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11. 发明专利

JPH06107980A COMPOSITE MATERIAL FOR COATING 失效
公开(公告)号：JPH06107980A
公开(公告)日：1994-04-19
申请号：JP28369192
申请日：1992-09-29
申请人： SHISEIDO CO LTD
发明人： TSUBOTA MINORU , FUKUI HIROSHI , KUTSUNA YUTAKA
IPC分类号： C09C3/12 , C09D5/00 , C09D5/24 , C09D7/12 , C09D163/00
摘要： PURPOSE:To provide a composite material containing a glycidyl group-containing powder and a polymer having a group reactive with a glycidyl group, excellent in mechanical strength and high-temperature stability and suitable, e.g. for a paste material for IC and a heat-resistant conductive coating material. CONSTITUTION:The objective composite material comprises (A) a glycidyl group-containing powder and (B) a polymer (e.g. an oildegenerated alkyd resin or an acrylic resin) having a group reactive with a glycidyl group preferably in a ratio of (A)= 0.1 to 95wt.% and (B) = 5 to 99wt.%. In addition, the component (A) is prepared preferably by coating a powder such as an inorganic pigment or carbon with a silicone polymer through a gas phase treatment and subsequently adding a glycidyl group-containing compound reactive with an Si-H, e.g. an allyl glycidyl ether or an epoxyhexene to an unreacted Si-H in the silicone polymer so as to introduce the glycidyl group into the silicone polymer.

12. 发明专利

JPH04166764A PACKING AGENT FOR LIQUID CHROMATOGRAPHY AND PREPARATION THEREOF 失效
公开(公告)号：JPH04166764A
公开(公告)日：1992-06-12
申请号：JP29169590
申请日：1990-10-31
申请人： SHISEIDO CO LTD
发明人： KUTSUNA YUTAKA , SUHARA TSUNEO , SHIOJIMA YOSHIHIRO , FUKUI HIROSHI , OTSU YUTAKA , YAMAGUCHI MICHIHIRO
IPC分类号： B01J20/286 , B01D15/08 , B01J20/281 , B01J20/32 , G01N30/88
摘要： PURPOSE:To enhance alkali resistance and separation characteristics by bonding polyalkyleneamine to a specific silicone polymer coated particle through a spacer having definite chain length. CONSTITUTION:The silicon atom originating from the SiH group of a silicone polymer coated porous silica gel part is bonded to one terminal of a spacer part through a silicon-carbon covalent bond and the other terminal of the spacer part is bonded to the amino group of polyalkylene polyamine through a carbon- nitrogen or sulfur-nitrogen covalent bond. The spacer constituting part between both bonds is a group consisting of 3 - 15 constitutional atoms and composed to a substituted or non-substituted hydrocarbon chain which may be interrupted by at least one of an oxygen atom, a sulfur atom and a nitrogen atom. In this case, an Si-H group is preferentially reacted with the vinyl group of the spacer compound and polyalkylene polyamine is reacted with the other functional group of the spacer compound and, if necessary, the amine part between mutual polyalkylene polyamine parts is crosslinked.

13. 发明专利

JPS6430637A EMULSION COMPOSITION 失效
公开(公告)号：JPS6430637A
公开(公告)日：1989-02-01
申请号：JP18524787
申请日：1987-07-24
申请人： SHISEIDO CO LTD
发明人： KUTSUNA YUTAKA , MATSUDA HAKU , FUKUI HIROSHI , NAGAI ISAO
IPC分类号： A61K9/06 , A61K8/06 , A61K8/11 , A61K8/29 , A61K8/58 , A61K9/10 , A61K9/107 , A61K47/00 , A61K47/02 , A61K47/10 , A61K47/34 , A61Q1/00 , A61Q1/04 , A61Q1/12 , A61Q17/04 , B01F17/00 , B01J13/00 , C09C3/10 , C09C3/12
摘要： PURPOSE:To improve the shelf stability and safety of the title emulsion composition by incorporating a granular body having 0.01-5mum mean particle diameter and with the surface modified with an alcoholic hydroxyl group and/or a polyoxyalkylene group to prepare the emulsion composition. CONSTITUTION:The powdery body is firstly coated with the silicon polymer having an Si-H group, and then an unsaturated compd. having an alcoholic hydroxyl group or a polyoxyalkylene group is added to the Si-H group to produce the powdery body having 0.01-5mum mean particle diameter and with the surface modified with an alcoholic hydroxyl group and/or a polyoxyalkylene group. The surface-modified powdery body, oil, water, and a surfactant, as required, are mixed to prepare the emulsion composition. The content of the surface-modified powdery body in the emulsion composition is appropriately controlled to 0.5-20wt.%. Talc, kaolin, calcium carbonate, etc., are used as the powder for surface modification.

