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21. 发明专利

JP2011231292A Method for producing nonpolar-polar olefin copolymer, and nonpolar-polar olefin copolymer 有权
标题翻译：生产非极性烯烃共聚物的方法和非极性烯烃共聚物
公开(公告)号：JP2011231292A
公开(公告)日：2011-11-17
申请号：JP2010105448
申请日：2010-04-30
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： IWASHITA AKIHIKO , MATSUKI TOMOAKI , TERAO HIROSHI , ISHII SEIICHI
IPC分类号： C08F4/645 , C08F210/00
摘要： PROBLEM TO BE SOLVED: To provide a nonpolar-polar olefin copolymer exhibiting excellent properties; and to provide a method for producing the same under a mild polymerization condition and at a high efficiency.SOLUTION: The production method of a nonpolar-polar olefin copolymer includes copolymerizing a nonpolar olefin and a polar olefin in the presence of a catalyst for olefin polymerization comprising a transition metal compound (A) represented by formula (I), and at least one compound (B) selected from the group consisting of organometal compounds, organoaluminumoxy compounds, and compounds to react with the transition metal compound (A) to form an ion pair.
摘要翻译：要解决的问题：提供显示出优异性能的非极性极性烯烃共聚物; 并提供在温和聚合条件下和高效率下制备该方法。解决方案：非极性极性烯烃共聚物的制备方法包括在包含由式（I）表示的过渡金属化合物（A）的烯烃聚合催化剂存在下，使非极性烯烃和极性烯烃共聚，至少一种选自有机金属化合物，有机铝氧化合物和与过渡金属化合物（A）反应以形成离子对的化合物的化合物（B）。版权所有（C）2012，JPO＆INPIT

22. 发明专利

JP2011122145A Olefin polymerization catalyst and method for producing olefin polymer 有权
标题翻译：烯烃聚合催化剂和生产烯烃聚合物的方法
公开(公告)号：JP2011122145A
公开(公告)日：2011-06-23
申请号：JP2010253870
申请日：2010-11-12
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： SAITO HARUKA , TERAO HIROSHI , KONO HIROSHI , IWASHITA AKIHIKO
IPC分类号： C08F4/649 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To provide an olefin polymerization catalyst having high polymerization activity and high copolymerizability for an olefin to produce a polymer with a high molecular weight. SOLUTION: The olefin polymerization catalyst includes a transition metal compound (A) represented by formula (I) (wherein M represents a transition metal atom of group 4-6 in a periodic table, m represents an integer of 1-4, n is a number satisfying a valence of M, X represents a hydrogen atom, a halogen atom or the like, R 1 represents a 6-30C substituted or unsubstituted aryl group, R 2 , R 3 , R 4 and R 5 represent a hydrogen atom, a halogen atom, a hydrocarbon group or the like, and R 6 represents an iodine atom or a bromine atom). COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种具有高聚合活性和对烯烃具有高共聚性的烯烃聚合催化剂，以生产具有高分子量的聚合物。解决方案：烯烃聚合催化剂包括由式（I）表示的过渡金属化合物（A）（其中M表示周期表中第4-6族的过渡金属原子，m表示1-4的整数， n是满足M价的数，X表示氢原子，卤素原子等，R 1表示6-30C取代或未取代的芳基，R 2， SP>，R 3 ，R 4 和R 5 表示氢原子，卤素原子，烃基等，R 6 表示碘原子或溴原子。版权所有（C）2011，JPO＆INPIT

