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91. 发明专利

JP2009256293A Silicon compound having fluorene skeleton 有权
标题翻译：含有氟橡胶的硅化合物
公开(公告)号：JP2009256293A
公开(公告)日：2009-11-05
申请号：JP2008121538
申请日：2008-05-07
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： YAMADA MASAHIRO , MIYAUCHI SHINSUKE , NAGASHIMA TAICHI , KAWASAKI SHINICHI , KITAJIMA SATSUKI , HANASAKA FUMIHIRO , SHIBAHARA TETSUYA , SATO MASAHIRO
IPC分类号： C07F7/18
摘要： PROBLEM TO BE SOLVED: To provide a new silicon compound having a fluorene skeleton which has excellent properties such as a high refractive index, and high transparency. SOLUTION: The new silicon compound is represented by the formula (wherein ring Z is a benzene ring or the like; X is a connecting group; R 1 is a cyano group or the like; R 2 is an alkyl group or the like; R 3 is an alkylene group; R 4 , R 5 , and R 6 are each hydrogen or the like; k is an integer of 0-4; m is an integer of not less than 0; n is an integer of not less than 0; p1 is an integer of not less than 1; and p2 is an integer of not less than 0). COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供具有优异性能如高折射率和高透明度的芴骨架的新的硅化合物。解决方案：新的硅化合物由式（其中环Z是苯环等）表示; X是连接基团; R 1是氰基等; R 2 是烷基等; R 3是亚烷基; R 4是，R 5，和R 6各自为氢等; k为0-4的整数; m为不小于0的整数; n为不小于0的整数; p1为整数不小于1; p2是不小于0的整数）。版权所有（C）2010，JPO＆INPIT

92. 发明专利

JP2009234998A Clathrate compound that uses compound comprising fluorene skeleton 有权
标题翻译：使用包含荧光素的化合物的复合化合物
公开(公告)号：JP2009234998A
公开(公告)日：2009-10-15
申请号：JP2008084058
申请日：2008-03-27
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： MIYAUCHI SHINSUKE , YAMADA MASAHIRO , KAWASAKI SHINICHI , NIWA ATSUSHI
IPC分类号： C07C39/17 , C07C31/02 , C07C33/025 , C07C35/37 , C07C37/88 , C07C43/04 , C07C49/08 , C07C49/10 , C07C69/14 , C07D307/06 , C07D319/10 , C09K3/00
摘要： PROBLEM TO BE SOLVED: To provide a new clathrate compound using a compound comprising a fluorene skeleton (a fluorene-containing clathrate compound), and a method of producing the same. SOLUTION: The clathrate compound comprises as a host compound, a fluorene-containing compound at least containing a 9,9-bisarylfluorene skeleton. A guest compound may be an araliphatic saturated alcohol, an aliphatic unsaturated alcohol, an alicyclic saturated alcohol, or an ether at least comprising a tertiary hydrocarbon group. The clathrate compound may contain the guest compound in a ratio of about 1 to 2 moles relative to 1 mole of the host compound. The clathrate compound may be used as a slow-releasing material, a temperature-sensitive material, a gas storage material, or a separation material. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：使用包含芴骨架的化合物（含芴包合物）提供新的包合物化合物及其制备方法。解决方案：包合物包含至少含有9,9-双芳基芴骨架的作为主体化合物的含芴化合物。客体化合物可以是至少包含叔烃基的芳脂族饱和醇，脂族不饱和醇，脂环族饱和醇或醚。相对于1摩尔的主体化合物，包合化合物可以含有约1至2摩尔的客体化合物。包合物可以用作缓释材料，温度敏感材料，气体储存材料或分离材料。版权所有（C）2010，JPO＆INPIT

93. 发明专利

JP2009234997A Compound containing fluorene skeleton 审中-公开
标题翻译：含有氟橡胶的化合物
公开(公告)号：JP2009234997A
公开(公告)日：2009-10-15
申请号：JP2008084057
申请日：2008-03-27
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： MIYAUCHI SHINSUKE , OGATA KAZUYUKI , MURASE HIROAKI , KAWASAKI SHINICHI
IPC分类号： C07C43/21
摘要： PROBLEM TO BE SOLVED: To provide a new nonfunctional fluorene-containing compound that is unreactive.
SOLUTION: The compound is represented by formula (1) [in the formula, Z may be the same or different and represents an aromatic hydrocarbon ring; R
1 may be the same or different and represents a hydrocarbon group, a halogen atom, or a cyano group; R
2 may be the same or different and represents a hydrocarbon group, an acyl group, an alkoxycarbonyl group, a halogen atom, a cyano group, an -XR
3 group (in the formula, R
3 represents a hydrocarbon group and X represents an oxygen atom or a sulfur atom) or an -N(R
4 )
2 group (in the formula, R
4 may be the same or different and represents a hydrocarbon group); m may be the same or different and is a natural number of 0 to 4; and n may be the same or different and is a natural number of 0 to 4].
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供一种不起反应的新的含有功能性的含芴化合物。解决方案：该化合物由式（1）表示[在该式中，Z可以相同或不同，表示芳族烃环; R 1可以相同或不同，表示烃基，卤素原子或氰基; R 2可以相同或不同，表示烃基，酰基，烷氧基羰基，卤原子，氰基，-XR 3 基（在式中，R“3”表示烃基，X表示氧原子或硫原子）或-N（R“SP”4 ） 2 组（式中，R 4 可以相同或不同，表示烃基）。 m可以相同或不同，为0〜4的自然数; n可以相同或不同，为0〜4的自然数]。版权所有（C）2010，JPO＆INPIT

