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11. 发明专利

JP2009106822A Method of removing moisture from azeotropic mixture using siloxane coating zeolite-based adsorbent 审中-公开
标题翻译：使用硅氧烷涂层沸石基吸附剂从AZEOTROPIC混合物中除去水分的方法
公开(公告)号：JP2009106822A
公开(公告)日：2009-05-21
申请号：JP2007279828
申请日：2007-10-29
申请人： Kyuchaku Gijutsu Kogyo Kk , Nagasaki Univ , 吸着技術工業株式会社 , 国立大学法人長崎大学
发明人： MORIGUCHI ISAMU , IZUMI JUN , O KOKO
IPC分类号： B01D53/26 , B01D53/28 , B01J20/18
摘要： PROBLEM TO BE SOLVED: To enable easy preparing of another highly concentrated component by separating moisture from the other component in a gas phase and performing this method in the downstream side of the distillation process. SOLUTION: First, the vapor of a mixture containing water and a component (hereafter called "another component") which forms an azeotropic mixture with the water is pressurized and introduced into a moisture-selective-type adsorbent bed. After this procedure, the adsorbent is made to adsorb the moisture by bringing the vapor into contact with the adsorbent, and thus, the moisture is separated from the other component. Further, the supply of the mixture into the adsorbent bed is suspended and the moisture is made to leave the adsorbent bed by reducing the pressure of the moisture selective-type adsorbent bed which has adsorbed the moisture. Alternatively, the moisture is made to leave the adsorbent bed under atmospheric pressure or pressure reduction conditions using the other component as a finished product or an inert gas as a purge gas. The above procedures are taken by the moisture removing method represented by the pressure swing process of the other component and the moisture. The moisture selective-type adsorbent is one kind or more selected from the group consisting of K-A, Na-A, Na-K-A and Ca-A, to which silica coating is applied by liquid-phase hydrolysis or a gas-phase hydrolysis using siloxane as a silica source. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：为了容易地制备另一种高浓度组分，通过在气相中从其它组分分离水分，并在蒸馏过程的下游侧进行该方法。解决方案：首先，将与水和与水形成共沸混合物的组分（以下称为“另一组分”）的混合物的蒸气加压并引入到湿气选择性吸附剂床中。在该过程之后，通过使蒸气与吸附剂接触，使吸附剂吸附水分，从而将水分与其他成分分离。此外，将混合物供应到吸附剂床中，并通过降低吸附了水分的水分选择性吸附剂床的压力使水分离开吸附剂床。或者，使用作为成品或惰性气体的其它组分作为吹扫气体，在大气压或压力降低条件下使湿气离开吸附剂床。上述步骤由通过其他组分的压力摆动过程表示的除湿方法和水分进行。水分选择性吸附剂是选自由KA，Na-A，Na-KA和Ca-A组成的组中的一种或多种，其中通过液相水解或使用硅氧烷的气相水解施用二氧化硅涂层作为二氧化硅源。版权所有（C）2009，JPO＆INPIT

