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1. 发明专利

JP2009256519A Chemical thermal storage medium composite and method for producing the same 审中-公开
标题翻译：化学热储存介质复合材料及其生产方法
公开(公告)号：JP2009256519A
公开(公告)日：2009-11-05
申请号：JP2008109386
申请日：2008-04-18
申请人： Oumi Kogyo Kk , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , 近江鉱業株式会社
发明人： SOFUGAWA HIDEO , SHIMAZU TAKASHI , MITSUI HIROYUKI , FUKUSHIMA YOSHIAKI , WAKAYAMA HIROAKI , ITAHARA HIROYUKI , FUJIMURA TAKATSUNE
IPC分类号： C09K5/08 , C09K5/16
摘要： PROBLEM TO BE SOLVED: To provide a chemical thermal storage medium composite capable of repeating heat storage and heat radiation for a long period of time stably, and a method for producing the same. SOLUTION: This chemical thermal storage medium composite is obtained by performing a mixing process and a baking process, and the method for producing the same is also provided. In the mixing process, a mixture M is obtained by mixing a powdery first chemical thermal storage medium 110 consisting of an oxide of the chemical thermal storage medium becoming the oxide accompanying with a dehydration reaction and becoming a hydroxide accompanying with a hydration reaction, with a powdery second thermal storage medium 111 consisting of the chemical thermal storage medium other than the oxide, a clay mineral 12 and water. In the baking process, by baking the mixture M, the chemical thermal storage medium composite 1 is obtained. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决的问题：提供能够长时间稳定地重复蓄热和热辐射的化学蓄热介质复合体及其制造方法。解决方案：通过进行混合处理和烘烤处理获得该化学蓄热介质复合体，并且还提供了其制造方法。在混合过程中，通过将由化学热存储介质的氧化物组成的粉末状第一化学热存储介质110与伴随脱水反应的氧化物混合并变成伴随水合反应的氢氧化物，得到混合物M，由氧化物以外的化学热存储介质，粘土矿物12和水组成的粉状第二蓄热介质111。在烘烤过程中，通过烘烤混合物M，得到化学蓄热介质复合体1。版权所有（C）2010，JPO＆INPIT

2. 发明专利

JP2009256517A Chemical heat storage material and production method thereof 有权
标题翻译：化学储热材料及其生产方法
公开(公告)号：JP2009256517A
公开(公告)日：2009-11-05
申请号：JP2008109384
申请日：2008-04-18
申请人： Oumi Kogyo Kk , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , 近江鉱業株式会社
发明人： WAKAYAMA HIROAKI , SHIMAZU TAKASHI , FUKUSHIMA YOSHIAKI , SOFUGAWA HIDEO , MITSUI HIROYUKI , ITAHARA HIROYUKI , FUJIMURA TAKATSUNE
IPC分类号： C09K5/08 , C09K5/16 , F28D20/00
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical heat storage material excellent in durability and capable of exercising fully the ability thereof as a chemical heat storage system; and a production method thereof. SOLUTION: This chemical heat storage material has: a basket-shaped structure 5 having a large number of pores which is obtained by calcining a mixture of a clay mineral 2 and a combustible granular substance 3; and a chemical heat storage material 6 supported on the outer surface and in the inside of pores of the basket-shaped structure 5. The combustible granular substance 3 is preferably one type or two or more types of a coconut, a chip, a carbon black and a ketjen black. The clay mineral 2 is preferably sepiolite and/or palygorskite. The chemical heat storage material 6 is preferably a hydration reaction-type chemical heat storage material converted into an oxide according to a dehydration reaction and converted into a hydroxide according to a hydration reaction. The chemical heat storage material is preferably produced by further incorporating a thermal conductivity-enhancing material. The thermal conductivity-enhancing material is preferably a carbon nanotube. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供耐久性优异并能充分发挥化学蓄热系统的能力的化学蓄热材料; 及其制造方法。解决方案：该化学蓄热材料具有：通过煅烧粘土矿物2和可燃颗粒物质3的混合物获得的具有大量孔的篮形结构5; 以及支撑在篮状结构体5的孔的外表面和内部的化学储热材料6.可燃性颗粒状物质3优选为椰子，芯片，炭黑的一种或两种以上和科琴黑。粘土矿物2优选为海泡石和/或坡缕石。化学蓄热材料6优选为根据脱水反应转化成氧化物并根据水合反应转化为氢氧化物的水合反应型化学蓄热材料。化学蓄热材料优选通过进一步掺入导热性增强材料来制造。导热性增强材料优选为碳纳米管。版权所有（C）2010，JPO＆INPIT

