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    • 27. 发明专利
    • MULTILAYER CERAMIC CAPACITOR, TERMINAL ELECTRODE PASTE AND FORMATION OF TERMINAL ELECTRODE
    • JPH04113608A
    • 1992-04-15
    • JP23361190
    • 1990-09-03
    • MATSUSHITA ELECTRIC IND CO LTD
    • YOKOYA YOICHIROANDO HAMAEKUGIMIYA KOICHI
    • H01G4/12H01G4/008H01G4/232H01G4/252H01G4/30
    • PURPOSE:To make solderability good, to reduce a drop in solderability when the surface of an electrode is oxidized and to relax a thermal shock to an element at a soldering operation by a method wherein the cross section of a terminal electrode part is provided with the following: a substratum layer containing an inorganic frit; and an intermediate layer as well as a surface layer which are composed of the mixed texture phase of metal phases at a specific composition. CONSTITUTION:The cross section of a terminal electrode part for a multilayer ceramic capacitor is provided with the following: a substratum layer 12 which contains inorganic frits 18 bonded to a ceramic raw body partially; an intermediate layer 13 composed of a mixed phase 17 by a metal phase composed mainly of one kind selected from (a) silver as well as (b) lead, zinc and tin, by an intermetallic compound phase or by a solid solution alloy phase and by a nickel metal phase 16; and, in addition, a surface layer 14 in which the content of said (b) component as at least one kind selected from lead, tin and zinc is more than that of said intermediate layer as an average composition. As the composition ratio of metal components contained in an electrode paste, the total weight ratio of lead, zinc and tin components is at 0.5wt.% or higher and 45wt.% or lower and the weight ratio of a nickel component is at 3wt.% or higher and 25wt.% or lower.