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131. 发明专利

JP2905947B2 失效
公开(公告)号：JP2905947B2
公开(公告)日：1999-06-14
申请号：JP10576591
申请日：1991-05-10
申请人： ANSUCHI* FURANSE DEYU PETOROORU
发明人： FURANSHISU RAA , BERUNAARU JUGAN , JAN HOORU BURUNONUIRU
IPC分类号： C07B61/00 , B01J29/40 , B01J29/74 , C07C2/00 , C07C2/76 , C07C15/02 , C10G35/06

132. 发明专利

JPH10216521A CATALYST FOR REFORMING HYDROCARBON WITH STEAM 失效
公开(公告)号：JPH10216521A
公开(公告)日：1998-08-18
申请号：JP2745297
申请日：1997-02-12
申请人： MITSUBISHI HEAVY IND LTD
发明人： YASUTAKE SATONOBU , TSUKUDA IWAO , IMAI TETSUYA
IPC分类号： C01B3/40 , B01J23/76 , B01J23/78 , C10G35/06 , H01M8/06
摘要： PROBLEM TO BE SOLVED: To produce a catalyst which carries out a reforming reaction of a hydrocarbon with steam for a long duration, accompanied with little carbon precipitation by using a heat-resistant oxide containing alumina and zirconia as a support and depositing nickel oxide as a catalytically active component and one or more compounds such as lanthanum oxide as auxiliary catalytic components on the support. SOLUTION: A catalyst for reforming hydrocarbon with steam and which has excellent carbon precipitation suppressing effect on the surface even at low reaction temperature and low S/C ratio condition is produced by employing a heat resistant oxide containing zirconia and alumina as a support and depositing nickel oxide as a catalytically active component and one or more of lanthanum oxide, potassium oxide as auxiliary catalytic components on the support. The deposition amount of nickel oxide is not less than 5wt.% and not more than 20wt.% to the total weight of the catalyst, and the total deposition amount of lanthanum oxide and potassium oxide is not less than 1wt.% and not more than 10wt.% to the total weight of the catalyst and the content of zirconia is not less than 1wt.% and not more than 10wt.% to the total weight of the support.

133. 发明专利

JPH10506671A 失效
公开(公告)号：JPH10506671A
公开(公告)日：1998-06-30
申请号：JP53278396
申请日：1996-04-29
IPC分类号： B01J29/08 , C10G11/02 , C10G11/18 , C10G35/06 , C10G50/00 , C10G69/00

134. 发明专利

JPH10500891A 失效
公开(公告)号：JPH10500891A
公开(公告)日：1998-01-27
申请号：JP52967095
申请日：1995-05-01
IPC分类号： B01J21/04 , B01J23/38 , B01J23/70 , B01J23/85 , B01J23/881 , B01J23/882 , B01J23/883 , B01J23/94 , B01J27/188 , B01J27/199 , B01J35/02 , B01J35/10 , B01J37/02 , B01J37/06 , B01J37/08 , B01J38/00 , B01J38/68 , C10G35/06 , C10G45/04 , C10G45/06 , C10G45/10 , C10G45/60 , C10G47/02 , C10G47/12 , C10G49/02 , C10G49/04

135. 发明专利

JPH10500146A 失效
公开(公告)号：JPH10500146A
公开(公告)日：1998-01-06
申请号：JP51703995
申请日：1994-05-31
IPC分类号： B01J29/06 , C07C2/66 , C10G35/06 , C10G35/095 , C10G45/64 , C10G59/02

136. 发明专利

JPH09328442A CONVERSION OF LOWER PARAFFINIC HYDROCARBON INTO AROMATIC HYDROCARBON 失效
公开(公告)号：JPH09328442A
公开(公告)日：1997-12-22
申请号：JP30972695
申请日：1995-11-06
申请人： INUI SATOYUKI , SHOWA SHELL SEKIYU
发明人： INUI SATOYUKI
IPC分类号： B01J29/06 , B01J29/068 , C07B61/00 , C07C2/76 , C07C15/02 , C10G35/06 , C10G35/085 , C10G35/095
摘要： PROBLEM TO BE SOLVED: To provide a method for converting a lower paraffinic hydrocarbon into an aromatic hydrocarbon in high conversion and selectivity by treating the lower paraffinic hydrocarbon with a specific catalyst. SOLUTION: A lower paraffinic hydrocarbon is treated with a metallosilicate catalyst at 300-500 deg.C. The metallosilicate catalyst is represented by the following composition: Si/Me (atomic ratio) is 25-3200 (Me represents Ge); OH/SiO2 (molar ratio) is 0.3-1.0; H2 O/SiO2 (molar ratio) is 30-100; R/(R + alkali metal) (molar ratio) is 0.05-0.15 (R is a quaternary alkylammonium cation); NaCl/H2 O (molar ratio) is 0.01-0.06. The catalyst is obtained by adding an A solution which is an aqueous solution containing a metal salt, the quaternary alkylammonium cation and the inorganic salt and a B solution comprising an aqueous silicate solution into a C solution comprising an aqueous solution of an agent for ionic regulation to reduce the change of the concentration of each liquid, further grinding the mixture, dividing the mixture and performing a hydrothermal synthesis by warming up from a room temperature to 150-190 deg.C. Pt or Ga is preferably supported on the catalyst in 0.25-1.5wt.%.