14. 发明专利

JPS63168346A IMPROVED SOLID MATERIAL 失效
公开(公告)号：JPS63168346A
公开(公告)日：1988-07-12
申请号：JP21787
申请日：1987-01-06
申请人： SHISEIDO CO LTD
发明人： FUKUI HIROSHI , KUTSUNA YUTAKA , SUHARA TSUNEO , NAKANO MASAKIYO , OGAWA TAKASHI , NAKADA OKITSUGU , OTSU YUTAKA
IPC分类号： B01J20/26 , A61K8/00 , A61K8/18 , A61K8/89 , A61K8/891 , A61K47/00 , A61K47/34 , A61L9/04 , A61Q1/00 , A61Q1/02 , A61Q1/12 , B01J20/283 , B32B27/00 , C08J7/04 , C08J7/12 , C08K9/06 , C08L83/05 , C09C3/12 , C09D5/23 , C09D7/12 , G01N30/88 , G01N33/552

15. 发明专利

JP2005010112A Compound, column filler, column for chromatography, chromatograph, and optical resolution method 审中-公开
标题翻译：化合物，柱填充液，色谱柱，色谱和光学分辨方法
公开(公告)号：JP2005010112A
公开(公告)日：2005-01-13
申请号：JP2003177372
申请日：2003-06-20
申请人： Shiseido Co Ltd , 株式会社資生堂
发明人： YAMAGISHI AKIHIKO , TANAKA ISAO , OGAWA TAKASHI , KUTSUNA YUTAKA
IPC分类号： B01J20/291 , B01D15/00 , B01J20/22 , B01J20/281 , B01J20/283 , B01J20/285 , C07B57/00 , C07C227/34 , G01N30/88 , G01N30/48
摘要： PROBLEM TO BE SOLVED: To provide a compound which contains optically active anions and is reduced in the solubility of the optically active anions in a liquid, a column filler containing the compound, a column for chromatography using the column filler, a chromatograph provided with the column for chromatography, and an optical resolution method using the compound.
SOLUTION: The compound contains a carrier and the optically active anions, and the optically active anions are carried by the carrier. The carrier is a clay mineral capable of exchanging anions and is a silica gel bonded to an anion exchange group or an anion exchange resin.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供含有光学活性阴离子并且降低光学活性阴离子在液体中的溶解度的化合物，含有化合物的柱填料，使用柱填料的色谱柱，色谱仪提供色谱柱和使用该化合物的光学拆分方法。解决方案：化合物含有载体和光学活性阴离子，光学活性阴离子由载体携带。载体是能够交换阴离子的粘土矿物，并且是与阴离子交换基团或阴离子交换树脂结合的硅胶。版权所有（C）2005，JPO＆NCIPI

16. 发明专利

JPS6287523A SAFFLOWER EXTRACT, PRODUCTION THEREOF AND VASODILATOR CONSISTING OF SAID SAFFLOWER EXTRACT 失效
公开(公告)号：JPS6287523A
公开(公告)日：1987-04-22
申请号：JP22744785
申请日：1985-10-12
申请人： SHISEIDO CO LTD
发明人： KUTSUNA YUTAKA , FUJII SEISHIROU , KITAMURA KENJI
IPC分类号： A61K36/28 , A61P9/08
摘要： PURPOSE:To industrially and advantageously obtain a safflower extract which is a specific component useful as a vasodilator without containing a side effect component, e.g. blood coagulation inhibitory action, etc., by using a purification step of fractionating precipitation of hot water extract concentrate of safflower and separation and collection by reversed phase liquid chromatography. CONSTITUTION:For example, a water-soluble organic solvent is added to a hot water extract concentrate of safflower to carry out fractionating precipitation and give a supernatant, which is then concentrated. The resultant concentrate is redissolved in water and subjected to reversed phase liquid chromatography. When water is passed as a mobile phase, only a fraction which is not held is recovered to afford the aimed safflower extract having a main peak at k'=0.5-6 when measured by high-speed liquid chromatography under conditions as follows; Column; ODS (5mu) 4phiX250mm. Mobile phase; acetic acid/acetonitrile/water=0.1/1/98.9. RI or UV (254nm). In the above-mentioned purification step, dyestuff components, blood platelet agglutination inhibitory components and and blood coagulation inhibitory components can be removed and the vasodilator action can be remarkably improved at the same time.

17. 发明专利

JPS61280411A COSMETIC 失效
公开(公告)号：JPS61280411A
公开(公告)日：1986-12-11
申请号：JP12316985
申请日：1985-06-06
申请人： SHISEIDO CO LTD , NIPPON SUISAN KAISHA LTD
发明人： KUTSUNA YUTAKA , MATSUOKA MASAHIRO , FUJITA TAKAO , SATAKE MIKIO
IPC分类号： A61K8/96 , A61K8/18 , A61K8/98 , A61Q1/00 , A61Q1/02 , A61Q1/04 , A61Q1/06 , A61Q1/10 , A61Q3/02 , C09B61/00
摘要： PURPOSE:A cosmetic containing an orange dyestuff of good quality obtained by hydrogenating selectively an unsaturated lipid other than a dyestff of a solvent extract of krills in the presence of a catalyst, hydrolyzing the lipid with lipase added thereto and removing the freed lipic acid. CONSTITUTION:A cosmetic obtained by hydrogenating selectively contaminating unsaturated lipid other than a dyestuff in a solution extracted from dried krill bodies with an organic solvent, e.g. n-hexane, in the presence of a catalyst, e.g. PdO, adding lipase thereto to hydrolyze the lipid, removing the freed lipic acid by addition of urea and/or molecular distillation to give an odorless bright orange dyestuff having improved hue stability without reversed odor and concentrating and purifying the dyestuff by column chromatography to afford the aimed orange dyestuff having the above-mentioned characteristics and further high tinting power. EFFECT:Useful as cosmetic for makeup having the desired bright hue, improved odor and hue stability and high tinting power without changing the odor nor fading with time.

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