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11. 发明专利

JPS6448832A MODIFIER FOR COMPOSITE MATERIAL 失效
公开(公告)号：JPS6448832A
公开(公告)日：1989-02-23
申请号：JP20492587
申请日：1987-08-18
申请人： SHINETSU CHEMICAL CO , NITTO BOSEKI CO LTD
发明人： ITAGAKI AKINARI , YAMATANI MASAAKI , YOSHIOKA HIROSHI , WATANABE AKIHIKO , MIYASATO KEITA
IPC分类号： D06M13/50 , C03C25/10 , C08J5/08 , C08K9/06 , D06M13/02 , D06M13/51 , D06M13/513 , D06M101/00 , H05K1/03
摘要： PURPOSE:To obtain the title modifier which improves the soldering heat resistance and heat shock resistance of a composite material, by using a specified amino silane compound (hydrochloride) as a base. CONSTITUTION:A silane of formula I (wherein R is methyl or ethyl, R is a 1-6C bivalent hydrocarbon group,and n is 4-8) is reacted with a compound of formula II at 50-150 deg.C in the presence of a hydrogen chloride binder (e.g., pyridine) in an alcohol or an aromatic hydrocarbon solvent to obtain a modifier for composite materials, comprising an amino silane compound (hydrochloride) of formula III. A composite material comprising a glass fiber or mica and an epoxy resin or a polyimide resin is impregnated with an aqueous solution containing 0.2-2wt.% said modifier and dried at 60-120 deg.C to effect the condensation of the surface of the composite material with the silanol groups of the silane compound.

12. 发明专利

JPS62279541A INFORMATION RECORDING MEDIUM DISK 失效
公开(公告)号：JPS62279541A
公开(公告)日：1987-12-04
申请号：JP12418286
申请日：1986-05-29
申请人： VICTOR COMPANY OF JAPAN , SHINETSU CHEMICAL CO
发明人： YAMAMOTO KANEO , YOSHIOKA HIROSHI
IPC分类号： B29D17/00 , G11B9/06
摘要： PURPOSE:To obtain a disk which has excellent durability an is stable for a long period of time by providing a thin film consisting of a mixture composed of specific compds. on the surface of an information recording disk consisting of a PVC resin contg. pulverized particles of a conductive material. CONSTITUTION:Information signals are recorded in the form of the change of a geometrical shape on the signal surface 2 of the disk 1 which is constituted by using the PVC resin as a base material and contg. at least a prescribed ratio of the pulverized particles of the conductive material. The thin film 3 is then formed on the signal surface 2. The thin film 3 is formed of the mixture composed of the a dimethyl siloxane and the modified polysiloxane expressed by the formula. In the formula, A, B are (CH2)3O(C2H4O)yH, x is 0-30 integer, y is 2-5 integer. The modified polysiloxane has 2.5-10 dielectric constant and is so mixed with the dimethyl siloxane that said siloxane is incorporated at 0.5-2 ratio by weight to dimethyl siloxane.

13. 发明专利

JPS626430A MAGNETIC RECORDING MEDIUM 失效
公开(公告)号：JPS626430A
公开(公告)日：1987-01-13
申请号：JP14536385
申请日：1985-07-02
申请人： SONY CORP , SHINETSU CHEMICAL CO
发明人： IKUYAMA SEIICHI , NINOMIYA YOSHINOBU , YOSHIOKA HIROSHI , ONO ICHIROU
IPC分类号： G11B5/702 , C09D5/23 , C09D127/04 , C09D127/06 , C09D175/00 , C09D175/04 , G11B5/708
摘要： PURPOSE:To improve durability, magnetic characteristics, electromagnetic conversion characteristic, etc. by using a vinyl chloride copolymer having double bonds sensitive to electron rays and a ternary amine salt of a sulfonic acid or ternary amine salt of sulfate as a polar group in the molecule for a binder constituting a magnetic layer. CONSTITUTION:The vinyl copolymer having the double bonds sensitive to electron rays and further having the ternary amine salt of the sulfonic acid and the ternary amine salt of sulfate as the polar group in the molecule is used as the binder for the magnetic material, by which the high affinity to magnetic powder is exhibited and the good dispersibility is obtd. even with the ultrafinely pulverized magnetic powder or the magnetic powder having a large quantity of magnetization. The durability and surface characteristic of the resulted magnetic recording medium are improved and the electromagnetic conversion characteristic is extremely highly improved as well. Since the binder has the double bonds sensitive to electron rays in the molecule, the magnetic coated film is easily cured by the irradiation of electron rays and the process for production is extremely simplified; in addition, the pot life and solidification of the paint are improved and thus there are many advantages in the process.