3. 发明专利

JP2009228952A Chemical thermal storage material composite, thermal storage device using it, and its manufacturing method 有权
标题翻译：化学热存储材料复合材料，使用它的热存储器件及其制造方法
公开(公告)号：JP2009228952A
公开(公告)日：2009-10-08
申请号：JP2008073490
申请日：2008-03-21
申请人： Oumi Kogyo Kk , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , 近江鉱業株式会社
发明人： FUKUSHIMA YOSHIAKI , SHIMAZU TAKASHI , WAKAYAMA HIROAKI , SOFUGAWA HIDEO , MITSUI HIROYUKI , ITAHARA HIROYUKI , FUJIMURA TAKATSUNE
IPC分类号： F28D20/00 , C09K5/16 , F28D7/10
CPC分类号： Y02E60/142 , Y02E70/30
摘要： PROBLEM TO BE SOLVED: To provide a chemical thermal storage material composite with superior thermal storage/radiation performance, heat transfer performance, and high durability. SOLUTION: The chemical thermal storage material composite 1 contains: a powder chemical thermal storage material 11; and an expanding material foam 12 comprised by foaming and expanding a foaming and expanding material placed adjacent to the chemical thermal storage material 11 by applying a predetermined foaming starting treatment. The thermal storage device 10 has a wall body 20 partitioning a thermal storage material housing part 32, and the chemical thermal storage material composite 1 housed in the thermal storage material housing part 32. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供具有优良的储热性能，传热性能和高耐久性的化学储热材料复合材料。化学蓄热材料复合材料1包含：粉末化学蓄热材料11; 以及膨胀材料泡沫12，其通过施加预定的发泡起始处理来发泡和膨胀放置在化学蓄热材料11附近的发泡和膨胀材料。蓄热装置10具有分隔蓄热材料容纳部32的壁体20和容纳在蓄热材料容纳部32中的化学蓄热材料复合体1.（C）2010，JPO＆INPIT

4. 发明专利

JP2009227772A Chemical heat storage material composite and method of manufacturing the same 有权
标题翻译：化学储热材料复合材料及其制造方法
公开(公告)号：JP2009227772A
公开(公告)日：2009-10-08
申请号：JP2008073487
申请日：2008-03-21
申请人： Oumi Kogyo Kk , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , 近江鉱業株式会社
发明人： SHIMAZU TAKASHI , MITSUI HIROYUKI , FUKUSHIMA YOSHIAKI , SOFUGAWA HIDEO , WAKAYAMA HIROAKI , ITAHARA HIROYUKI , FUJIMURA TAKATSUNE
IPC分类号： C09K5/08 , C09K5/16
摘要： PROBLEM TO BE SOLVED: To provide a chemical heat storage material composite which stably performs repetition of heat storage and heat radiation for a long period of time and to provide a method of manufacturing the same. SOLUTION: In the chemical heat storage material composition 1 having at least a chemical heat storage material 11 and a clay mineral 12, particles of the clay mineral 12 are dispersed in at least a part between primary particles of the chemical heat storage material 11. In the method of manufacturing the same, at least a hydration reaction step for mixing a powdery chemical heat storage material oxide, the clay mineral, ammonia or a water soluble organic compound having a polar functional group and water is performed. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种能够长时间稳定地进行蓄热和热辐射重复的化学蓄热材料复合体，并提供其制造方法。解决方案：在至少具有化学蓄热材料11和粘土矿物12的化学储热材料组合物1中，粘土矿物12的颗粒至少部分分散在化学储热材料的初级颗粒之间在其制造方法中，至少进行用于混合粉状化学蓄热材料氧化物，粘土矿物，氨或具有极性官能团的水溶性有机化合物和水的水合反应步骤。版权所有（C）2010，JPO＆INPIT

