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1. 发明专利

JP2007224451A Polyester fiber for resin-reinforced fabric 有权
标题翻译：用于树脂增强织物的聚酯纤维
公开(公告)号：JP2007224451A
公开(公告)日：2007-09-06
申请号：JP2006046786
申请日：2006-02-23
申请人： Teijin Techno Products Ltd , 帝人テクノプロダクツ株式会社
发明人： OKUMURA HISAO , TERASAKA FUYUKI , MAKINO SHOJI
IPC分类号： D03D1/00 , D01F6/62 , D06M15/55 , D06M101/32 , F16G1/28
摘要： PROBLEM TO BE SOLVED: To provide polyester fiber fully exerting its own performance in the form of a fiber-resin composite.
SOLUTION: The polyester fiber, which consists of polyethylene terephthalate, has a breaking tenacity of 7.0 cN/dtex or higher, an elongation at break of 13% or greater and a heat shrinkage of 0.1-5.0% at 230°C under a load of 0.10 cN/dtex, and also is characterized in being 0.05-1.0 wt.%, on a fiber weight basis, in epoxy compound pickup on the fiber surface. Besides, in the polyester fiber, it is preferable that the peak value of the heat shrinkage force be less than 0.15 cN/dtex at 200-230°C, the single filament fineness be 4.5-6.0 dtex and the single filament count be 190-250 fil.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供聚酯纤维以纤维树脂复合材料的形式充分发挥自身的性能。解决方案：由聚对苯二甲酸乙二醇酯组成的聚酯纤维在230℃下的断裂强度为7.0cN / dtex或更高，断裂伸长率为13％以上，热收缩率为0.1-5.0％负载为0.10cN / dtex，并且在纤维表面上的环氧化合物拾取中，其特征在于以纤维重量为基准的0.05-1.0重量％。此外，在聚酯纤维中，优选在200-230℃下，热收缩力的峰值小于0.15cN / dtex，单丝细度为4.5-6.0dtex，单丝数为190〜 250 fil。版权所有（C）2007，JPO＆INPIT

2. 发明专利

JP2006336131A Carbon fiber strand for reinforcing thermoplastic resin 审中-公开
标题翻译：用于增强热塑性树脂的碳纤维布
公开(公告)号：JP2006336131A
公开(公告)日：2006-12-14
申请号：JP2005160314
申请日：2005-05-31
申请人： Teijin Techno Products Ltd , 帝人テクノプロダクツ株式会社
发明人： MURAYAMA HISAMITSU , SHIRAKI KOJI , MAKINO SHOJI
IPC分类号： D06M15/227 , C08K9/04 , C08L23/10 , C08L101/00 , D06M101/40
摘要： PROBLEM TO BE SOLVED: To obtain a carbon fiber strand for reinforcing a thermoplastic resin, which is provided with a sizing agent having excellent affinity for and adhesiveness to a thermoplastic resin matrix and controls fiber breakage in kneading.
SOLUTION: The carbon fiber strand for reinforcing a thermoplastic resin is a carbon fiber strand which is adhered with a modified polyolefin copolymer that comprises at least one selected from an ethylene-propylene copolymer, a propylene-butene copolymer and an ethylene-propylene-butene copolymer as a main chain, is graft modified with 0.1-20% by mass of an unsaturated carboxylic acid and has 30-40% degree of crystallization measured by an FT-IR method. The coating weight of the modified copolymer is 0.5-10.0% by mass based on the carbon fiber. Since a carbon fiber-reinforced thermoplastic resin mixed with the carbon fiber strand has slight breakage of carbon fiber filament and the resin having high affinity for carbon fiber and a matrix resin is bonded to the filament, the carbon fiber strand has high mechanical strength such as flexural strength, etc.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：为了获得具有对热塑性树脂基体的亲和性和粘附性优异的上胶剂的热塑性树脂的增强用碳纤维束，控制捏合时的纤维断裂。解决方案：用于增强热塑性树脂的碳纤维线是碳纤维线，其与改性聚烯烃共聚物粘合，所述改性聚烯烃共聚物包括选自乙烯 - 丙烯共聚物，丙烯 - 丁烯共聚物和乙烯 - 丙烯中的至少一种丁烯共聚物作为主链，用0.1-20质量％的不饱和羧酸进行接枝改性，并通过FT-IR法测量结晶度为30-40％。改性共聚物的涂布重量相对于碳纤维为0.5〜10.0质量％。由于与碳纤维束混合的碳纤维增强热塑性树脂碳纤维丝具有轻微断裂，并且对碳纤维和基体树脂具有高亲和力的树脂与长丝结合，所以碳纤维股具有高的机械强度，例如弯曲强度等。版权所有（C）2007，JPO＆INPIT