12. 发明专利

JP2009082785A Method and apparatus for treating gas containing harmful substance 审中-公开
标题翻译：用于处理含有有害物质的气体的方法和装置
公开(公告)号：JP2009082785A
公开(公告)日：2009-04-23
申请号：JP2007253300
申请日：2007-09-28
申请人： Kyuchaku Gijutsu Kogyo Kk , 吸着技術工業株式会社
发明人： IZUMI JUN , O KOKO
IPC分类号： B01D53/70 , A61L9/01 , A61L9/015 , A61L9/16 , A62D3/38 , A62D101/22 , A62D101/28 , B01D53/48 , B01D53/52 , B01D53/66 , B01D53/72 , B01J20/10 , B01J20/18
CPC分类号： Y02A50/2347
摘要： PROBLEM TO BE SOLVED: To provide a method and an apparatus for treating a gas containing harmful substances such as organic contaminants, odorous components, and bacteria to make them harmless having an improved efficiency of making them harmless achieved particularly by virtue of ozone.
SOLUTION: The method for treating harmful substances contained in a gas to make them harmless by virtue of ozone comprises adding and mixing ozone to and with a gas comprising harmful substances, and causing the mixed gas to pass through a layer filled with at least one species of adsorbents capable of adsorbing ozone and the harmful substances selected from the group consisting of a high-silica zeolite doped with boron, high-silica mesoporous silica doped with boron, and a hydrothermally synthesized high-silica zeolite doped with boron. The apparatus for treating harmful substances in a gas to make them harmless comprising an adsorbent-packed column 6 provided with the layer 6a of the adsorbent(s), a feed pipe for feeding the gas to the adsorbent-packed column 6, an ozone generator 5 in communication with the feed pipe for generating ozone and adding it to the gas, and a discharge pipe 7 for discharging the treated gas, is characterized by further comprising an ozone decomposer layer 6b for decomposing leaking ozone disposed downstream of the adsorbent-packed column 6.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于处理含有有害物质如有机污染物，气味成分和细菌的气体以使其无害化的方法和装置，使得其具有提高的使其无害化的效率，特别是凭借臭氧。解决方案：用于处理气体中含有的有害物质以通过臭氧使其无害化的方法包括将臭氧与包含有害物质的气体相加并混合，并使混合气体通过填充在能够吸附臭氧的至少一种吸附剂和选自掺杂硼的高二氧化硅沸石，掺杂有硼的高二氧化硅介孔二氧化硅和掺杂有硼的水热合成高硅石沸石组成的组中的有害物质。用于处理气体中的有害物质使其无害的装置包括设置有吸附剂层6a的吸附剂填充塔6，用于将气体供给到吸附剂填充塔6的进料管，臭氧发生器与用于产生臭氧的进料管连通并将其添加到气体中，以及用于排出处理气体的排出管7的特征在于还包括臭氧分解器层6b，用于分解设置在吸附剂填充塔的下游的泄漏臭氧 6.版权所有（C）2009，JPO＆INPIT

13. 发明专利

JP2008055386A Method for removing moisture from component forming azeotrope by making use of adsorbent 有权
标题翻译：通过使用吸附剂除去形成AZEOOPOPE的组分的水分的方法
公开(公告)号：JP2008055386A
公开(公告)日：2008-03-13
申请号：JP2006238526
申请日：2006-09-04
申请人： Kyuchaku Gijutsu Kogyo Kk , 吸着技術工業株式会社
发明人： IZUMI JUN , O KOKO
IPC分类号： B01D53/26 , B01D53/02 , B01D53/04 , B01J20/18 , B01J20/34
摘要： PROBLEM TO BE SOLVED: To provide a method for removing moisture from a component forming an azeotrope by making use of an adsorbent. SOLUTION: The method for removing moisture by a pressure swing process of moisture and the component forming an azeotrope together with water (hereinafter, referred to as other component) is conducted by pressurizing vapor of a mixture containing water and the other component, introducing it to an adsorbent bed having selectivity for moisture to separate moisture from the other component by adsorbing moisture with the adsorbent and then discontinuing to supply the mixture to the adsorbent bed and desorbing the moisture from the adsorbent bed by depressurizing the adsorbent bed having selectivity for moisture that has adsorbed moisture or by using the product other component or an inert gas as a purge gas under atmospheric or reduced pressure. The adsorbent having selectivity for moisture is at least one kind selected from the group consisting of K-A, Na-A, Na-K-A and Ca-A. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供通过利用吸附剂从形成共沸物的成分除去水分的方法。解决方案：通过对水分的压力摆动过程除去水分和与水一起形成共沸物的组分（以下称为其它组分）的方法通过对含有水和其它组分的混合物的蒸汽进行加压来进行，将其引入到具有选择性的吸湿剂床上，通过与吸附剂吸湿来分离水分与其它组分，然后停止将混合物供给到吸附剂床中，并通过减压吸附床的吸附剂床，使其具有选择性在大气压或减压下吸收了水分的水分或者使用其它成分或惰性气体作为吹扫气体的水分。具有水分选择性的吸附剂是选自K-A，Na-A，Na-K-A和Ca-A中的至少一种。版权所有（C）2008，JPO＆INPIT