5. 发明专利

JP2009222273A Method of manufacturing chemical heat storage material molded product 有权
标题翻译：制造化学热储存材料成型产品的方法
公开(公告)号：JP2009222273A
公开(公告)日：2009-10-01
申请号：JP2008065543
申请日：2008-03-14
申请人： Oumi Kogyo Kk , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , 近江鉱業株式会社
发明人： MITSUI HIROYUKI , SHIMAZU TAKASHI , SOFUGAWA HIDEO , FUKUSHIMA YOSHIAKI , WAKAYAMA HIROAKI , ITAHARA HIROYUKI , FUJIMURA TAKATSUNE
IPC分类号： F28D20/00 , C09K5/08
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a method of manufacturing a chemical heat storage material molded product suppressed in the occurrence of deformation and cracks. SOLUTION: This manufacturing method includes the steps of: molding a mixed material 11 formed by mixing at least a clay mineral and water with a powdery chemical heat storage material into a desired hollow molded product 1; and drying the hollow molded product 1 in a state of a porous core material 2 inserted in a hollow part 12 formed to penetrate the hollow molded product 1, and the outer peripheral face of the core material in contact with the inner peripheral face of the hollow part. The core material 2 is preferably composed of a baked ceramic material. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：待解决的问题：提供抑制发生变形和裂纹的化学蓄热材料成型体的制造方法。解决方案：该制造方法包括以下步骤：将通过将至少一种粘土矿物和水与粉末状化学储热材料混合而形成的混合材料11成型为所需的中空成型体1; 并将中空成型体1以插入形成为中空成型体1的中空部12的多孔芯材2的状态干燥，芯材的外周面与中空部的内周面接触部分。芯材2优选由烘烤的陶瓷材料构成。版权所有（C）2010，JPO＆INPIT

6. 发明专利

JP2014185782A Filter, chemical heat storage reactor, and chemical heat storage system 有权
标题翻译：过滤器，化学储热反应器和化学储热系统
公开(公告)号：JP2014185782A
公开(公告)日：2014-10-02
申请号：JP2013058985
申请日：2013-03-21
申请人： Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , Oumi Kogyo Kk , 近江鉱業株式会社
发明人： MOCHIZUKI MIYO , MITSUI HIROYUKI , SHIMAZU TAKASHI , ITAHARA HIROYUKI , FUJIMURA TAKATSUNE
IPC分类号： F28D20/00
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To suppress the entry of powder into a flow path for water vapor.SOLUTION: A unit filter 40A formed of a metallic fiber sintered body has a bottom part 44A placed between a flow path 23 for water vapor W and a heat storage material 30, and a peripheral wall part 45A integrated with the bottom part 44A at a peripheral edge thereof to encircle the heat storage material 30. Here, when the heat storage material 30 is expanded or so and part thereof is changed into powder P, the bottom part 44A of the unit filter 40A restricts the entry of the powder P. Besides, at the peripheral edge of the bottom part 44A, the peripheral wall part 45A suppresses the turn-around of the powder P into the flow path 23. This suppresses the entry of the powder P into the flow path 23.
摘要翻译：要解决的问题：抑制粉末进入水蒸汽流路。解决方案：由金属纤维烧结体形成的单元过滤器40A具有底部44A，其设置在水蒸气W的流路23和热量存储材料30以及在其周边部与底部44A一体化的周壁部45A，以包围蓄热材料30.这里，当蓄热材料30膨胀等，其一部分变成粉末P时，单元过滤器40A的底部44A限制粉末P的进入。此外，在底部44A的周缘处，周壁部45A抑制粉末P向流路23的转过。抑制粉末P进入流路23。