3. 发明专利

JP2006291377A Carbon fiber strand for reinforcing thermoplastic resin 审中-公开
标题翻译：用于增强热塑性树脂的碳纤维布
公开(公告)号：JP2006291377A
公开(公告)日：2006-10-26
申请号：JP2005111095
申请日：2005-04-07
申请人： Teijin Techno Products Ltd , 帝人テクノプロダクツ株式会社
发明人： MURAYAMA HISAMITSU , SHIRAKI KOJI , MAKINO SHOJI
IPC分类号： D06M15/227 , B29B15/08 , B29K307/04 , D06M101/40
摘要： PROBLEM TO BE SOLVED: To provide a carbon fiber strand for reinforcing a thermoplastic resin and for preventing the breakage of the fiber at kneading with a thermoplastic resin matrix.
SOLUTION: The carbon fiber strand for reinforcing the thermoplastic resin has ≥70 mJ/1,000 filaments breaking energy measured by a tensile tester of the carbon fiber strand obtained by imparting a sizing agent, and ≥9 MPa interfacial adhesion strength measured by a micro droplet test measured by attaching a prescribed polypropylene resin to the monofilament. A modified polyolefin resin containing at least one kind selected from a polypropylene, an ethylene-propylene copolymer, a propylene-butene copolymer and a ethylene-propylene-butene copolymer as a main chain, and graft-modified with 0.1-20 mass% unsaturated carboxylic acids is preferably used as the sizing agent.
COPYRIGHT: (C)2007,JPO&INPIT
摘要翻译：要解决的问题：提供一种用于增强热塑性树脂的碳纤维股线，并且防止在与热塑性树脂基体捏合时纤维的断裂。解决方案：用于增强热塑性树脂的碳纤维束具有通过赋予施胶剂而获得的碳纤维线的拉伸试验机测得的≥70mJ/ 1,000丝断裂能，以及由通过将规定的聚丙烯树脂附着到单丝来测量微滴试验。包含选自聚丙烯，乙烯 - 丙烯共聚物，丙烯 - 丁烯共聚物和乙烯 - 丙烯 - 丁烯共聚物中的至少一种作为主链的改性聚烯烃树脂，并用0.1-20质量％的不饱和羧酸接枝改性酸优选用作施胶剂。版权所有（C）2007，JPO＆INPIT

4. 发明专利

JP2006233379A Polyalkylene naphthalate fiber for reinforcing thermoplastic resin 有权
标题翻译：用于增强热塑性树脂的聚亚烷基亚磺酸纤维
公开(公告)号：JP2006233379A
公开(公告)日：2006-09-07
申请号：JP2005050986
申请日：2005-02-25
申请人： Teijin Techno Products Ltd , 帝人テクノプロダクツ株式会社
发明人： TAKAHASHI SHINICHI , MAKINO SHOJI
IPC分类号： D06M15/227 , C08J5/06 , C08L23/00 , D01F6/62 , D06M13/224
摘要： PROBLEM TO BE SOLVED: To provide a polyalkylene naphthalate fiber for reinforcing a thermoplastic resin having excellent heat resistance, scarcely causing mechanical deterioration and having excellent impact resistance when converted into a fiber-reinforced resin composition and affording a thermoplastic resin having excellent recyclability.
SOLUTION: The fiber is obtained by applying a polyolefin resin in an amount of 0.2-2.0 wt% and a lubricant and an emulsifying agent in the total amount of 0.05-1.0 wt% based on the fiber weight to the surface of the polyalkylene naphthalate fiber having 2-8 dtex single fiber fineness. Furthermore, the intrinsic viscosity of the fiber is preferably ≥0.7 and the dry heat shrinkage percentage at 180°C is preferably ≤8%. The polyalkylene naphthalate preferably consists essentially of ethylene-2,6-naphthalate and the polyolefin resin is preferably an acid-modified polyolefin resin.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种用于增强耐热性优异的热塑性树脂的聚萘二甲酸亚烷基酯纤维，几乎不引起机械劣化，并且当转化为纤维增强树脂组合物时具有优异的耐冲击性，并提供具有优异的可回收性的热塑性树脂。解决方案：通过将0.2-2.0重量％的聚烯烃树脂和基于纤维重量的润滑剂和乳化剂的总量为0.05-1.0重量％施加到表面上而获得纤维聚萘二甲酸亚烷基酯纤维具有2-8分特单纤维细度。此外，纤维的特性粘度优选≥0.7，180℃下的干热收缩率优选≤8％。聚萘二甲酸亚烷基酯优选基本上由2,6-萘二甲酸乙烯酯组成，聚烯烃树脂优选为酸改性聚烯烃树脂。版权所有（C）2006，JPO＆NCIPI