94. 发明专利

JP2009173648A Multi-functional (meth)acrylate having fluorene skeleton 有权
标题翻译：具有荧光素的多功能（甲基）丙烯酸酯
公开(公告)号：JP2009173648A
公开(公告)日：2009-08-06
申请号：JP2008333783
申请日：2008-12-26
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： MIYAUCHI SHINSUKE , YAMADA MASAHIRO , KAWASAKI SHINICHI , MOTOKAWA TAKUYA , KURATANI HIROTSUGU , MINAMI SATOSHI , NAGASHIMA TAICHI , OSAWA SHINGO , MURASE HIROAKI
IPC分类号： C07C69/54 , C07C67/08 , C08F20/30
摘要： PROBLEM TO BE SOLVED: To provide a new fluorene skeleton-containing multi-functional (meth)acrylate which is excellent in handleability, although having a 9,9-bis(condensed multi-cyclic aryl) fluorene skeleton. SOLUTION: Provided is the (meth)acrylate represented by formula [wherein, a ring Z is a condensed multi-cyclic aromatic hydrocarbon ring such as naphthalene ring; R 1 is a substituent such as an alkyl group; R 2 is an alkylene group; R 3 is H or a methyl group; R 4 is a substituent such as a hydrocarbon group or an alkoxy group; (k) is an integer of 0 to 4; (m) is an integer of ≥1; (n) is 0 or an integer of ≥1; (p) is an integer of ≥1]. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供具有优异的操作性的新的含芴骨架的多官能（多）（甲基）丙烯酸酯，尽管具有9,9-双（缩合的多环芳基）芴骨架。解决方案：提供由式[其中，环Z是缩合的多环芳族烃环如萘环的（甲基）丙烯酸酯; R 1是取代基，例如烷基; R 2是亚烷基; R 3是H或甲基; R 4是取代基，例如烃基或烷氧基; （k）为0〜4的整数，（m）为≥1的整数; （n）为0或≥1的整数; （p）为≥1的整数。版权所有（C）2009，JPO＆INPIT

95. 发明专利

JP2009173647A Bifunctional (meth)acrylate having fluorene skeleton 有权
标题翻译：具有荧光素的双官能（甲基）丙烯酸酯
公开(公告)号：JP2009173647A
公开(公告)日：2009-08-06
申请号：JP2008333782
申请日：2008-12-26
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： MIYAUCHI SHINSUKE , YAMADA MASAHIRO , KAWASAKI SHINICHI , MOTOKAWA TAKUYA , KURATANI HIROTSUGU , MINAMI SATOSHI , NAGASHIMA TAICHI , OSAWA SHINGO , MURASE HIROAKI
IPC分类号： C07C69/54 , C08F20/30
摘要： PROBLEM TO BE SOLVED: To provide a new fluorene skeleton-containing bifunctional (meth)acrylate which is excellent in handleability, although having the fluorene skeleton.
SOLUTION: Provided is the (meth)acrylate represented by formula [wherein, R
1 is a cyano group, a halogen atom or an alkyl group; R
2 is a branched alkylene group; R
3 is H or a methyl group; R
4 is a hydrocarbon ring group such as an aryl group; (k) is an integer of 0 to 4; (m) is an integer of ≥1].
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：待解决的问题：提供具有优异的操作性的新的含芴骨架的双官能（甲基）丙烯酸酯，尽管具有芴骨架。解决方案：提供由式[其中R 1为氰基，卤素原子或烷基的式（I））表示的（甲基）丙烯酸酯; R 2是支链亚烷基; R 3是H或甲基; R 4是一个烃环基，例如芳基; （k）为0〜4的整数，（m）为≥1的整数。版权所有（C）2009，JPO＆INPIT