23. 发明专利

JP2010241930A Olefin copolymer and process for producing the same 审中-公开
标题翻译：烯烃共聚物及其生产方法
公开(公告)号：JP2010241930A
公开(公告)日：2010-10-28
申请号：JP2009091226
申请日：2009-04-03
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： TERAO HIROSHI , IWASHITA AKIHIKO , MIYAKE ATSUKO
IPC分类号： C08F210/00 , C08F4/645 , C08F212/14
摘要： PROBLEM TO BE SOLVED: To provide a nonpolar/polar olefin copolymer exhibiting excellent properties which the conventional olefin copolymers do not possess, and to provide a process for producing the same at high efficiency under mild polymerization conditions. SOLUTION: The nonpolar/polar olefin copolymer is obtained by copolymerization of a nonpolar olefin and a polar olefin represented by the general formula (I), wherein p represents an integer of 0-30; R 11 -R 15 is selected from a hydrogen atom, a halogen atom, a hydrocarbon group, a heterocyclic compound residue, an oxygen-containing group, a nitrogen-containing group, a boron-containing group, a sulfur-containing group, a phosphorus-containing group, a silicon-containing group, a germanium-containing group, and a tin-containing group, wherein at least one of R 11 -R 15 are halogen atoms, or groups containing one or more halogen atoms, oxygen atoms, nitrogen atoms, boron atoms, sulfur atoms, phosphorus atoms, silicon atoms, germanium atoms, and tin atoms. COPYRIGHT: (C)2011,JPO&INPIT
摘要翻译：要解决的问题：提供一种显示出传统烯烃共聚物不具有的优异性能的非极性/极性烯烃共聚物，并提供一种在温和聚合条件下以高效率生产该方法。解决方案：非极性/极性烯烃共聚物通过非极性烯烃和由通式（I）表示的极性烯烃的共聚获得，其中p表示0-30的整数; R 11选自氢原子，卤素原子，烃基，杂环化合物残基，含氧基团，含氮基团，含硼基团，含硫基团，含磷基团，含硅基团，含锗基团和含锡基团中的至少一个，其中R 11，或者含有一个或多个卤素原子，氧原子，氮原子，硼原子，硫原子，磷原子，硅原子，锗原子和锡原子的卤原子或基团。版权所有（C）2011，JPO＆INPIT

24. 发明专利

JP2006265541A Method for polymerizing olefin and polymer obtained thereby 有权
标题翻译：用于聚合烯烃和获得的聚合物的方法
公开(公告)号：JP2006265541A
公开(公告)日：2006-10-05
申请号：JP2006046299
申请日：2006-02-23
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： TERAO HIROSHI , ISHII SEIICHI , MITANI MAKOTO , FUJITA TERUNORI
IPC分类号： C08F4/64 , C08F4/68 , C08F210/00
摘要： PROBLEM TO BE SOLVED: To provide a method for efficiently producing a polar olefin copolymer excellent in property, wherein the polar olefin exerts an excellent copolymerizability. SOLUTION: A non-polar olefin is copolymerized with the polar olefin in the presence of an olefin polymerization catalyst comprising a transition metal compound represented by formula (I) (wherein M is a group 4 or 5 transition metal atom; m is an integer of 1-4; n is a number satisfying the valency of M; and X is a hydrogen atom, a halogen atom or the like) and at least one compound chosen from the group consisting of an organometallic compound, an organoaluminum oxy compound and a compound which reacts with the transition metal compound and forms an ion pair. COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种有效制备性能优异的极性烯烃共聚物的方法，其中极性烯烃具有优异的共聚性。解决方案：在包含由式（I）表示的过渡金属化合物的烯烃聚合催化剂存在下，将非极性烯烃与极性烯烃共聚合（其中M为4或5族过渡金属原子; m为 1-4的整数; n是满足M的化合价的数; X是氢原子，卤素原子等）和至少一种选自有机金属化合物，有机铝氧化合物和与过渡金属化合物反应形成离子对的化合物。版权所有（C）2007，JPO＆INPIT

