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21. 发明专利

JP2909231B2 失效
公开(公告)号：JP2909231B2
公开(公告)日：1999-06-23
申请号：JP1161991
申请日：1991-01-09
申请人： BAIERU AG , EICHI SHII SUTARUKU GMBH UNTO CO KG
发明人： UDO BIRUKENSHUTOTSUKU , YURUGEN SHARUSHUMITSUTO , PEETAA KUNERUTO , HERUMUUTO MAINHARUTO , PAURU HENZERU , PAURU MAIAA
IPC分类号： B01J21/02 , B01J21/04 , B01J25/00 , B22F9/08 , C07B35/02 , C07B37/02 , C07B43/04 , C07B61/00 , C07C29/20 , C07C35/08 , C07C209/36 , C07C211/51 , C22C1/04

22. 发明专利

JPH10511344A 失效
公开(公告)号：JPH10511344A
公开(公告)日：1998-11-04
申请号：JP51883795
申请日：1995-11-15
IPC分类号： B01J23/44 , C07B35/02 , C07B61/00 , C07C17/354 , C07C19/01

23. 发明专利

JPH10137587A PRODUCTION OF NOBLE METAL CATALYST ON CARRIER 失效
公开(公告)号：JPH10137587A
公开(公告)日：1998-05-26
申请号：JP31423796
申请日：1996-11-11
申请人： COSMO SOGO KENKYUSHO KK , COSMO OIL CO LTD
发明人： MIZUGUCHI HIROSHI , SUZUKI TAKASHI , IWANAMI HIKOICHI , YOSHIZAWA TAKASHI
IPC分类号： B01J23/44 , B01J23/46 , B01J37/03 , B01J37/08 , C07B35/02 , C07B35/04 , C07B61/00 , C10G45/10
摘要： PROBLEM TO BE SOLVED: To produce a highly active catalyst only by activation treatment by depositing a noble metal on a carrier, using an alkali soln. to change the noble metal into insoluble as a hydroxide and to fix, and then treating the noble metal at specified temp. in an inert gas atmosphere under reduced pressure without the presence of an oxidizing gas. SOLUTION: In the production of a noble metal catalyst by depositing a noble metal such as palladium, rhodium and ruthenium on a carrier, one kind of noble metal selected from ruthenium, rhodium and palladium is deposited on a carrier, the noble metal is changed into soluble and fixed by using an alkali soln., and then the metal is treated at 100 to 500 deg.C in an inert gas atmosphere or reduced pressure atmosphere without the presence of an oxidative gas. The alkali soln. used for insoluble and fixing treatment is controlled to 8 to 10 pH and the temp. is controlled to 20 to 50 deg.C. As for the alkali soln., ammonia water is preferably used. As for the carrier, alumina, silica and oxide of rare earth metal can be used.

24. 发明专利

JPH09510140A 失效
公开(公告)号：JPH09510140A
公开(公告)日：1997-10-14
申请号：JP52380595
申请日：1995-03-04
IPC分类号： B01J23/755 , B01J37/03 , C07B35/02 , C07B61/00 , C07C5/02 , C10G45/46 , C10G45/48 , C10G73/44

25. 发明专利

JPH09504991A 失效
公开(公告)号：JPH09504991A
公开(公告)日：1997-05-20
申请号：JP51420494
申请日：1994-11-11
IPC分类号： B01J23/89 , B01J35/00 , B01J35/08 , B01J37/02 , B01J38/00 , C07B35/02 , C07D301/00

26. 发明专利

JPH07275713A METHOD OF PREPARING HYDROGENATED CATALYST SOLUBLE IN ORGANICLIQUID PHASE 失效
公开(公告)号：JPH07275713A
公开(公告)日：1995-10-24
申请号：JP379095
申请日：1995-01-13
申请人： INST FRANCAIS DU PETROLE
发明人： DANIERU DEYURAN , JIERAARU IRIYON , PATORITSUKU SARAZAN
IPC分类号： B01J31/04 , B01J31/12 , B01J31/14 , B01J35/12 , C07B35/02 , C07B61/00 , C07C5/03 , C07C5/05 , C07C5/10 , C07C13/02 , C07C13/28
摘要： PURPOSE: To improve activity and selectivity in a hydrogenation reaction of an unsaturated compound by neutralizing the residual of a reducing compound with an oxidizing agent after melting plural metals in plural organic solvents and contacting one of metals with the other metal in the reducing compound. CONSTITUTION: When arranging a homogeneous phase catalyst soluble in organic media, at first, at least one compound of at least one metal A in at least one organic solvent S, and at least one reducing compound R of at least one metal B in at least one organic solvent S', are respectively dissolved. Next, the reducing compound R and the compound of the metal A are contacted. Then the residual reducing functional base is neutralized by at least one oxidizing agent O. The catalyst thus manufactured has excellent activity and selectivity in hydrogenation reaction of unsaturated compounds.