14. 发明专利

JP2013198845A Smoothing method of easily-adsorbable component concentration and apparatus 有权
标题翻译：易吸收组分浓度和装置的平滑方法
公开(公告)号：JP2013198845A
公开(公告)日：2013-10-03
申请号：JP2012067547
申请日：2012-03-23
申请人： Kyuchaku Gijutsu Kogyo Kk , 吸着技術工業株式会社
发明人： IZUMI JUN
IPC分类号： B01D53/72 , B01D53/02
摘要： PROBLEM TO BE SOLVED: To provide: a method concerning smoothing of an easily-adsorbable component concentration variation by an adsorption method that smoothens concentration variation by high efficiency by using an easily-adsorbable component adsorbent for a fluid that contains the easily-adsorbable component with concentration variation; and an apparatus.SOLUTION: A smoothing method of an easily-adsorbable component concentration comprises as follows. When a fluid that contains an easily-adsorbable component and in which a concentration varies is supplied to an adsorption column, the fluid is supplied to the adsorption column that fills the easily-adsorbable component, a flow direction cross-section of the adsorption column is divided into at least two, filling of the easily-adsorbable component of a flow direction of each cross-section is made to be a different filling amount, and a difference is made to arise in a residence time of the easily-adsorbable component of each cross-section, and thereby fluctuation of a concentration of the easily-adsorbable component of the fluid at an adsorption column outlet is smoothened. In addition, an apparatus of the smoothing method is disclosed.
摘要翻译：要解决的问题：提供一种通过使用容易吸附的成分吸附剂对含有易吸附成分的流体进行吸附的方法，其通过高效率使浓度变化平滑化的容易吸附成分浓度变化的方法，浓度变化; 和装置。解决方案：易吸附组分浓度的平滑方法如下。当含有易吸附成分并且浓度变化的流体被供给到吸附塔时，将流体供给到填充易吸附组分的吸附塔，吸附塔的流动方向横截面为分为至少两个，将每个横截面的流动方向的容易吸附组分的填充量设定为不同的填充量，并且在每个横截面的容易吸附组分的停留时间上出现差异使吸附塔出口处的流体的容易吸附成分的浓度的波动变平滑。此外，公开了一种平滑方法的装置。

15. 发明专利

JP2013154340A Method and apparatus for adsorption separation of oxygen and nitrogen from air 审中-公开
标题翻译：从空气中分离氧气和氮气的方法和装置
公开(公告)号：JP2013154340A
公开(公告)日：2013-08-15
申请号：JP2012095453
申请日：2012-04-19
申请人： Kyuchaku Gijutsu Kogyo Kk , 吸着技術工業株式会社
发明人： IZUMI JUN
IPC分类号： B01D53/04 , B01D53/26 , B01J20/18 , B01J20/34 , C01B13/02
CPC分类号： Y02C10/08
摘要： PROBLEM TO BE SOLVED: To provide a method and an apparatus for separating oxygen and nitrogen, which are used in oxygen-enriched combustion, an environmental apparatus and a chemical apparatus, from air by a compact and highly effective adsorption method at a low cost in regard to a method and an apparatus for generating small and medium-sized capacity of oxygen of about 1 to 100 mN/h.SOLUTION: There is provided a method and an apparatus for producing oxygen of one tower pressure swing system, in which moist air is supplied with high pressure equal to or higher than atmospheric pressure, and nitrogen, moisture, COor the like are removed and further oxygen is recovered from the back of the tower (a nitrogen adsorption process). Before oxygen concentration decreases, the front of an auxiliary adsorption tower which is installed at the back of the tower and is filled with a nitrogen adsorbent is joined with the back of a nitrogen adsorption tower. Oxygen remaining at the back of the tower is moved to the auxiliary adsorption tower (an oxygen recovering process). After finish of a vacuum reproduction process, the back of the nitrogen adsorption tower of atmospheric pressure is joined with the front of the auxiliary adsorption tower and recovered oxygen is supplied from the back of the nitrogen adsorption tower to increase pressure in the nitrogen adsorption tower.
摘要翻译：要解决的问题：提供一种通过紧凑且高效吸附方法以低成本从空气中分离用于富氧燃烧中的氧和氮的方法和装置，环境装置和化学装置关于产生约1〜100mN / h的中小容量氧气的方法和装置。解决方案：提供一种塔式压力摆动系统的氧气生产方法和装置，其中湿空气被供给等于或高于大气压的高压，并且除去氮，水分等等，并且从塔的后部回收另外的氧（氮吸附过程）。在氧气浓度降低之前，安装在塔背部并填充有氮气吸附剂的辅助吸附塔的前部与氮气吸附塔的背面接合。将塔背面残留的氧气移至辅助吸附塔（氧气回收过程）。真空再生过程完成后，大气压氮吸附塔的背面与辅助吸附塔的前面连接，从氮吸附塔的后面提供回收的氧气，以增加氮吸附塔的压力。