25. 发明专利

JP2005002086A Transition metal compound and olefin polymerization catalyst containing the same 审中-公开
标题翻译：过渡金属化合物和含烯烃聚合催化剂
公开(公告)号：JP2005002086A
公开(公告)日：2005-01-06
申请号：JP2003322177
申请日：2003-09-12
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： MATSUURA SADAHIKO , MATSUKAWA NAOTO , TERAO HIROSHI , MITANI MAKOTO , SAITO JUNJI , FUJITA TERUNORI
IPC分类号： C07C251/24 , C07F11/00 , C08F4/64 , C08F4/659
摘要： PROBLEM TO BE SOLVED: To provide an olefin polymerization catalyst for producing a polyolefin in high catalytic activity. SOLUTION: The transition metal compound is expressed by general formula (I) (M is a transition metal atom of group 4 or 5 of the periodic table; m is an integer of 1-4; R 1α is expressed by general formula (II) or general formula (III); R 2 to R 6 are each H, a halogen atom, a hydrocarbon group or the like; n is a number satisfying the valence of M; and X is H, a halogen atom, a hydrocarbon group or the like). In the general formula (II) or (III), R a is H, an aliphatic hydrocarbon group or an alicyclic hydrocarbon group; R b and R c are each independently H or methyl; and the dotted line shows the direct bond between two C β atoms or a bond connecting two C β atoms through a ≥1C hydrocarbon group. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：待解决的问题：提供一种生产具有高催化活性的聚烯烃的烯烃聚合催化剂。过渡金属化合物由通式（I）表示（M为周期表第4或5族的过渡金属原子; m为1-4的整数; R为1〜 SP>由通式（II）或通式（III）表示; R 2至R 6中的每一个均为H，卤素原子，烃基等 ; n为满足M价的数; X为H，卤原子，烃基等）。在通式（II）或（III）中，R SB为a，脂族烃基或脂环族烃基; R SB和R SB各自独立地为H或甲基; 虚线表示两个C β原子之间的直接键或通过≥1C烃基连接两个C β原子的键。版权所有（C）2005，JPO＆NCIPI

26. 发明专利

JP2004331965A Catalyst for olefin polymerization and process for producing olefin polymer 审中-公开
公开(公告)号：JP2004331965A
公开(公告)日：2004-11-25
申请号：JP2004121276
申请日：2004-04-16
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： TERAO HIROSHI , YOSHIDA IKUNORI , MORI JUNICHI , ISHII SEIICHI , MITANI MAKOTO , FUJITA TERUNORI
IPC分类号： C08F210/00 , C08F4/625 , C08F4/639 , C08F232/00
摘要： PROBLEM TO BE SOLVED: To provide a catalyst for olefin polymerization effectively incorporating a cycloolefin, a conjugated polyene or an aromatic vinyl compound, and exhibiting a high polymerization activity, and to provide a method for production of olefin copolymer by using the same.
SOLUTION: The method comprises a (co)polymerization of at least one kind of monomers (C) selected from an α-olefin, the cycloolefin, the conjugated polyene and the aromatic vinyl compound, in the presence of the catalyst for olefin polymerization comprising (A) a specific transition metal compound and (B-1) an organometallic compound, (B-2) an organic aluminumoxy compound and (B-3) a compound forming an ion pair by reacting with the transition metal compound (A).
COPYRIGHT: (C)2005,JPO&NCIPI

27. 发明专利

JP2004002641A Catalyst for olefin polymerization and method for olefin polymerization 审中-公开
公开(公告)号：JP2004002641A
公开(公告)日：2004-01-08
申请号：JP2002311686
申请日：2002-10-25
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： FURUYAMA RIEKO , MORI JUNICHI , TSURU KAZUTAKA , ISHII SEIICHI , TERAO HIROSHI , MITANI MAKOTO , FUJITA TERUNORI
IPC分类号： C08F4/64 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To obtain a catalyst for olefin polymerization, which has excellent olefin polymerization activity and forms high-molecular-weight polymer or a catalyst for olefin polymerization, which exhibits high stereoselectivity in α-olefin polymerization. SOLUTION: The catalyst for olefin polymerization comprises a transition metal compound represented by general formula (I) (M is a titanium atom; m is an integer of 1-2; R 1 is a 1-30C fluorine-containing hydrocarbon group; R 2 -R 5 may be mutually the same or different, a hydrocarbon group, a hydrogen atom or the like and two or more of R 2 -R 5 may be mutually bonded to form a ring; R 6 is a silyl group or a hydrocarbon-substituted silyl group; when m is 2, two groups of R 2 -R 6 may be bonded; n is a number satisfying the valence of M; X is a hydrogen atom, a halogen atom or the like). COPYRIGHT: (C)2004,JPO