5. 发明专利

JP2005220457A Pretreated polyester fiber for rubber reinforcement 有权
标题翻译：用于橡胶加固的预制聚酯纤维
公开(公告)号：JP2005220457A
公开(公告)日：2005-08-18
申请号：JP2004027672
申请日：2004-02-04
申请人： Teijin Techno Products Ltd , 帝人テクノプロダクツ株式会社
发明人： SHIMADA SHINTARO , MAKINO SHOJI
IPC分类号： B60C9/00 , D06M13/11 , D06M13/325 , D06M101/32
摘要： PROBLEM TO BE SOLVED: To obtain a pretreated polyester fiber that has excellent process passage in a post-processing and stable qualities in adhesion to rubber. SOLUTION: The pretreated polyester fiber for rubber reinforcement is a polyester fiber provided with an aliphatic amine compound and an epoxy compound on the surface, has ≤1.0×10 -3 equivalent/kg epoxy index (EI) of the fiber and the value of a ratio C/O of a carbon atom (C) to an oxygen atom (O) constituting the surface of the fiber of 3.0-3.5. Preferably the aliphatic amine compound is an adduct of ethylene oxide and/or propylene oxide and the epoxy compound contains two or more epoxy groups in one molecule. COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：获得在后处理中具有优异的工艺通道并且具有稳定的与橡胶粘合性质的预处理的聚酯纤维。解决方案：用于橡胶增强的预处理聚酯纤维是在表面上具有脂族胺化合物和环氧化合物的聚酯纤维，具有≤1.0×10 -3 当量/ kg环氧树脂指数 EI）和碳原子（C）与构成纤维表面的氧原子（O）的C / O比为3.0-3.5的值。优选地，脂族胺化合物是环氧乙烷和/或环氧丙烷的加合物，环氧化合物在一个分子中含有两个或更多个环氧基。版权所有（C）2005，JPO＆NCIPI

6. 发明专利

JP2006207073A Carbon fiber strand for reinforcing thermoplastic resin 审中-公开
标题翻译：用于增强热塑性树脂的碳纤维布
公开(公告)号：JP2006207073A
公开(公告)日：2006-08-10
申请号：JP2005021263
申请日：2005-01-28
申请人： Teijin Techno Products Ltd , 帝人テクノプロダクツ株式会社
发明人： MURAYAMA HISAMITSU , SHIRAKI KOJI , MAKINO SHOJI
IPC分类号： D06M15/227 , B29B15/08 , C08K9/04 , C08L23/12 , C08L101/00 , D06M101/40
摘要： PROBLEM TO BE SOLVED: To provide a carbon fiber strand for reinforcing thermoplastic resins, excellent in affinity for the thermoplastic resins such as polypropylene.
SOLUTION: The carbon fiber strand for reinforcing thermoplastic resins is obtained by imparted with 0.1-5.0 mass% modified polyethylene having 20-80 acid value and 1,000-10,000 number-average molecular weight based on carbon fiber, wherein the strand has ≤150 mm horizontal distance X in drapability evaluation test. The carbon fiber strand has good treatability and is excellent in affinity and adhesion to thermoplastic resins especially polypropylene. The carbon fiber-reinforced thermoplastic resin obtained by compounded with the carbon fiber strand of 5-70 mass% in a thermoplastic resin is excellent in mechanical properties such as flexural strength.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种用于增强热塑性树脂的碳纤维束，对聚丙烯等热塑性树脂的亲和性优异。解决方案：用于增强热塑性树脂的碳纤维股是通过赋予0.1-5.0质量％的具有20-80酸值的改性聚乙烯和基于碳纤维的1,000-10,000数均分子量而得到的，悬垂性评价试验中的150mm水平距离X。碳纤维束具有良好的处理性，并且对热塑性树脂，特别是聚丙烯的亲和性和粘合性优异。通过与热塑性树脂中的5-70质量％的碳纤维束混合而得到的碳纤维增强热塑性树脂，具有优异的机械性能如弯曲强度。版权所有（C）2006，JPO＆NCIPI