7. 发明专利

JP2009257686A Chemical heat-storage system 有权
标题翻译：化学储热系统
公开(公告)号：JP2009257686A
公开(公告)日：2009-11-05
申请号：JP2008108580
申请日：2008-04-18
申请人： Oumi Kogyo Kk , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , 近江鉱業株式会社
发明人： SHIMAZU TAKASHI , MITSUI HIROYUKI , FUKUSHIMA YOSHIAKI , SOFUGAWA HIDEO , WAKAYAMA HIROAKI , ITAHARA HIROYUKI , FUJIMURA TAKATSUNE
IPC分类号： F28D20/00
CPC分类号： Y02A30/277 , Y02B30/62 , Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical heat-storage system reducing carbon dioxide reacting with chemical heat storage medium in a closed system.
SOLUTION: This chemical heat-storage system 10 includes a reaction section 16 filled with the chemical heat-storage medium 14 for storing heat by causing dehydration reaction by heating and dissipating heat by causing hydration reaction, and an evaporator/condenser 34 airtightly communicating with the reaction section 16. The evaporator/condenser 34 has a function of condensing vapor produced from the reaction section 16 due to the hydration reaction, a function of reserving condensed water, and a function of evaporating water in a reservoir to produce vapor to be supplied to the reaction section 16. A carbon dioxide adsorbing filter 46 with lithium silicate internally sealed for absorbing carbon dioxide in the vapor is provided in a vapor circulation passage 42 connecting the reactor 16 to the evaporator/condenser 34. Methyldiethanolamine for absorbing carbon dioxide in water is added into the water reserved in the liquid phase portion 36B of the evaporator-condenser 34.
COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供一种在封闭系统中减少与化学蓄热介质反应的二氧化碳的化学蓄热系统。解决方案：该化学蓄热系统10包括：反应部分16，填充有化学蓄热介质14，用于通过加热引起的脱水反应并通过引起水合反应而散热，并将蒸发器/冷凝器34气密地与反应部分16连通。蒸发器/冷凝器34具有由于水合反应而产生的由反应部分16产生的蒸汽，保留冷凝水的功能，以及蒸发储存器中的水以产生蒸气的功能的功能供给到反应部分16.在将反应器16连接到蒸发器/冷凝器34的蒸气循环通道42中设置内部密封有用于吸收蒸气中二氧化碳的硅酸锂的二氧化碳吸附过滤器46。用于吸收二氧化碳的甲基二乙醇胺在水中加入保留在蒸发器 - 冷凝器34的液相部分36B中的水中 HT：（C）2010，JPO＆INPIT

8. 发明专利

JP2009256518A Chemical heat storage material, chemical heat storage material molded article, and production methods thereof 有权
标题翻译：化学热储存材料，化学储热材料成型品及其生产方法
公开(公告)号：JP2009256518A
公开(公告)日：2009-11-05
申请号：JP2008109385
申请日：2008-04-18
申请人： Oumi Kogyo Kk , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , 近江鉱業株式会社
发明人： WAKAYAMA HIROAKI , SHIMAZU TAKASHI , FUKUSHIMA YOSHIAKI , SOFUGAWA HIDEO , MITSUI HIROYUKI , ITAHARA HIROYUKI , FUJIMURA TAKATSUNE
IPC分类号： C09K5/08 , C01B31/02 , C01B33/40 , C09K5/16
摘要： PROBLEM TO BE SOLVED: To provide: a chemical heat storage material having water repelling property and capable of suppressing a pulverization of the chemical heat storage material according to a hydration/dehydration reaction and of exercising fully an ability thereof as a chemical heat storage system; a chemical heat storage material molded article; and production methods thereof. SOLUTION: This chemical heat storage material is produced by forming a carbide structure 3 produced by disposing a refractory organic substance 31 on at least a part of the surface of a powder chemical heat storage material 2 and by calcining the resultant laminate in an inactive atmosphere. The refractory organic substance 31 is preferably polysuccharides. The refractory organic substance 31 is preferably hydrophilic. The chemical heat storage material 2 is preferably a hydration reaction-type chemical heat storage material converted into an oxide according to a dehydration reaction and converted into a hydroxide according to a hydration reaction. The chemical heat storage material 2 preferably contains further a clay mineral. The clay mineral is preferably sepiolite and/or palygorskite. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：要解决的问题：提供：具有防水性能并且能够根据水合/脱水反应抑制化学储热材料的粉碎并充分发挥作为化学热的能力的化学蓄热材料存储系统; 化学蓄热材料成型品; 及其制造方法。解决方案：该化学蓄热材料是通过在粉末化学储热材料2的表面的至少一部分上设置耐火有机物31而形成的碳化物结构体3，通过在不活跃的气氛耐火有机物质31优选为聚蔗糖。难熔有机物质31优选为亲水性的。化学蓄热材料2优选为根据脱水反应转化为氧化物的水合反应型化学蓄热材料，并根据水合反应转化为氢氧化物。化学蓄热材料2优选还含有粘土矿物。粘土矿物优选为海泡石和/或坡缕石。版权所有（C）2010，JPO＆INPIT