96. 发明专利

JP2009173645A Bifunctional (meth)acrylate having fluorene skeleton 有权
标题翻译：具有荧光素的双官能（甲基）丙烯酸酯
公开(公告)号：JP2009173645A
公开(公告)日：2009-08-06
申请号：JP2008333780
申请日：2008-12-26
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： MIYAUCHI SHINSUKE , YAMADA MASAHIRO , KAWASAKI SHINICHI , MOTOKAWA TAKUYA , KURATANI HIROTSUGU , MINAMI SATOSHI , NAGASHIMA TAICHI , OSAWA SHINGO , MURASE HIROAKI
IPC分类号： C07C69/54 , C08F20/30
摘要： PROBLEM TO BE SOLVED: To provide a new fluorene skeleton-containing bifunctional (meth)acrylate which is excellent in handleability, although having the fluorene skeleton.
SOLUTION: Provided is the (meth)acrylate represented by formula [wherein, R
1 is a cyano group, a halogen atom or an alkyl group; R
2 is a branched alkylene group such as propylene group; R
3 is H or a methyl group; R
4 is an alkyl group; (k) is an integer of 0 to 4; (m) is an integer of ≥1].
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：待解决的问题：提供具有优异的操作性的新的含芴骨架的双官能（甲基）丙烯酸酯，尽管具有芴骨架。解决方案：提供由式[其中R 1为氰基，卤素原子或烷基的式（I））表示的（甲基）丙烯酸酯; R SP2是支链亚烷基，例如丙烯基; R 3是H或甲基; R 4 是烷基; （k）为0〜4的整数，（m）为≥1的整数。版权所有（C）2009，JPO＆INPIT

97. 发明专利

JP2009057483A Fluorene skeleton-containing polyester-based block copolymer and method for producing the same 有权
标题翻译：含氟橡胶的基于聚烯烃的嵌段共聚物及其制备方法
公开(公告)号：JP2009057483A
公开(公告)日：2009-03-19
申请号：JP2007226431
申请日：2007-08-31
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： KATO MARIKO , YAMADA MASAHIRO , KOBORI KANA , KAWASAKI SHINICHI , KONDO YOSHIKAZU
IPC分类号： C08G63/91
摘要： PROBLEM TO BE SOLVED: To provide a resin excellent in thermal resistance and transparency, having a high refractive index and low birefringence, a method for producing the same and a molding formed from the resin.
SOLUTION: This polyester-based block copolymer comprises a fluorene-based polyester block chain (A) having a 9,9-bis(hydroxyaryl)fluorene skeleton and an aromatic polyester block chain (B) linked by a chain extender. The copolymer may be produced by way of a step of melt-kneading the fluorene skeleton-containing polyester-based resin having 9,9-bis(hydroxyaryl)fluorene skeleton with the aromatic polyester-based resin in the presence of a depolymerizing agent to depolymerize them; and a step of adding a chain extender to the product produced by the depolymerization to react the fluorene-based polyester block chain (A) with the aromatic polyester block chain (B).
COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：为了提供具有高折射率和低双折射性的耐热性和透明性优异的树脂，其制造方法和由树脂形成的模制品。解决方案：该聚酯类嵌段共聚物包括具有9,9-双（羟基芳基）芴骨架的芴基聚酯嵌段链（A）和通过扩链剂连接的芳族聚酯嵌段链（B）。共聚物可以通过在解聚剂的存在下将具有9,9-双（羟基芳基）芴骨架的含芴骨架的聚酯类树脂与芳香族聚酯类树脂熔融捏合的工序来制造，他们; 以及将通过解聚产生的产物添加扩链剂以使基于芴的聚酯嵌段链（A）与芳族聚酯嵌段链（B）反应的步骤。版权所有（C）2009，JPO＆INPIT

98. 发明专利

JP2008239956A Method for producing silicon-containing polymer having fluorene backbone 有权
标题翻译：用于生产含有荧光底板的含硅聚合物的方法
公开(公告)号：JP2008239956A
公开(公告)日：2008-10-09
申请号：JP2008006434
申请日：2008-01-16
申请人： Osaka Gas Co Ltd , Tokyo Institute Of Technology , 国立大学法人東京工業大学 , 大阪瓦斯株式会社
发明人： TAKADA TOSHIKAZU , HAYASHI HIDEKI , MIYAUCHI SHINSUKE , KOBORI KANA , KAWASAKI SHINICHI
IPC分类号： C08G77/48
摘要： PROBLEM TO BE SOLVED: To provide a method for producing a silicon-containing polymer having a fluorene backbone, excellent in heat resistance, etc., in a good efficiency. SOLUTION: This silicon-containing polymer having the fluorene backbone is provided by reacting a compound of formula (1) having the specific fluorene backbone with a silane compound of formula (2) having a halogen atom. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：待解决的问题：提供一种以高效率制备具有芴骨架的含硅聚合物的方法，耐热性等优异的方法。解决方案：具有芴主链的含硅聚合物通过使具有特定芴主链的式（1）化合物与具有卤素原子的式（2）的硅烷化合物反应来提供。版权所有（C）2009，JPO＆INPIT