27. 发明专利

JPH07242630A PRODUCTION OF PIPERIDINECABOXYLIC ACIDS 失效
公开(公告)号：JPH07242630A
公开(公告)日：1995-09-19
申请号：JP6029694
申请日：1994-03-04
申请人： ISHIHARA SANGYO KAISHA
发明人： ASAI NOBUYOSHI
IPC分类号： C07D211/60 , B01J23/44 , C07B35/02 , C07B61/00
摘要： PURPOSE:To industrially and advantageously produce a high-purity piperidinecarboxylic acid free from coloration in a high yield while inhibiting formation of a by-product by reducing a pyridinecarboxylic acid in the presence of a palladium-based catalyst and a reducing agent. CONSTITUTION:These piperidinecarboxylic acids of formula II can be produced by reducing a pyridinecarboxylic acid represented by formula I [X is COOH, CONH2 or COOR' (R' is a lower alkyl); R is H or a lower alkyl] in the presence of a palladium-based catalyst and a reducing agent. Palladium-hydrocarbon or palladium-sodiumtreated hydrocarbon catalyst is preferably used as the palladium-based catalyst and hydrogen gas is suitably used as the reducing agent. This reduction reaction is conducted preferably at 50 to 150 deg.C and 10kg/cm pressure of hydrogen. As the solvent of this reduction reaction, ethanol, water or a mixture thereof is preferably used. This compound of formula II is useful as an intermediate for production of medicines such as a quinuclidinebased medicine for senile dementia and agrochemicals.

28. 发明专利

JPH0692427B2 失效
公开(公告)号：JPH0692427B2
公开(公告)日：1994-11-16
申请号：JP17851990
申请日：1990-07-07
IPC分类号： B01J31/22 , C07B35/02 , C07B53/00 , C07B57/00 , C07B61/00 , C07C51/36 , C07C53/128 , C07C55/02 , C07C67/303 , C07C69/34 , C07C205/06 , C07C205/12 , C07C231/16 , C07C233/47 , C07C233/83 , C07F9/50 , C07F15/00 , C07F19/00

29. 发明专利

JPH06199705A PRODUCTION OF TETRALIN DERIVATIVE 失效
公开(公告)号：JPH06199705A
公开(公告)日：1994-07-19
申请号：JP212093
申请日：1993-01-08
申请人： MITSUI PETROCHEMICAL IND
发明人： TATSUKI YUUICHIROU , TANAKA CHIHO , NISHIYAMA SHINICHI
IPC分类号： B01J23/46 , C07B35/02 , C07B61/00 , C07C17/00 , C07C17/354 , C07C25/22 , C07C65/11 , C07C205/06 , C07C253/30 , C07C255/52 , C07C255/53 , C07C255/54
摘要： PURPOSE:To synthesize a tetralin derivative from a naphthalene compound in high selectivity. CONSTITUTION:A tetralin derivative is produced by contacting a naphthalene compound having relatively electron-accepting substituent or atom on one ring and relatively electron-donative substituent or atom on the other ring with hydrogen in the presence of at least one kind of catalyst consisting of Ru or Rh, thereby selectively reducing the ring substituted with substituent or atom having relatively high electron-donative property.

30. 发明专利

JPH05255128A 失效
公开(公告)号：JPH05255128A
公开(公告)日：1993-10-05
申请号：JP8595292
申请日：1992-03-09
IPC分类号： B01J31/12 , B01J31/22 , B01J31/24 , C07B35/02 , C07B61/00 , C07C5/09 , C07C11/02 , C07C15/42 , C07C29/17 , C07C33/044 , C07C51/36 , C07C57/03 , C07C69/007 , C07C69/145 , C07C69/606 , C07C253/30 , C07C255/06 , C07D309/12 , C07F7/18
摘要： PURPOSE:To selectively and readily produce a cis-olefin useful as an intermediate for various fine chemicals under a mild reaction condition in a high yield by reducing an alkine with formic acid in the presence of a palladium catalyst. CONSTITUTION:An alkine (e.g. 2-undecyne) of formula I [R1, R2 are H, ester, substituted silyl, carboxyl, cyano, (substituted)1-20C aliphatic hydrocarbon, (substituted)phenyl] is reduced with formic acid in the presence of a palladium catalyst to give a cis-olefin of formula II (e.g. 2-undedecene). A compound selected from an amine, a phosphine and a phosphite is preferably added to the reaction system. The method is advantageous because of substantially no production of a trans-olefin and saturated compounds.

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