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    • 21. 发明专利
    • CERIUM OXIDE POWDER AND COSMETIC MATERIAL, COATING MATERIAL AND PLASTIC CONTAINING THE SAME
    • JPH11228135A
    • 1999-08-24
    • JP3472198
    • 1998-02-17
    • TORAY INDUSTRIES
    • ONO MAMORUYOSHIDA FUMIOTANAKA KOICHI
    • A61K8/06C01F17/00C04B35/50C08K3/22C09D7/12A61K7/00
    • PROBLEM TO BE SOLVED: To reduce the deterioration or the photoactivity of cosmetic, coating material and plastic caused by ultraviolet ray by specifying the number average particle diameter range of a primary particle and the half-value width range of angle of diffraction in X-ray diffraction to improve ultraviolet shielding property. SOLUTION: In a powder of cerium oxide, the number average particle diameter of the primary particle is controlled to 0.01-0.5 μm. If the particle diameter is below the lower limit, the probability of light transmission is increased to make the shielding property insufficient though the number of the particle is increased and if the particle diameter exceeds the upper limit, the number of the particle is decreased to make the shielding property insufficient though light is not transmitted to be scattered. And the half-value width 2δ (degree) of 28.6 deg. angle of diffraction (111 plane) in the X-ray diffraction is 0.7-0.15. In the range where the half-value width exceeds the upper limit, the crystallinity becomes insufficient to be nearly amorphous and in the range below the lower limit, the particle is over grown and in both case, ultraviolet ray is easily transmitted. The cerium oxide is blended to the coating material or the cosmetic in the form as the particle is and can be also blended in a paste-like or slurry like form.