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    • 25. 发明专利
    • Paint composition
    • 涂料组合物
    • JPS5721464A
    • 1982-02-04
    • JP9719280
    • 1980-07-15
    • Nippon Paint Co Ltd
    • ISHII KEIZOUMIZUGUCHI RIYUUZOUISHIKURA SHINICHIKANDA KAZUNORI
    • C08F2/24C09D133/04C09D167/00
    • PURPOSE: An acrylic resin emulsion paint capable of forming a coat of a high crosslinking degree at a high curing rate, which is prep. by use of a specified polyester resin having an amphoteric group as an emulsifier.
      CONSTITUTION: A polyester resin of an acid value about 30W150 and a number- average MW about 500W5,000 having an amino sulfonic acid-type amphateric ion group of the formula [wherein A is 1W6C straight-chain or branched alkylene or (substd) phemylene] is used as an emulsifier. Namely, an α,β-unsaturated monomer such as (meth) acrylic or crotonic acid is emulsion-polymerized in an aq. medium by use of said polyester resin as an emulsifier. Is is adequate to use about 0.5W200pts. of the emulsifier for 100pts. of the monomer.
      COPYRIGHT: (C)1982,JPO&Japio
    • 目的:一种能够以高固化速度形成高交联度的涂层的丙烯酸树脂乳液漆,其为制备。 通过使用具有两性基团的特定的聚酯树脂作为乳化剂。 组成:酸值约30-150,数均分子量约500-5,000的聚酯树脂具有下式的氨基磺酸型立体离子基团[其中A为1-6C直链或支链亚烷基或 (subd)聚亚甲基]用作乳化剂。 即,α,β-不饱和单体如(甲基)丙烯酸或巴豆酸在水溶液中进行乳液聚合。 通过使用所述聚酯树脂作为乳化剂。 是否足够使用约0.5-200pts。 的乳化剂为100pts。 的单体。
    • 26. 发明专利
    • Acrylic resin emulsion and production thereof
    • 丙烯酸树脂乳液及其生产
    • JPS5721446A
    • 1982-02-04
    • JP9719080
    • 1980-07-15
    • Nippon Paint Co Ltd
    • ISHII KEIZOUMIZUGUCHI RIYUUZOUISHIKURA SHINICHIKANDA KAZUNORI
    • C08F2/00C08F2/24C08F2/44C08F20/00C08L33/00C08L33/02C08L33/04C08L35/00C08L67/00
    • PURPOSE: To obtain an acrylic resin emulsion in which polymer particles are uniformly emulsified, by emulsion-polymerizing an α,β-unsaturated monomer in an aq. medium by using a resin having an aminosulfonic acid type amphoteric ion group as an emulsifying agent.
      CONSTITUTION: An α,β-unsaturated monomer is emulsion-polymerized in the presence of a polymn. initiator and in an aq. medium by using a polyester resin having an aminosulfonic acid type amphoteric ion group of the formula (wherein A is a 1W6C straight or branched chain alkylene, phenylene, substituted phenylene) in the molecule as an emulsifying agent. Usually, the polyester resin is used in an amount of 0.5W200pts.wt. per 100pts.wt. said α,β-unsaturated monomer. When the amount is less than 0.5pts.wt., a large amount of agglomerates is formed during synthesis. Even when the amount exceeds 200pts.wt., an additional effect can not be obtd. Usually, the amount of nonvolatile matter in the emulsion produced should be not more than 60wt%.
      COPYRIGHT: (C)1982,JPO&Japio
    • 目的:为了获得其中聚合物颗粒均匀乳化的丙烯酸树脂乳液,通过将α,β-不饱和单体在水溶液中乳液聚合。 通过使用具有氨基磺酸型两性离子基团的树脂作为乳化剂的培养基。 构成:在聚合物存在下,将α,β-不饱和单体进行乳液聚合。 发起者和在一个水平。 通过使用具有式(其中A为1-6C直链或支链亚烷基,亚苯基,取代亚苯基)的氨基磺酸型两性离子基团的聚酯树脂作为乳化剂。 通常,聚酯树脂的用量为0.5-200pts.wt。 每100pts.wt 所述α,β-不饱和单体。 当该量小于0.5pts.wt.时,在合成过程中形成大量附聚物。 即使超过200pts.wt。,也不能说有额外的效果。 通常,乳液中不挥发成分的含量应不超过60wt%。