137. 发明专利

JPH09253488A ISOMERIZATION CATALYST FOR LIGHT PARAFFIN AND METHOD FOR USING IT 失效
公开(公告)号：JPH09253488A
公开(公告)日：1997-09-30
申请号：JP9475996
申请日：1996-03-25
申请人： PETROLEUM ENERGY CENTER FOUND , MITSUBISHI OIL CO
发明人： HASHIMOTO YASUTSUGU , MATSUMOTO TAKANARI , KUMADA FUMIO
IPC分类号： B01J23/40 , B01J23/42 , B01J23/44 , B01J23/74 , C07B61/00 , C07C5/27 , C10G35/06
摘要： PROBLEM TO BE SOLVED: To prepare a source for a good gasoline mixed material with high octane value and small sensitivity by isomerizing a straight light naphtha in purification of petroleum. SOLUTION: In an isomerization catalyst for light paraffin used in a method for isomerizing light paraffin under hydrogen pressure, the isomerization catalyst is a catalyst wherein a binary metal hydroxide contg. metal hydroxides of zirconium and hafnium by a molar ratio of 1:1-20:1 is prepd. by coprecipitation method wherein it is precipitated under a condition of pH of 7.5-9.0 and a VIII group metal is carried on the formed binary metal hydroxide and it is treated with sulfate ion and thereafter, it is calcined at 550-750 deg.C.

138. 发明专利

JPH093459A PRODUCTION OF GASOLINE BASE 失效
公开(公告)号：JPH093459A
公开(公告)日：1997-01-07
申请号：JP32969195
申请日：1995-11-24
申请人： NIPPON OIL CO LTD
发明人： ISHIKAWA KATSUHIKO
IPC分类号： B01J27/188 , B01J29/12 , C10G35/06 , C10G45/52 , C10L1/06
摘要： PROBLEM TO BE SOLVED: To produce a gasoline base without containing benzene by bringing a crude benzene fraction into contact with hydrogen in the presence of a hydrogenating isomerization catalyst containing a specific active metal supported on zeolite, etc., and selectively converting the benzene into methylcyclopentane. SOLUTION: A crude benzene fraction is brought into contact with hydrogen in the presence of a hydrogenating isomerization catalyst containing at least one active metal selected from group VIII metals of the periodic table supported on zeolite (preferably Y type zeolite) or an acidic salt of a heteropoly acid at 200-360 deg.C, 2.0-14.0 raw material feed rate (LHSV) and 3.0-10.0 molar ratio of hydrogen/benzene under 10-100atm pressure to selectively convert the benzene in the crude benzene fraction into methylcyclopentane.

139. 发明专利

JPH0829254B2 失效
公开(公告)号：JPH0829254B2
公开(公告)日：1996-03-27
申请号：JP23706792
申请日：1992-09-04
申请人： PESHINE RUSHERUSHU GURUUPUMAN DANTERE EKONOMITSUKU REJI PAARU RORUDONANSU DOYU 23 SEPUTANBURU 1967
发明人： MARUKUUJATSUKU RUDOO , JANNRUI GIIYU , KYUON FUANNYUU , HYUU DANROTSUPU , MARII PURAN
IPC分类号： B01J23/28 , B01J27/22 , B01J37/02 , B01J37/18 , C10G35/06

140. 发明专利

JPH0867882A HYDROGENATION OF BENZENE IN HYDROCARBON OIL 失效
公开(公告)号：JPH0867882A
公开(公告)日：1996-03-12
申请号：JP20335394
申请日：1994-08-29
申请人： COSMO SOGO KENKYUSHO KK , COSMO OIL CO LTD
发明人： SHIMIZU TOSHIO
IPC分类号： C10G35/06 , C10G45/44 , C10G45/48 , C10G45/52 , C10G45/54
摘要： PURPOSE: To hydrogenate benzene harmful to human body selectively, industrially and advantageously by reacting a hydrocarbon oil with a hydrogen gas in the presence of both a specific catalyst and a zinc-containing alkali water phase and suppressing hydrogenation of a compound as an octane number base for gasoline. CONSTITUTION: (A) A hydrocarbon oil is reacted with (D) a hydrogen gas in the presence of both (B) a hydrogenating catalyst comprising a metal of the group VIII of the periodic table (e.g. ruthenium oxide) and (C) a zinc (compound)-containing alkali water phase to hydrogenate benzene in the component A. The component A is a benzene-containing gasoline fraction, especially a reformed oil having a high benzene concentration. The zinc compound of the component C is zinc oxide or zinc sulfate.

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