14. 发明专利

JPS55149331A MODIFIER FOR SYNTHETIC RESIN 失效
公开(公告)号：JPS55149331A
公开(公告)日：1980-11-20
申请号：JP5736279
申请日：1979-05-10
申请人： SHINETSU CHEMICAL CO
发明人： TAKAMIZAWA MINORU , INOUE KACHIO , YOSHIOKA HIROSHI
IPC分类号： C08L7/00 , C07F7/18 , C08J7/04 , C08K5/00 , C08K5/54 , C08K5/5419 , C08L1/00 , C08L21/00 , C08L23/00 , C08L27/00 , C08L33/00 , C08L33/02 , C08L51/00 , C08L51/02 , C08L67/00 , C08L77/00 , C08L101/00 , C09D5/00 , C09D7/00 , C09D7/12 , C09D183/04 , C10M111/04 , C10N40/36 , C10N50/02 , C10N50/08
摘要： PURPOSE:To provide a modifier based on a specific org. silicon compound, for imparting lubricating property or a mold-releasing property to a surface of a molded synthetic resin product as well as improving molding workability. CONSTITUTION:A modifier is prepared by using an org. silicon compound shown by formula I (wherein R is 1-6C monovalent hydrocarbon group; R is 7-21C monovalent hydrocarbon group; x is H, F; n is 1-4; m is 1, 2, 3) as a main agent. The adding quantity of this modifier is about 0.01-20pts.wt. to 100pts.wt. of a molding resin. An org. silicon compound to be applied is easily abtained by reacting mono-, di- or tri-chlorosilane having a group shown by formula II and an aliphatic acid in the presence of a dehydrochlorinating agent such as pyridine or triethylamine.

15. 发明专利

JPS52103499A PREPARATION OF POLYOXYALKYLENEE*MERCAPTOOGROUPPCONTAINING ORGANOPOLYSI LOXANE* COPOLYMERS 失效
公开(公告)号：JPS52103499A
公开(公告)日：1977-08-30
申请号：JP2010276
申请日：1976-02-27
申请人： SHINETSU CHEMICAL CO
发明人： ISOBE KENICHI , YOSHIOKA HIROSHI
IPC分类号： C09K3/16 , C08G77/00 , C08G77/46 , C09D183/04
摘要： PURPOSE:To prepare polyoxyalkylene-(mercapto-group-containing organopolysiloxane) copolymers which exhibit excellent antiblocking properties without cissing which added to water-based paints, by reacting specific polyoxyalkylene-organopolysiloxane copolymers with hydrosulfides.

16. 发明专利

JPH0859315A CEMENT ADMIXTURE 失效
公开(公告)号：JPH0859315A
公开(公告)日：1996-03-05
申请号：JP19703994
申请日：1994-08-22
申请人： SHINETSU CHEMICAL CO
发明人： UCHIDA SATORU , OSAKI HIROMI , YOSHIOKA HIROSHI , SAKAZUME KATSUAKI , ENDO MIKIO
IPC分类号： C04B14/04 , C04B24/12 , C04B24/42 , C04B40/00 , C08L83/04
摘要： PURPOSE: To improve the waterproofness, algae proof property and durability of a concrete or mortal structure by incorporating specific oraganopolysiloxanes, an inorganic material and an algae proofing agent. CONSTITUTION: A cement admixture is obtained by mixing 100 pts.wt. powdery or single fibrous inorganic material with 50-300 pts.wt. organopolysiloxanes expressed by the formula (R is a 1-20C univalent hydrocarbon group, R is a >=2C univalent hydrocarbon group, phenyl, a polyoxyalkylene or a univalent hydrocarbon group having substituted group and (m) and (n) are 0 or positive integers) and further additively mixing 10-200 pts.wt. algae proofing agent having a hydrolytic silyl group in the molecule and, if necessary 50-500 pts.wt. silica containing material of at least one kind selected from silica fume, fly ash and blast furnace slug having /g specific surface area. As occasion demands, 20-80 pts.wt. water is added into a mixture previously prepared by mixing 0.1-30 pts.wt. cement admixture and 0-3000 pts.wt. aggregate with 100 pts.wt. of the above cement to use.

17. 发明专利

JPH0519526A DRY PROCESS ELECTROPHOTOGRAPHIC DEVELOPER 失效
公开(公告)号：JPH0519526A
公开(公告)日：1993-01-29
申请号：JP20011691
申请日：1991-07-15
申请人： SHINETSU CHEMICAL CO
发明人： ONO ICHIROU , YOSHIOKA HIROSHI , HIGUCHI HIDEO
IPC分类号： G03G9/08
摘要： PURPOSE:To provide excellent moisture resistance, positive electrostatic charge characteristics and adequateness of production and to reduce a cost by incorporating metal oxide powder which is treated with an org. silicon compd. having a silazane bond and has a positive electrostatic charge characteristic into the above developer. CONSTITUTION:The metal oxide powder which is treated with the org. silicon compd. having the silazane bond and has the positive electrostatic charge characteristic is incorporated into this developer. The representative examples of the org. silicon compd. having the silazane compd. to be used include hexamethyl disilazane, hexamethyl cyclotrisilazane and octamethyl cyclotetrasilazane. The hexamethyl disilazane is most preferable in terms of a hydrophobing capacity and cost. The metal oxide powder to be treated with the org. silicon compd. having the silazane bond is more preferably one or >=2 kinds of the oxide powers selected from the oxides of Si, Ti, Al, and Zr and is more particularly preferably the silicon dioxide powder in terms of the reactivity of the org. silicon compd. having the silazane bond.