7. 发明专利

JP2006022441A Carbon fiber for reinforcing thermoplastic resin 审中-公开
标题翻译：碳纤维增强热塑性树脂
公开(公告)号：JP2006022441A
公开(公告)日：2006-01-26
申请号：JP2004202302
申请日：2004-07-08
申请人： Teijin Techno Products Ltd , 帝人テクノプロダクツ株式会社
发明人： SHIRAKI KOJI , MURAYAMA HISAMITSU , MAKINO SHOJI
IPC分类号： D06M13/02 , C08J5/06 , C08L23/10 , D06M101/40
摘要： PROBLEM TO BE SOLVED: To provide carbon fiber for reinforcing a thermoplastic resin, high in adhesivity to the thermoplastic resin, openability and fretting resistance.
SOLUTION: The carbon fiber is such as to be imparted with a sizing agent containing ≥50 mass% of a mineral oil. In the carbon fiber, the dynamic viscosity of the mineral oil is preferably 15-125 mm
2 /s at 30°C and the pickup of the sizing agent is preferably 0.1-5.0 mass% based on the carbon fiber. The carbon fiber is high in affinity for thermoplastic resins, especially polypropylene, and a carbon fiber-reinforced thermoplastic resin obtained by compounding 5-70 mass% of the carbon fiber in the corresponding thermoplastic resin is excellent in mechanical properties including flexural strength.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供用于增强热塑性树脂的碳纤维，对热塑性树脂的粘合性高，开放性和耐磨性。解决方案：将碳纤维赋予含有≥50质量％矿物油的施胶剂。在碳纤维中，30℃下的矿物油的动态粘度优选为15〜125mm×SP 2 /秒，上胶剂的收率优选为0.1〜5.0质量％纤维。碳纤维对热塑性树脂，特别是聚丙烯的亲和性高，通过在相应的热塑性树脂中配合5-70质量％的碳纤维而获得的碳纤维增强热塑性树脂具有优异的机械性能，包括弯曲强度。版权所有（C）2006，JPO＆NCIPI

8. 发明专利

JP2005256206A Carbon fiber, carbon fiber-reinforced thermoplastic resin and method for producing carbon fiber 有权
标题翻译：碳纤维，碳纤维增强热塑性树脂和碳纤维生产方法
公开(公告)号：JP2005256206A
公开(公告)日：2005-09-22
申请号：JP2004067906
申请日：2004-03-10
申请人： Teijin Techno Products Ltd , 帝人テクノプロダクツ株式会社
发明人： SHIRAKI KOJI , MURAYAMA HISAMITSU , MAKINO SHOJI
IPC分类号： D06M15/227 , D06M15/27 , D06M101/40
摘要： PROBLEM TO BE SOLVED: To provide a thermoplastic resin-reinforcing carbon fiber imparted with a sizing agent excellent in bonding property with a polypropylene resin matrix.
SOLUTION: This thermoplastic-reinforcing carbon fiber is obtained by imparting a modified polyolefin resin having at least 1 kind selected from an ethylene-propylene copolymer, a propylene-butene copolymer, and an ethylene-propylene-butene copolymer as a main chain, graft-modified by maleic acid anhydride and a (meth)acrylic acid ester and having 15,000-150,000 weight-average molecular weight. A polypropylene resin is reinforced by using the carbon fiber.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：提供赋予与聚丙烯树脂基质结合性优异的上浆剂的热塑性树脂增强碳纤维。解决方案：该热塑性增强碳纤维通过赋予选自乙烯 - 丙烯共聚物，丙烯 - 丁烯共聚物和乙烯 - 丙烯 - 丁烯共聚物中的至少1种的改性聚烯烃树脂作为主链而获得，由马来酸酐和（甲基）丙烯酸酯接枝改性并具有15,000-150,000重均分子量。通过使用碳纤维来增强聚丙烯树脂。版权所有（C）2005，JPO＆NCIPI