99. 发明专利

JP2007314776A Electroconductive composition using carbon coil and electroconductive film therefrom 有权
标题翻译：使用碳化硅的电极组合物及其电导膜
公开(公告)号：JP2007314776A
公开(公告)日：2007-12-06
申请号：JP2007111368
申请日：2007-04-20
申请人： Osaka City , Osaka Gas Co Ltd , Osaka Prefecture Univ , 公立大学法人大阪府立大学 , 大阪市 , 大阪瓦斯株式会社
发明人： YAMADA MASAHIRO , KAWASAKI SHINICHI , KAKEGAWA HIROYA , KITA YASUO , NAKAYAMA YOSHIKAZU
IPC分类号： C08L101/00 , B01J23/825 , B01J23/835 , C01B31/02 , C08J5/18 , C08K7/00 , C08L67/00 , H01B1/24 , H01B5/14
摘要： PROBLEM TO BE SOLVED: To provide an electroconductive composition having both of electroconductivity and transparency in combination. SOLUTION: The conductive composition is composed with a resin and a conductive carbon constituted of at least carbon coils. The resin may be constituted of a resin with a fluorene skeleton (for example, a polyester type resin with a fluorene skeleton). The carbon coils are preferred to be constituted by carbon nano-coils. In such a composition containing carbon nano-coils, a ratio of the contained carbon nano-coils may be at least 40 wt.% per the total of the carbon coils. Also the ratio of the contained conductive carbon included may be 0.1-15 pts.wt. more or less per the resin of 100 pts.wt. COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供组合具有导电性和透明性两者的导电组合物。导电组合物由至少由碳线圈构成的树脂和导电性碳构成。树脂可以由具有芴骨架的树脂（例如，具有芴骨架的聚酯类树脂）构成。碳线圈优选由碳纳米线圈构成。在这种含有碳纳米线圈的组合物中，所含的碳纳米线圈的比例可以相对于总共的碳线圈至少为40重量％。所含的导电性碳的比例也可以为0.1〜15重量份。或多或少每树脂100重量份版权所有（C）2008，JPO＆INPIT

100. 发明专利

JP2007302748A New biodegradable compatibilizer and resin composition comprising the same 有权
标题翻译：新的可生物降解的相容剂和包含其的树脂组合物
公开(公告)号：JP2007302748A
公开(公告)日：2007-11-22
申请号：JP2006130718
申请日：2006-05-09
申请人： Osaka Gas Co Ltd , 大阪瓦斯株式会社
发明人： KOBORI KANA , YAMADA MASAHIRO , KAWASAKI SHINICHI , SAKAMOTO HIRONORI , YAMAOKA HITOSHI , TANIMOTO TOMOHITO
IPC分类号： C08F290/06 , C08L101/00 , C08L101/16
摘要： PROBLEM TO BE SOLVED: To provide a vinylic polymer having biodegradability and improving compatibility of different kinds of polymers.
SOLUTION: The vinylic polymer having an epoxy group and an aliphatic polyester block chain in the side chain is prepared. The aliphatic polyester block chain may be a polylactone block chain obtained by carrying out ring opening polymerization of 3-12C lactones and the weight-average molecular weight thereof may be about 1,000 to 50×10
4 . The ratio (molar ratio) of the epoxy group to the aliphatic polyester block chain is about (5/1) to (10,000/1) of the former/latter. The vinylic polymer may be an acrylic graft copolymer of glycidyl (meth)acrylate and an acrylic macromonomer having the aliphatic polyester block chain as polymerizable components. The vinylic polymer has the biodegradability and is suitable as a compatibilizer.
COPYRIGHT: (C)2008,JPO&INPIT
摘要翻译：要解决的问题：提供具有生物降解性和提高不同种类的聚合物的相容性的乙烯基聚合物。解决方案：制备侧链中具有环氧基和脂族聚酯嵌段链的乙烯基聚合物。脂肪族聚酯嵌段链可以是通过进行3-12℃内酯的开环聚合而得到的聚内酯嵌段链，其重均分子量可以为约1000〜50×10 SP 3。环氧基与脂肪族聚酯嵌段链的比率（摩尔比）为前者/后者的约（5/1）〜（10,000 / 1）。乙烯基聚合物可以是（甲基）丙烯酸缩水甘油酯和具有脂肪族聚酯嵌段链作为可聚合成分的丙烯酸类大分子单体的丙烯酸接枝共聚物。乙烯基聚合物具有生物降解性，适合作为增容剂。版权所有（C）2008，JPO＆INPIT

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