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    • 25. 发明专利
    • SEAWATER CORROSION RESISTING AL-MN ALLOY THERMALLY SPRAYED STEEL STOCK
    • JPH0375351A
    • 1991-03-29
    • JP21035589
    • 1989-08-15
    • SUMITOMO METAL IND
    • YAMAMOTO YASUHIROTSUDA TETSUAKIUCHIDA JUNICHISETO HIROHISA
    • C23C4/08C22C21/00
    • PURPOSE:To obtain a seawater corrosion resisting Al-Mn thermally sprayed steel stock having high corrosion resistance and long-term stability in a seawater atmosphere and also excellent in design characteristics by forming, by thermal spraying, an Al-Mn alloy coating layer on the surface of a steel stock and further subjecting the resulting thermally sprayed layer to sealing treatment. CONSTITUTION:The surface of a steel stock for use in a highly corrosive atmosphere, such as seawater atmosphere, is subjected to descaling and surface roughening treatments by means of shot blasting treatment, etc. Subsequently, an Al-Mn alloy containing 1-40wt.% Mn is thermally sprayed on the above surface by means of plasma spraying, etc. Then, the above steel stock having the resulting thermally sprayed layer of Al-Mn alloy is immersed into a treatment solution of sulfuric acid, phosphoric acid, etc., and subjected to anodic oxidation treatment to undergo the formation of colored anodic oxidation film, and then, fine pores in the anodic oxidation film are sealed by means of vapor sealing, epoxy resin, water glass, etc. By this method, the Al-Mn alloy thermally sprayed steel stock having design characteristics and excellent in corrosion resistance and stability to seawater can be obtained.
    • 26. 发明专利
    • METHOD FOR REVEALING GRAIN BOUNDARY OF GAMMA-STAINLESS STEEL
    • JPH0270075A
    • 1990-03-08
    • JP21927888
    • 1988-09-01
    • SUMITOMO METAL IND
    • YAMAMOTO YASUHIROYAMAZAKI AKIHIKO
    • C23C8/18C23F1/00C23F1/28G01N1/32
    • PURPOSE:To distinctly reveal the gamma-grain boundary by polishing the surface of a gamma-stainless steel, carburizing the steel under a specified condition, then again polishing the steel, and dip-etching the steel with a liq. etchant capable of preferentially etching the grain boundary and having a low etching rate. CONSTITUTION:The surface of a sample gamma-stainless steel is buffed to facilitate the infiltration of C in carburization. The sample is then carburized at 550-925 deg.C for 6hr, and C is forcedly infiltrated into the grain boundary in the temp. region where recrystallization is not caused to impart C segregation. The sample is then again buffed to the extent that the carburized region is not removed. The sample is subsequently dip-etched with a liq. etchant capable of preferentially etching the grain boundary. An etchant consisting of about 5cc of hydrochloric acid, about 1g of picric acid, about 100cc of alcohol, and about 2cc of a surfactant and having a low etching rate is appropriately used as the etchant. By this method, gamma-grain boundary is distinctly revealed and the mechanical characteristics of stainless steel can be clarified.