-hiophene, tpyrrole or indole ring, R1 is methyl, alkoxy or perfluoroalkyl and each of R2-R7 is H, halogen, hydroxy, optionally substd. alkyl, etc. The photochromic compd. may bond to a polymer as a side chain at the position of A.

39. 发明专利

JPH0782266A PHOTOCHROMIC COMPOUND 失效
公开(公告)号：JPH0782266A
公开(公告)日：1995-03-28
申请号：JP22975093
申请日：1993-09-16
申请人： TOKUYAMA CORP , IRIE MASAHIRO
发明人： IRIE MASAHIRO
IPC分类号： C07D409/14 , C08F20/34 , C08F20/38 , C08F220/36 , C08F220/38 , C09K9/02
摘要： PURPOSE:To provide a new compound capable of producing a polymer containing the compound in a diaryl ester structure by the copolymerization with a copolymerizable monomer and accordingly dispersible in a polymeric medium in high concentration to give a dispersion resistant to phase separation without lowering the color density. CONSTITUTION:A compound of the formula I (X is O or N which may have cyanoalkyl as a substituent; R1 to R5 are alkyl, cyano, etc.; R6 is alkylene; R7 is H or CH3), e.g. the compound of the formula II. The compound is produced preferably by reacting a compound of the formula III such as 1-(11- methacryloyloxy)undecyl-2-methylindole with oxalyl chloride in a solvent such as dichloromethane and reacting the reaction product with a compound of the formula IV (X is halogen or OH) such as 5-cyano-2,4-dimethyl-3-thienylacetic acid in the presence of trimethylamine, etc.

40. 发明专利

JPH05128523A REPRODUCING METHOD OF OPTICAL RECORDING MEDIUM 失效
公开(公告)号：JPH05128523A
公开(公告)日：1993-05-25
申请号：JP29160191
申请日：1991-11-07
申请人： SANYO ELECTRIC CO , IRIE MASAHIRO
发明人： TSUJIOKA TSUYOSHI , IRIE MASAHIRO
IPC分类号： G11B7/00 , G11B7/005 , G11B7/30 , G11B20/00
摘要： PURPOSE:To remove a cross-talk component by a method wherein a beam of reflected replay light of a multiple recording medium is separated into corresponding components, they are detected independently and an operation processing operation is executed to a part between signals. CONSTITUTION:Rd represents a reflection factor at a time when no recording operation is executed; Rc, Rb and Ra are reflection factors at a time when lambdab and lambdaa as well as lambdaa and lambdab are irradiated respectively and a recording operation is executed. DELTAR1 (Rb to Rd) not equal to DELTAR2 (Ra to Rc) and deltaR (Ra to Rb) not equal to deltaR* (Rc to Rd). At this time, a reflection factor at lambdaa corresponds to a value which has changed Rb to Rd at an amplitude of DELTAR1/2 according to lambdaa (omega1) at a part not irradiated with lambdab. Consequently, a change DELTAR ch1 (proportional replay output) in the reflection factor at lambdaa is a value which has amplitude-modulated a signal omega by omega2 (a signal at lambdab) and which has superposed the signal omega2. deltaR ch2 at lambdab can be found in the same manner. When xsi...eta are used as cross-talk parameters, nonlinear cross-talk terms corresponding to a product exist in a standardized reproduced output in addition to linear terms. In order to reduce a cross-talk component, a specific operation is executed by using respective standardized replay outputs, xsi and eta, and a portion mixed with a piece of information is removed.

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