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    • 22. 发明专利
    • JPH05249055A
    • 1993-09-28
    • JP8170192
    • 1992-03-03
    • TOSHIBA CORP
    • NUMANO MASAKUNITSUCHIYA NORIHIKOMATSUSHITA YOSHIAKI
    • G01N23/223
    • PURPOSE:To conduct accurate distribution measurement of a sample wherein the distribution of concentration of impurities is not uniform, by a method wherein a primary X-ray of uniform intensity is made to fall on the whole area of a part of the surface of the sample so that fluorescent X-rays of uniform intensity may be excited. CONSTITUTION:As to a controlling direction of an incident angle of X rays, two guide rails 21A and 21B are operated first by a driving part 20a and made to move to a position (0 degree) at which primary X-rays from two X-ray sources are superposed. Next, the X ray is made to fall on a sample 13 from one X-ray source 11A, a sample stage 16 is moved, the intensity of the X ray is detected by a counter tube 17 and then the sample stage 16 is moved to a position at which it is parallel to the primary X-rays. By moving the rails 21A and 21B by the same amount by the driving part 20a from the state (position of 0 degree) wherein the X-ray sources 11A and 11B and the surface of the sample are lined, incident angles of the primary X-rays from the X-ray sources 11A and 11B are made equal. On the occasion of measurement, the counter tube 17 is disposed outside the course of the X ray. An incident X-ray in an X-ray-irradiated part of the surface of the sample is the sum of incident X-rays from the first X-ray source 11A and the second X-ray source 11B and thus uniformity in an X-ray intensity distribution in the X-ray-irradiated part is improved to a large extent.
    • 24. 发明专利
    • MANUFACTURE OF SEMICONDUCTOR DEVICE
    • JPH04256310A
    • 1992-09-11
    • JP1773891
    • 1991-02-08
    • TOSHIBA CORP
    • NUMANO MASAKUNISAMATA SHUICHI
    • H01L21/205H01L21/302
    • PURPOSE:To make it possible to grow reliably a polycrystalline Si film by a method wherein a vapor growth treatment is performed setting the ratio of the concentration of hydrochloric acid gas to the concentration of dichlorosilane gas at a specified value or lower and setting temperature conditions at a temperature or higher to need to decompose material gas and at a specified temperature or lower in a state that a natural oxide film of a specified film thickness is left. CONSTITUTION:An SiO2 insulating film 12 of a thickness of about 0.5mum is formed on the surface of an Si substrate 11 and thereafter, an opening part 13 of a diameter of about 0.6 to 2.0mum is formed by a photolithography technique. Then, an HF treatment of 1:200 is performed and at the time of a cleaning treatment using pure water subsequent to the HF treatment, the concentration of oxygen dissolved in the pure water is controlled to form a natural oxide film 14 of a thickness of 2 to 3Angstrom on the surface of the substrate 11 in the part 13 and a substrate to be treated is obtained. The substrate to be treated is set in a furnace, is heated up to 900 deg.C in an H2 atmosphere and immediately after the heat-up, SiH2Cl2 and HCl are used, a vapor growth treatment is performed at [SiH2Cl2]=0.1% and [HCl]=0.2%, with H2 carrier gas and at a pressure of 10Torr and lastly, a cooling-down treatment is performed.