16. 发明专利

JP2013040077A Ozone/oxygen separation method and apparatus using adsorbent 审中-公开
标题翻译：臭氧/氧气分离方法和使用吸附剂的装置
公开(公告)号：JP2013040077A
公开(公告)日：2013-02-28
申请号：JP2011178329
申请日：2011-08-17
申请人： Kyuchaku Gijutsu Kogyo Kk , 吸着技術工業株式会社
发明人： IZUMI JUN , O KOKO
IPC分类号： C01B13/10 , B01D53/02 , B01D53/04 , B01J20/18
摘要： PROBLEM TO BE SOLVED: To produce an ozone-containing gas at a low cost by performing ozone/oxygen separation by PSA using an ozone adsorbent; recovering separated oxygen and reusing it as raw material oxygen for an ozonizer; and desorbing and recovering adsorbed ozone with dry air.SOLUTION: In a method for producing an ozone-air two-component gas, an ozone-oxygen two-component gas produced in an ozonizer using oxygen as a raw material is introduced into an ozone adsorbent adsorption column; ozone is adsorbed on the adsorbent; passed oxygen is recovered and reused as raw material oxygen; dry air is introduced as a countercurrent flowing purge gas into the adsorbent bed; and ozone is desorbed and recovered as the objective ozone-air two-component gas. As the ozone adsorbent, at least one selected from (1) a pentasil-type zeolite containing 0.5-1.25 wt.% (expressed in terms of phosphorus) of phosphoric acid, (2) a pentasil-type zeolite containing 0.5-1.25 wt.% (expressed in terms of boron) of boric acid, and (3) a pentasil-type zeolite containing 0.5-1.25 wt.% of chlorine is used.
摘要翻译：要解决的问题：通过使用臭氧吸附剂通过PSA进行臭氧/氧气分离来以低成本生产含臭氧气体; 回收分离的氧气并将其用作臭氧发生器的原料氧气; 并用干燥空气解吸和回收吸附的臭氧。解决方案：在臭氧气体双组分气体的制造方法中，将以氧为原料的臭氧发生器中产生的臭氧 - 二氧化碳气体引入臭氧吸附剂吸附塔中; 臭氧吸附在吸附剂上; 通过氧气回收再利用为原料氧气; 将干燥空气作为逆流流动的吹扫气体引入吸附床; 臭氧作为目标的臭氧 - 空气双组分气体解吸和回收。作为臭氧吸附剂，选自（1）含有0.5-1.25重量％（以磷表示）的磷酸的五硅烷型沸石中的至少一种，（2）含有0.5-1.25重量％使用硼酸的％（以硼表示），（3）使用含有0.5-1.25重量％氯的pentasil型沸石。版权所有（C）2013，JPO＆INPIT