18. 发明专利

JPH04168415A CONTACT LENS 失效
公开(公告)号：JPH04168415A
公开(公告)日：1992-06-16
申请号：JP29632790
申请日：1990-10-31
申请人： MENICON CO LTD , SHINETSU CHEMICAL CO
发明人： KAWAGUCHI TORU , TOYOSHIMA NOBUYUKI , YOSHIOKA HIROSHI , YAMAZAKI TOSHIO
IPC分类号： G02C7/04 , C08F20/22 , C08F30/08 , C08F222/18 , C08F230/08 , C08F290/00 , C08F299/08
摘要： PURPOSE:To allow a contact lens excellent in oxygen permeability, hardness, softness and transparency by forming the contact lens from a copolymer containing a monomer mixture in which a silicone containing styrene and a fumarate are mixed together in a specified mole ratio. CONSTITUTION:A contact lens is formed by using, as a material, a copolymer consisting of a copolymer component containing at least 10 mole % of a monomer mixture obtained by mixing a silicon-containing styrene and at least one of fumarates of dialkyl fumarate, di(fluoroalkyl)fumarate, di(silicon-containing alkyl)fumarate, alkyl(fluoroalkyl)fumarate, alkyl(silicon-containing alkyl)fumarate, and fluoroalkyl(silicon-containing alkyl)fumarate are mixed together in a mole ratio of 1:1 - 25:1, preferably 1:1 - 10:1. The copolymer component desirably contain 0.1 - 20 mole % of a cross-linking monomer.

19. 发明专利

JPH0368588A POLYESTER DERIVATIVE OF ALKOXYSILANE AND MAGNETIC RECORDING MEDIUM USING THE SAME 失效
公开(公告)号：JPH0368588A
公开(公告)日：1991-03-25
申请号：JP20617889
申请日：1989-08-09
申请人： SONY CORP , SHINETSU CHEMICAL CO
发明人： SOMEZAWA MASASHI , TAKANO MASAE , YOSHIOKA HIROSHI , ONO ICHIROU
IPC分类号： C07F7/18 , C08G63/68 , C08G63/695 , C09D5/23 , C09D127/04 , C09D127/06 , C09D175/00 , C09D175/04 , G11B5/702
摘要： NEW MATERIAL:A compound expressed by formula I (R and R represent 1-4C alkyl; X represents divalent organic group having oxy, imino, etc., at one end of main chain; n is 1-3; m is 1-30; p is 2-6). EXAMPLE:A compound expressed by formula II. USE:A surface-treating agent for ferromagnetic powder constituting a magnetic layer of a magnetic recording medium, capable of improving dispersibility of the ferromagnetic powder, durability of the magnetic layer and affinity between an inorganic powder with high hydrophilicity and an organic polymer compound with high hydrophobicity. PREPARATION:For example, a compound expressed by formula III, wherein an intermediate group X having a terminal active hydrogen is bound with Si atom of alkoxy-silane at the other terminus, is used as an initiator, which together with epsilon-caprolactone expressed by formula IV, is subjected to cyclization polymerization in the presence of a catalyst such as isopropyl orthotitanate in nitrogen atmosphere at 100-200 deg.C for 2-10hr.

20. 发明专利

JPH036230A POLYACTONE-MODIFIED ORGANOPOLYSILOXANE COMPOUND 失效
公开(公告)号：JPH036230A
公开(公告)日：1991-01-11
申请号：JP14063289
申请日：1989-06-02
申请人： SHINETSU CHEMICAL CO
发明人： ONO ICHIROU , YOSHIOKA HIROSHI
IPC分类号： C08G18/61 , C08G63/68 , C08G63/695 , C08G77/14 , C08G77/22 , C08G77/38 , C08G77/445 , C08G81/00 , C08L63/00 , C08L101/00 , C09D183/04 , C09D183/10
摘要： PURPOSE:To prepare a film-forming agent highly compatible with various resins and having characteristics of polyorganosiloxane by bonding a branched polylactone-contg. group to an organopolysiloxane. CONSTITUTION:A polylactone-modified organopolysiloxane useful as a synthetic resin modifier, a film-forming agent, etc., comprises a polysiloxane wherein a polylactone-contg. group of formula I [wherein Z is a trivalent hydrocarbon group optionally contg. O, S, or N; X is a lactone group of formula II (wherein R is H, or 1-12C alkyl; and (a) is 4-6), Y is H or acetyl; and (k)>1 and (l)>1] is bonded to an Si atom at the molecular terminals or in the molecular chain.

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