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    • 22. 发明专利
    • Multilayered film for agriculture
    • 农业多层膜
    • JP2002370329A
    • 2002-12-24
    • JP2001183462
    • 2001-06-18
    • Mitsubishi Chem Mkv Co三菱化学エムケーブイ株式会社
    • YOKOYAMA KAZUHIKOYAMAGISHI HIROSHIKINOSHITA KAZUYAYOSHIMURA EMI
    • A01G13/02A01G9/14B32B27/28B32B27/32C08F210/16
    • Y02A40/252
    • PROBLEM TO BE SOLVED: To provide a film which exhibits good film appearance (transparency and see-through) and high balance of mechanical strength and ease of opening, and further, satisfies beam transmission property (dust proofness and haze-proof durability) during stretching over time. SOLUTION: This multilayered film of a polyolefin resin for agriculture comprises an outer layer and an inner layer of a film which are composed of a resin composition containing not less than 55 wt.% of an ethylene-α-olefin copolymer resin (A) with specified properties obtained by copolymerizing it with the help of a metallocene catalyst, an intermediate layer composed mainly of an ethylene/vinyl acetate copolymer resin with a vinyl acetate content of 5 to 25 wt.% and 2 to 25 wt.% of inorganic fine particle containing at least one atom selected from among Mg, Ca, Zn, Al, Si and Li. On the surface of the inner layer of this layered film of an at least three-tier construction, a haze-proof coating film composed mainly of a binder resin and an inorganic colloidal sol is formed.
    • 要解决的问题:提供具有良好的膜外观(透明性和透视性)以及高机械强度平衡和开放性的薄膜,并且还能满足拉伸期间的透光性(防尘性和防雾耐久性) 随着时间的推移。 解决方案:用于农业的聚烯烃树脂的多层膜包括外层和内层,该树脂组合物由含有不少于55重量%的乙烯-α-烯烃共聚物树脂(A)与 通过在金属茂催化剂的帮助下共聚获得的特定性能,主要由乙酸乙烯酯含量为5至25重量%的乙烯/乙酸乙烯酯共聚物树脂和2至25重量%的无机细颗粒组成的中间层 含有选自Mg,Ca,Zn,Al,Si和Li中的至少一种原子。 在至少三层结构的层状膜的内层的表面上,形成主要由粘合剂树脂和无机胶体溶胶构成的防雾涂膜。