17. 发明专利

JP2009297629A Hazardous component-containing liquid treatment method and apparatus 审中-公开
标题翻译：包含有害成分的液体处理方法和装置
公开(公告)号：JP2009297629A
公开(公告)日：2009-12-24
申请号：JP2008153671
申请日：2008-06-12
申请人： Kyuchaku Gijutsu Kogyo Kk , 吸着技術工業株式会社
发明人： IZUMI JUN , O KOKO
IPC分类号： C02F1/72 , B01J20/10 , B01J20/18 , B01J20/34 , C01B37/02 , C02F1/28 , C02F1/32 , C02F1/78
摘要： PROBLEM TO BE SOLVED: To provide a method and an apparatus for detoxifying a liquid containing hazardous components, such as various organic pollutants, offensive odor components, and bacteria.
SOLUTION: In the hazardous component-containing liquid treatment method and apparatus, (A) a water-soluble oxidizing agent or fine ozone bubbles are added to and mixed with the hazardous component-containing liquid, and (B) under a condition of ultraviolet irradiation, (C) the hazardous component-containing liquid is made to flow through a packed tower filled with at least one kind of adsorbent selected from the group of (1) pentasil zeolite, (2) zeolite β, (3) ultrastable Y zeolite (USY), (4) mesoporous silicate, (5) ultrastable mordenite (USM), and (6) silica gel which adsorb the water-soluble oxidizing agent or the ozone, and adsorb the hazardous components, (D) to detoxify the hazardous components in the liquid by the effect of adsorption reaction with the water-soluble oxidizing agent or the ozone.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种含有各种有机污染物，恶臭成分，细菌等有害成分的液体的解毒方法和装置。解决方案：在含有危险成分的液体处理方法和装置中，（A）将水溶性氧化剂或细小臭氧气体加入含有危险成分的液体中并与其混合，（B）在条件的紫外线照射，（C）含有危险成分的液体流过填充有至少一种吸附剂的填充塔，所述吸附剂选自（1）pentasil沸石，（2）沸石β，（3）超稳定 Y沸石（USY），（4）介孔硅酸盐，（5）超稳定丝光沸石（USM）和（6）吸附水溶性氧化剂或臭氧并吸附有害成分的硅胶，（D）通过与水溶性氧化剂或臭氧的吸附反应的作用，液体中的有害成分。版权所有（C）2010，JPO＆INPIT

18. 发明专利

JP2009108871A Methane storage method utilizing activated carbon dispersed with metal lithium as methane adsorbent 审中-公开
标题翻译：甲醇储存方法利用金属锂作为甲烷吸附剂分散的活性炭
公开(公告)号：JP2009108871A
公开(公告)日：2009-05-21
申请号：JP2007278356
申请日：2007-10-26
申请人： Kyuchaku Gijutsu Kogyo Kk , 吸着技術工業株式会社
发明人： IZUMI JUN , O KOKO
IPC分类号： F17C11/00 , B01J20/20 , C01B31/08
CPC分类号： Y02E60/321
摘要： PROBLEM TO BE SOLVED: To provide a methane storage method that efficiently adsorbs methane while maintaining an in-tower temperature at a fixed level by discharging adsorption heat, caused by methane adsorption, with a circulating gas to the outside of a system.
SOLUTION: The methane storage method is configured as follows. An adsorption tower 7 is filled with metal lithium-carrying activated carbon 6 serving as a methane adsorbent. Methane is pressurized and introduced into the adsorption tower. The methane is adsorbed by being brought into contact with the adsorbent and stored. A circulation line from the rear of the adsorption tower to an inlet pressurization line is provided so that adsorption heat caused by methane adsorption is discharged to the outside of a system by a compressor after-cooler and by a circulating gas, thereby efficiently adsorbing the methane while maintaining an in-tower temperature at a fixed level. Further, a chiller unit 4 is provided at the rear of the compressor after-cooler so that methane having a temperature below the room temperature is supplied to the adsorption tower for adsorption.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种甲烷储存方法，其通过将循环气体排放到系统外部，通过排出由甲烷吸附引起的吸附热量将塔内温度保持在固定水平，有效地吸附甲烷。解决方案：甲烷储存方法如下配置。吸附塔7填充有作为甲烷吸附剂的带有金属的锂的活性炭6。甲烷被加压并引入吸附塔。甲烷通过与吸附剂接触而吸附并被储存。提供从吸附塔后部到入口加压管线的循环管线，使得由甲烷吸附引起的吸附热量通过压缩机后冷却器和循环气体排放到系统的外部，从而有效地吸附甲烷同时将塔内温度保持在固定水平。此外，在压缩机后冷却器的后部设置有冷却器单元4，使得具有低于室温的温度的甲烷被供给到用于吸附的吸附塔。版权所有（C）2009，JPO＆INPIT

