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    • 3. 发明专利
    • SEALED NICKEL HYDROGEN BATTERY
    • JPH10162815A
    • 1998-06-19
    • JP32300096
    • 1996-12-03
    • TOSHIBA BATTERY
    • HATA KATSUYUKISATO TSUTOMU
    • H01M4/62H01M4/24H01M10/30
    • PROBLEM TO BE SOLVED: To provide an electrode which can prevent fibers from projecting to an outside surface and has high strength and has stable performance by setting curled conductive fibers to be contained in a paste electrode to a length of a specific range, and forming notch parts in the lengthwise direction. SOLUTION: Conductive fibers 8 which have a length of 5 to 20mm and whose cross section is polygonal are curled, and are used for a paste electrode, and fluffy softness and a thickness are imparted, and tip parts of the fibers are made hard to project outside a sheet, and a length is set to this range, and a crack is eliminated at sheet winding time, and the fibers are not locally gathered, and are uniformly dispersed. Notch parts 9 are formed on the fibers whose cross section is polygonal, and the fibers are made mutually entangled, and thickness directional strength of the sheet is increased, and they are made untearable. Therefore, an active material can be sufficiently filled, and current collecting efficiency is enhanced, and short-circuiting by projection of the fibers is eliminated, and a sealed nickel hydrogen battery having an electrode which has high strength and stable performance, can be obtained.
    • 7. 发明专利
    • Manufacture of nickel hydrogen secondary battery
    • 镍氢二次电池的制造
    • JP2000077065A
    • 2000-03-14
    • JP24475398
    • 1998-08-31
    • Toshiba Battery Co Ltd東芝電池株式会社
    • TAKAHASHI HIROYUKISATO TSUTOMUTAKAHASHI TATSU
    • H01M4/38H01M4/26H01M4/62
    • Y02E60/124Y02P70/54
    • PROBLEM TO BE SOLVED: To suppress an increase in inner pressure in overcharge at a low production cost by manufacturing a negative electrode in a process applying paste containing a hydrogen storage alloy having a fluorine compound and a carbon material on the surface to a current collector.
      SOLUTION: A negative electrode is manufactured in such a way that paste is prepared by adding a binder and a conductive material to hydrogen storage alloy powder having a fluorine compound and a carbon material on the surface, kneading them together with water, the paste is applied to a current collector, dried, then they are rolled. The fluorine compound forms a water repellent interface against an electrolyte on the alloy surface to ensure the contact of the alloy metal surface and a gas phase, and oxygen gas absorbing performance of the alloy is enhanced. As the fluorine compound, PTFE is listed. The content of the fluorine compound is preferable to be 0.1-2.0 wt.% based on the weight of the alloy. The carbon material enhances oxygen gas reduction capability of the alloy, and carbon black and graphite are listed. The content of the carbon material is preferable to be 0.1-2.0 wt.% based on the weight of the alloy.
      COPYRIGHT: (C)2000,JPO
    • 要解决的问题:通过在包含表面上含有氟化合物和碳材料的储氢合金的糊剂中将负极制造成集电体,以低的制造成本来抑制过充电中的内压增加。 解决方案:制造负极,通过向表面上具有氟化合物和碳材料的储氢合金粉末中加入粘合剂和导电材料来制备糊料,并将其与水一起捏合,施加糊料 到集电器,干燥,然后它们被滚动。 氟化合物与合金表面上的电解质形成防水界面,以确保合金金属表面与气相的接触,并提高合金的氧气吸收性能。 作为氟化合物,列出了PTFE。 相对于合金的重量,氟化合物的含量优选为0.1〜2.0重量%。 碳素材料可提高合金的氧气还原能力,并列出炭黑和石墨。 相对于合金的重量,碳材料的含量优选为0.1〜2.0重量%。
    • 8. 发明专利
    • MANUFACTURE OF NICKEL HYDROGEN SECONDARY BATTERY
    • JPH10116626A
    • 1998-05-06
    • JP27006296
    • 1996-10-11
    • TOSHIBA BATTERY
    • YUKIZONO TOSHIJITAKAHASHI HIROYUKITAKAHASHI TATSUSATO TSUTOMU
    • H01M4/26H01M10/28H01M10/30
    • PROBLEM TO BE SOLVED: To provide a manufacturing method of a nickel hydrogen secondary battery in which the occurrence of failure resulting from the separation of negative electrode layers of the winding-start end portion and the winding-end end portion side of a negative electrode in an electrode group manufacturing process. SOLUTION: A separator 6 is caused to intervene between a positive electrode 7 and a negative electrode 5 in which a punched metal board is coated by a negative electrode layer containing hydrogen storage alloy so as to laminate, the laminated matter thereof is spiral-like wound so that the negative electrode 5 is positioned outside in one pair of electrode group hold block, the outer peripheral face of the spiral electrode group is held by the one pair of blocks, and further the electrode group 8 is contained in a cylindrical vessel with bottom so as to manufacture an alkaline secondary battery. In the manufacturing method of the same, the negative electrode 5 is formed by coating the punched metal board having no punched plain portions on a winding-start end portion and a winding-end end portion side with the negative electrode layer containing the hydrogen storage alloy excluding at least one part or all of the winding-end side plain portion out of the plain portions.