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    • 12. 发明专利
    • Gas adsorbent
    • 气体吸收
    • JP2010082545A
    • 2010-04-15
    • JP2008254291
    • 2008-09-30
    • Ngk Insulators Ltd日本碍子株式会社
    • GOTO MASASHIFURUKAWA MASAHIRO
    • B01J20/22C01B3/00
    • Y02E60/327
    • PROBLEM TO BE SOLVED: To provide a novel gas adsorbent having enhanced structural stability capable of adsorbing hydrogen in a greater amount.
      SOLUTION: The gas adsorbent is structured by including: a first material of a three-dimensional structure constituted of a plurality of basic skeletons each formed by a metal nucleus (Zn) and a ligand (p-hydroxybenzoic acid) comprising an aromatic ring as its main skeleton, a carboxyl group and a functional group capable of forming a coordinate covalent bond other than a carboxyl group, each attached to the aromatic ring, by binding to each other in a ratio of 1:1; and a second material capable of chemically adsorbing hydrogen constituted of catalytic metal (platinum) supported by an inorganic support (carbon). The ratio of the first material to the second material is 90:10 by weight. The gas adsorbent exhibits a volume of adsorbed hydrogen gas four times greater than the calculated value theoretically calculated from the volume of hydrogen gas to be adsorbed by each of the first material and the second material, which clearly indicates the presence of a synergetic effect of the first and the second materials.
      COPYRIGHT: (C)2010,JPO&INPIT
    • 要解决的问题:提供一种具有能够更大量吸附氢的结构稳定性的新颖的气体吸附剂。 解决方案:气体吸附剂的结构包括:由金属核(Zn)形成的多个碱性骨架和包含芳族化合物的配体(对羟基苯甲酸)构成的三维结构的第一材料 环作为其主骨架,羧基和能够形成除羧基以外的配位共价键的官能团,各自连接到芳环上,以1:1的比例彼此结合; 以及能够化学吸附由无机载体(碳)负载的催化金属(铂)构成的氢的第二材料。 第一材料与第二材料的重量比为90:10。 气体吸附剂表现出吸附氢气的体积比理论计算的计算值高四倍于要由第一材料和第二材料吸收的氢气的体积,这清楚地表明存在协同效应 第一和第二材料。 版权所有(C)2010,JPO&INPIT