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    • 31. 发明专利
    • Method for detoxifying instrument containing organic halogen compound
    • 用于脱氧含有机卤素化合物的仪器的方法
    • JP2006142278A
    • 2006-06-08
    • JP2005192951
    • 2005-06-30
    • Tokyo Electric Power Co Inc:The東京電力株式会社
    • ITO KOICHIITOI MASAYUKIOTSUKI SHIGERUAMANO KOJIOTAKE KUNINOBUSHIMOJO MIKIOTEZUKA HIROKO
    • B09B3/00A62D3/178A62D3/30A62D3/36A62D101/22
    • PROBLEM TO BE SOLVED: To provide a method of detoxifying instruments containing organic halogen compounds capable of easily detoxifying the instruments (transformers, oil tanks of insulation oil) having oil mixed with organic halogen compounds adhering thereto in a short time without using any special decomposition apparatus, and with little possibility of forming reaction byproducts. SOLUTION: This method of detoxifying instruments containing organic halogen compounds comprises a process for filling a solution 2 formed by adding an alkaline compound to a hydrogen donator, into an instrument 1 having insulation oil containing organic halogen compounds adhering thereto; and a process for decomposing the organic halogen compounds contained in the insulation oil remaining in the instrument 1, by circulating the solution 2 through a catalyst-packed apparatuses 4. COPYRIGHT: (C)2006,JPO&NCIPI
    • 解决问题的方法:提供一种含有有机卤素化合物的仪器的解毒方法,所述有机卤素化合物能够在短时间内容易地将附着有有机卤素化合物的油体与容易地解毒的仪器(绝缘油的变压器,油箱) 特殊的分解装置,几乎没有形成反应副产物的可能性。 解决方案:这种含有机卤素化合物的解毒装置的方法包括将含有碱性化合物形成的溶液2填充到氢供体中的方法,包括含有粘附有有机卤素化合物的绝缘油的仪器1; 以及通过使溶液2通过催化剂填充装置4循环来分解包含在仪器1中的绝缘油中的有机卤素化合物的方法。(C)2006,JPO&NCIPI
    • 32. 发明专利
    • Method for removing chlorinated organic compound
    • 去除氯化有机化合物的方法
    • JP2005111470A
    • 2005-04-28
    • JP2003434792
    • 2003-12-26
    • Tokyo Electric Power Co Inc:The東京電力株式会社
    • ITO KOICHIOTAKE KUNINOBUUMEDA YOKOOGAWA HITOSHIITOI MASAYUKI
    • C07D319/24B01D15/00C02F1/28C02F1/42H01F41/00
    • PROBLEM TO BE SOLVED: To provide a method for easily and efficiently removing a chlorinated organic compound from a solution which is filled into a vessel and contains low-concentration chlorinated organic compound, particularly from insulating oil which is filled into a pole-mounted transformer member and contains the chlorinated organic compound.
      SOLUTION: This method for removing the chlorinated organic compound from the solution which is filled into the vessel and contains the chlorinated organic compound comprises the steps of: charging an adsorbing material in the solution or circulating the solution and making the solution pass through an adsorption apparatus arranged outside or inside the vessel to bring the solution into contact with the adsorbing material in the adsorption apparatus, so that the chlorinated organic compound is adsorbed on the adsorbing material and; recovering the adsorbing material together with the chlorinated organic compound.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:提供一种从填充到容器中的溶液中容易且有效地除去氯化有机化合物的方法,并且含有低浓度氯化有机化合物,特别是从填充到极性溶剂中的绝缘油, 安装的变压器构件并含有氯化有机化合物。 解决方案:从填充到容器中并含有氯化有机化合物的溶液中除去氯化有机化合物的方法包括以下步骤:在溶液中加入吸附材料或使溶液循环并使溶液通过 吸附装置设置在容器内部或内部,以使溶液与吸附装置中的吸附材料接触,使得氯化有机化合物吸附在吸附材料上; 与氯化有机化合物一起回收吸附材料。 版权所有(C)2005,JPO&NCIPI
    • 33. 发明专利
    • Chlorinated organic compound adsorbing agent and method for separating chlorinated organic compound by using the same
    • 氯化有机化合物吸附剂及其使用方法分离氯化有机化合物
    • JP2005111387A
    • 2005-04-28
    • JP2003350129
    • 2003-10-08
    • Tokyo Electric Power Co Inc:The東京電力株式会社
    • ITO KOICHIOGAWA HITOSHIOTSUKI SHIGERUAMANO KOJIUMEDA YOKOITOI MASAYUKI
    • C02F1/28B01J20/20
    • PROBLEM TO BE SOLVED: To obtain a chlorinated organic compound adsorbing agent with which a chlorinated organic compound such as PCBs (perchlorobipheryls) contained minutely in oil such as insulating oil can be adsorbed/removed efficiently and the chlorinated organic compound can be treated at a cost lower than that of a chemical extracting/decomposing method, and to provide a method for separating the chlorinated organic compound by using this adsorbing agent.
      SOLUTION: The adsorbing agent for adsorbing the chlorinated organic compound in the oil consists of modified activated carbon obtained by treating activated carbon with an amine compound such as an aromatic polyamine, an alkylamine quaternary salt, an ethylene oxide (EO) adduct to a mono- or di-alkylamine and an amine oxide. The method for separating the chlorinated organic compound comprises a step to adsorb the chlorinated organic compound in the oil by bringing the chlorinated organic compound adsorbing agent into contact with the oil containing the chlorinated organic compound.
      COPYRIGHT: (C)2005,JPO&NCIPI
    • 要解决的问题:为了获得氯化有机化合物吸附剂,可以有效地吸附/除去诸如绝缘油等在油中微量含有的PCB(全氯乙烯基)等氯化有机化合物,氯化有机化合物的处理 成本低于化学提取/分解方法的成本,并且提供通过使用该吸附剂分离氯化有机化合物的方法。 溶剂:用于吸附油中的氯化有机化合物的吸附剂由通过用胺化合物如芳族多胺,烷基胺季盐,环氧乙烷(EO)加合物处理活性炭得到​​的改性活性炭组成, 单 - 或二 - 烷基胺和氧化胺。 分离氯化有机化合物的方法包括通过使氯化有机化合物吸附剂与含有氯化有机化合物的油接触来吸附油中的氯化有机化合物的步骤。 版权所有(C)2005,JPO&NCIPI