28. 发明专利

JP2004002640A Catalyst for olefin polymerization and method for olefin polymerization 有权
公开(公告)号：JP2004002640A
公开(公告)日：2004-01-08
申请号：JP2002311685
申请日：2002-10-25
申请人： Mitsui Chemicals Inc , 三井化学株式会社
发明人： FURUYAMA RIEKO , MORI JUNICHI , TSURU KAZUTAKA , ISHII SEIICHI , TERAO HIROSHI , MITANI MAKOTO , FUJITA TERUNORI
IPC分类号： C07C251/24 , C07F7/28 , C08F4/64 , C08F10/00
摘要： PROBLEM TO BE SOLVED: To obtain a catalyst for olefin polymerization, which has excellent olefin polymerization activity and forms a high-molecular-weight polymer, a catalyst for olefin polymerization, which exhibits high activity in α-olefin polymerization or a catalyst for olefin polymerization, which forms a copolymer having a high α-olefin content in ethylene/α-olefin copolymerization. SOLUTION: The catalyst for olefin polymerization comprises a transition metal compound represented by formula (I). COPYRIGHT: (C)2004,JPO

29. 发明专利

JP2000313788A EPOXY RESIN COMPOSITION FOR SEMICONDUCTOR SEALING USE 失效
公开(公告)号：JP2000313788A
公开(公告)日：2000-11-14
申请号：JP12221599
申请日：1999-04-28
申请人： YAMAMOTO CHEMICALS INC , MITSUI CHEMICALS INC
发明人： CHICHIWA KEIKI , TERAO HIROSHI , HARADA HIROAKI , EDA TSUNETO , KUMAGAI YOJIRO
IPC分类号： C08K5/34 , C08L63/00 , H01L23/29 , H01L23/31
摘要： PROBLEM TO BE SOLVED: To obtain the subject composition with the high ability to absorb YAG laser beams, excellent in YAG laser marking ability and useful as an epoxy resin for sealing semiconductor devices by formulating an epoxy resin with a phthalocyanine compound. SOLUTION: This composition is obtained by formulating an epoxy resin (e.g. bisphenol A-type one) with pref. 0.5-3 wt.% of a phthalocyanine compound of the formula (R is an alkyl or alkoxyalkyl; X is a halogen, alkylthio or the like; M is two hydrogen atoms or a bivalent to tetravalent metal derivative) which is prepared by reaction between a diiminoisoindolin compound and a metal or its derivative (e.g. Cu) at 100-300 deg.C in an organic solvent with a boiling point of pref. >=130 deg.C.

30. 发明专利

JPH1160579A PYRROLIDINOPHENOTHIAZINE COMPOUND, ITS PRODUCTION, AND PRODUCTION OF PHTHALOCYANINE COMPOUND BY USING THE SAME 失效
公开(公告)号：JPH1160579A
公开(公告)日：1999-03-02
申请号：JP26519197
申请日：1997-08-19
申请人： YAMAMOTO CHEMICALS INC , MITSUI CHEMICALS INC
发明人： FUJITA SHIGEO , MASAOKA TOSHIHIRO , TERAO HIROSHI , TANIGUCHI JUNICHI , KUMAGAI YOJIRO
IPC分类号： C07D513/04 , B01J31/02 , C07B61/00 , C07D513/22 , C09B47/04 , C09B47/067 , C09K3/00
摘要： PROBLEM TO BE SOLVED: To obtain the subject new compound excellent in absorptivity of near infrared rays, and useful as an intermediate for a phthalocyanine compound. SOLUTION: The objective compound is a pyrrolidinophenothiazine compound of formula I (R1 and R2 are each an alkyl or an alkoxyalkyl; R3 is H or an alkyl), e.g. 1,3-diimino-4,11-di-iso-pentoxypyrro1idino[3,4-b]phenothiazine. The compound of formula I is obtained by reacting a dinitrile of formula II (e.g. 1,4-di-iso-pentoxy-2,3-dicyanophenothiazine) with 1-20 mol ammonia based on 1 mol dinitrile in the presence of 0.01-5 mol metal alkoxide of the formula R4 O-X (R4 is an alkyl or an alkoxyalkyl; X is Na or Ca), (e.g. a reaction product of metal sodium) and 200 mlL-15 L alcoholic solvent (e.g. methanol) based on 1 mol dinitrile at a temperature from 0 deg.C to a reflux temperature of the solvent for 30 min to 72 hr.

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