9. 发明专利

JP2005002517A Method for producing thermoplastic synthetic fiber 审中-公开
标题翻译：生产热塑性合成纤维的方法
公开(公告)号：JP2005002517A
公开(公告)日：2005-01-06
申请号：JP2003168910
申请日：2003-06-13
申请人： Teijin Techno Products Ltd , 帝人テクノプロダクツ株式会社
发明人： YAMAGUCHI YORIHISA , TAKIGAMI KOTARO , MAKINO SHOJI
IPC分类号： D06M11/79 , D02J1/22 , D06M11/00 , D06M11/05 , D06M11/72 , D06M23/08
摘要： PROBLEM TO BE SOLVED: To provide a production method for obtaining high-quality fiber having good processability by efficiently removing inorganic fine powder applied to the fiber in order to prevent fusion between single fibers which occurs when thermally drawing and/or heat-treating the fiber under high temperature and improve yarn-making properties after thermal drawing and/or heat treatment.
SOLUTION: The method for producing the thermoplastic synthetic fiber comprises applying inert inorganic fine powder to undrawn fiber composed of a thermoplastic synthetic polymer, thermally drawing and/or heat-treating the fine powder-coated fiber, applying an aqueous solution of surfactant having action for swelling the inorganic fine powder to the drawn and heat-treated fiber, blowing fluid thereto and removing the inorganic fine powder attached to the fiber.
COPYRIGHT: (C)2005,JPO&NCIPI
摘要翻译：要解决的问题：为了提供通过有效地除去施加到纤维上的无机细粉而获得具有良好加工性的高品质纤维的制造方法，以防止当热拉伸和/或热处理时发生的单个纤维之间的熔合，在高温下处理纤维，并且在热拉伸和/或热处理后提高纱线制造性能。解决方案：制造热塑性合成纤维的方法包括将惰性无机细粉末施加到由热塑性合成聚合物构成的未拉伸纤维上，对细粉末涂覆纤维进行热拉伸和/或热处理，施加表面活性剂水溶液具有使无机细粉膨胀到拉伸和热处理的纤维的作用，向其中吹送流体并除去附着在纤维上的无机细粉末。版权所有（C）2005，JPO＆NCIPI

10. 发明专利

JP2006089614A Carbon fiber strand for thermoplastic resin reinforcement 审中-公开
标题翻译：用于热塑性树脂增强的碳纤维条
公开(公告)号：JP2006089614A
公开(公告)日：2006-04-06
申请号：JP2004277175
申请日：2004-09-24
申请人： Teijin Techno Products Ltd , 帝人テクノプロダクツ株式会社
发明人： SHIRAKI KOJI , MURAYAMA HISAMITSU , MAKINO SHOJI
IPC分类号： C08J5/06 , C08K9/04 , C08L23/10 , C08L101/00 , D06M15/227
摘要： PROBLEM TO BE SOLVED: To provide a carbon fiber strand for thermoplastic resin reinforcement, having excellent adhesiveness to thermoplastic resins and good openability and scratch resistance.
SOLUTION: The carbon fiber strand for thermoplastic resin reinforcement is coated with polypropylene, polybutene, an ethylene-propylene copolymer, a propylene-butene copolymer, an ethylene-propylene-butene copolymer or their terminal modified polymers having a number-average molecular weight of 300-2,000 or their mixture. The amount of the polypropylene, etc. applied to the strand is preferably 0.05-5.0 mass% in total based on the carbon fiber. The carbon fiber strand has excellent affinity and adhesiveness to thermoplastic resins, especially polypropylene. A carbon fiber-reinforced thermoplastic resin containing 5-70 mass% carbon fiber strand of the invention has excellent mechanical properties such as interlaminar shear strength.
COPYRIGHT: (C)2006,JPO&NCIPI
摘要翻译：要解决的问题：提供一种用于热塑性树脂增强物的碳纤维股线，其与热塑性树脂的粘合性优异，并且具有良好的开放性和耐划伤性。解决方案：用于热塑性树脂增强材料的碳纤维股用聚丙烯，聚丁烯，乙烯 - 丙烯共聚物，丙烯 - 丁烯共聚物，乙烯 - 丙烯 - 丁烯共聚物或其末端改性聚合物涂覆数均分子重量为300-2,000或其混合物。基于碳纤维，施加于线材的聚丙烯等的量优选为0.05〜5.0质量％。碳纤维股线对热塑性树脂，特别是聚丙烯具有优异的亲和性和粘合性。含有本发明的5-70质量％碳纤维束的碳纤维增强热塑性树脂具有优异的机械性能，例如层间剪切强度。版权所有（C）2006，JPO＆NCIPI

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