19. 发明专利

JP2009055821A Seawater-purifying apparatus for making fish or shellfish to live and method for purifying the seawater 有权
标题翻译：海水净化装置，用于制造鱼类或鱼粉，以及用于净化海水的方法
公开(公告)号：JP2009055821A
公开(公告)日：2009-03-19
申请号：JP2007225157
申请日：2007-08-31
申请人： Furukawa Denki Seisakusho:Kk , Kyuchaku Gijutsu Kogyo Kk , Nagasaki Prefecture , 吸着技術工業株式会社 , 株式会社古川電機製作所 , 長崎県
发明人： OWAKI HIROKI , YOKOYAMA FUMIHIKO , IZUMI JUN , YAMAGUCHI MASAMI , YAMAMOTO TAKAHIRO
IPC分类号： A01K63/04 , B01J20/18 , C02F1/28 , C02F1/46 , C02F1/76
摘要： PROBLEM TO BE SOLVED: To provide a seawater-purifying apparatus which can remarkably reduce the number of water exchanges due to the accumulation of nitrate nitrogen components in a seawater purification system needed on the existence or raising of seawater fishes, and can also reduce the total volume of the seawater purification system to lower the running cost, and to provide a seawater-purifying method.
SOLUTION: Disposed is a seawater-purifying system having an electrolysis tank, a reaction tank filled with an adsorbent, and a tank filled with a removing material for removing by-products produced by the degradation reactions of an excessive oxidant component and hypochlorous acid with organic substances, in a water circulation route having a water tank for receiving fishes or shellfishes. Contaminants such as ammonia, organic materials and the like excreted from the fishes or shellfishes are adsorbed on the surface of the adsorbent together with the hypochlorous acid and simultaneously reacted with each other, thereby not accumulating nitrogen components during the raising of the fishes or shellfishes.
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种海水净化装置，其可以显着地减少由于在存在或养殖海水鱼所需的海水净化系统中的硝酸盐氮成分的积累而导致的水交换次数，并且还可以降低海水净化系统的总体积，降低运行成本，提供海水净化方法。解决方案：设置有具有电解槽，填充有吸附剂的反应槽和填充有去除材料的罐的槽，用于除去由过氧化物组分和次氯酸的降解反应产生的副产物的海水净化系统在具有用于接收鱼类或贝类的水箱的水循环路线中与有机物质接触。从鱼类或贝类中排出的氨，有机物质等污染物与次氯酸一起被吸附在吸附剂的表面，同时彼此反应，从而在鱼类或贝类的养殖中不会积存氮成分。版权所有（C）2009，JPO＆INPIT

20. 发明专利

JP2008012439A Oxygen producing method and apparatus by pressure swing method using high temperature oxygen adsorbent 有权
标题翻译：使用高温氧气吸附剂的压力方式生产方法和设备
公开(公告)号：JP2008012439A
公开(公告)日：2008-01-24
申请号：JP2006186442
申请日：2006-07-06
申请人： Kyuchaku Gijutsu Kogyo Kk , Norio Miura , 則雄三浦 , 吸着技術工業株式会社
发明人： IZUMI JUN , MIURA NORIO
IPC分类号： B01D53/04 , B01J20/06 , C01B13/02
CPC分类号： Y02P20/57
摘要： PROBLEM TO BE SOLVED: To provide an oxygen producing method and apparatus by a pressure swing method using a high temperature oxygen adsorbent. SOLUTION: This method is for recovering heat of high temperature oxygen using the apparatus for heat recovery, wherein oxygen is adsorbed in an adsorbent at a high temperature using a Perovskite type adsorbent, and nitrogen is made to flow down, and heat of high temperature nitrogen is recovered, and oxygen is desorbed from the adsorbent. Sufficient heat recovery requires the minimum electric power consumption, to produce oxygen economically. COPYRIGHT: (C)2008,JPO&INPIT

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