9. 发明专利

JP2009203444A Chemical heat accumulation material composite body 有权
标题翻译：化学热收集材料复合体
公开(公告)号：JP2009203444A
公开(公告)日：2009-09-10
申请号：JP2008050166
申请日：2008-02-29
申请人： Oumi Kogyo Kk , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , 近江鉱業株式会社
发明人： WAKAYAMA HIROAKI , SHIMAZU TAKASHI , FUKUSHIMA YOSHIAKI , SOFUGAWA HIDEO , MITSUI HIROYUKI , ITAHARA HIROYUKI , FUJIMURA TAKATSUNE
IPC分类号： C09K5/08 , C09K5/16 , F28D20/00
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical heat accumulation material composite body being excellent in durability and capable of sufficiently exhibiting ability as a chemical heat accumulation system. SOLUTION: The chemical heat accumulation material composite body is obtained by mixing a powdery chemical heat accumulation material 1 with a laminar composite hydroxide 2. A clay mineral 3 other than the laminar composite hydroxide 2 is further preferably mixed with it. The laminar composite hydroxide 2 is preferably hydrotalcite or hydrocalumite. The chemical heat accumulation material 1 is a hydration reaction system chemical heat accumulation material for performing endothermic action accompanying a dehydration reaction and performing heat releasing action accompanying a hydration reaction. The chemical heat accumulation material 1 is preferably the hydration reaction system chemical heat accumulation material becoming an oxide accompanying a dehydration reaction and becoming a hydroxide accompanying a hydration reaction. The chemical heat accumulation material 1 preferably comprises a hydroxide. The hydroxide is preferably an inorganic compound. COPYRIGHT: (C)2009,JPO&INPIT
摘要翻译：要解决的问题：提供一种化学蓄热材料复合体，其耐久性优异，能够充分发挥作为化学蓄热系统的能力。解决方案：通过将粉状化学蓄热材料1与层状复合氢氧化物2混合而获得化学蓄热材料复合体。进一步优选与片状复合氢氧化物2以外的粘土矿物3混合。层状复合氢氧化物2优选为水滑石或水钙钙石。化学蓄热材料1是用于进行伴随脱水反应的吸热作用并进行伴随水合反应的放热作用的水合反应系统化学蓄热材料。化学蓄热材料1优选是水合反应体系化学热积累材料成为伴随脱水反应的氧化物，并且随着水合反应变成氢氧化物。化学蓄热材料1优选包含氢氧化物。氢氧化物优选为无机化合物。版权所有（C）2009，JPO＆INPIT

10. 发明专利

JP2009227773A Chemical heat storage material composite and its manufacturing method 有权
标题翻译：化学热储存材料复合材料及其制造方法
公开(公告)号：JP2009227773A
公开(公告)日：2009-10-08
申请号：JP2008073489
申请日：2008-03-21
申请人： Oumi Kogyo Kk , Toyota Central R&D Labs Inc , 株式会社豊田中央研究所 , 近江鉱業株式会社
发明人： SOFUGAWA HIDEO , SHIMAZU TAKASHI , MITSUI HIROYUKI , FUKUSHIMA YOSHIAKI , WAKAYAMA HIROAKI , ITAHARA HIROYUKI , FUJIMURA TAKATSUNE
IPC分类号： C09K5/16
CPC分类号： Y02E60/142
摘要： PROBLEM TO BE SOLVED: To provide a chemical heat storage material composite suppressing generation of fine powder of a chemical heat storage material, securing heat conduction paths and enhancing structural strength and to provide its manufacturing method. SOLUTION: The chemical heat storage material composite 1 is formed by mixing a clay mineral 12 and a structural strength enhancing material 13 into a powdery chemical heat storage material 11 and firing the resultant mixture. The manufacturing method of the chemical heat storage material composite 1 has a mixing step for mixing the powdery chemical heat storage material 11, the clay mineral 12 and the structural strength enhancing material 13 to obtain a heat storage material mixture and a firing step for firing the heat storage material mixture to obtain the chemical heat storage material composite 1. COPYRIGHT: (C)2010,JPO&INPIT
摘要翻译：解决的问题：提供一种抑制化学蓄热材料细粉的产生的化学蓄热材料复合体，确保导热路径，提高结构强度，提供其制造方法。解决方案：化学储热材料复合材料1是通过将粘土矿物12和结构强度增强材料13混合到粉末化学储热材料11中并焙烧所得混合物而形成的。化学蓄热材料复合物1的制造方法具有混合粉末化学蓄热材料11，粘土矿物12和结构强度增强材料13以获得储热材料混合物和烧制步骤储热材料混合物获得化学储热材料复合材料1.版权所有（C）2010，JPO＆INPIT

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