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1. 发明专利

JPH0243736B2 失效
公开(公告)号：JPH0243736B2
公开(公告)日：1990-10-01
申请号：JP12882981
申请日：1981-08-19
申请人： MITSUI TOATSU CHEMICALS
发明人： HONDA TADATOSHI , YAMAUCHI ATSURO , TERADA KAZUHIRO
IPC分类号： C07D209/08 , B01J21/00 , B01J23/00 , B01J23/50 , B01J23/66 , B01J27/00 , B01J27/02 , B01J27/04 , C07B61/00

2. 发明专利

JPS63145274A PRODUCTION OF PIPERIDINE 失效
公开(公告)号：JPS63145274A
公开(公告)日：1988-06-17
申请号：JP29159986
申请日：1986-12-09
申请人： MITSUI TOATSU CHEMICALS
发明人： KITAGAWA MASANORI , INOMATA MASASANE , MIYAMA KANEMITSU , YAMAUCHI ATSURO
IPC分类号： C07D295/02 , B01J23/74 , B01J25/02 , C07B61/00
摘要： PURPOSE:To obtain the titled compound useful as a raw material for epoxy resin curing agents, rubber chemicals, etc., in high yield at a low cost in a short time, by using a nickel based catalyst as a catalyst and carrying out catalytic hydrogenation of glutaronitrile under specific condition. CONSTITUTION:Glutaronitrile is catalytically hydrogenated in the presence of a nickel based catalyst, e.g. nickel-diatomaceous earth, nickel-silica or nickel silica.alumina used with about 50% content of supported nickel, at 0-130 deg.C under 1-500kg/cm , preferably 1-200kg/cm hydrogen pressure, preferably in the presence of ammonia to afford the aimed compound. In the above- mentioned reaction, the ammonia is used as not only a solvent but also an additive useful as an inhibitor for formation of polyamines. The amount thereof used is preferably

3. 发明专利

JPS62185059A PRODUCTION OF ALKYLAMINOALKYL ESTER OF ACRYLIC ACID OR METHACRYLIC ACID 失效
公开(公告)号：JPS62185059A
公开(公告)日：1987-08-13
申请号：JP2602786
申请日：1986-02-10
申请人： MITSUI TOATSU CHEMICALS
发明人： ITOI AKIRA , YAMAUCHI ATSURO , MURANAKA HIDEKAZU , YARIMIZU YOSHIYUKI , AIKAWA TOSHIKAZU , SAGAWA EIICHI , NODATE YOSHIHIRO
IPC分类号： C07C213/06 , B01J27/232 , C07B61/00 , C07C67/00 , C07C213/00 , C07C219/08
摘要： PURPOSE:To obtain the titled compound useful as a textile finishing agent, paper treatment agent, paint, etc., in high yield and purity, by reacting methyl acrylate or methacrylate with an alkylamino alcohol while continuously adding a catalyst to the reaction system. CONSTITUTION:Methyl acrylate or methacrylate is made to react with an alkylamino alcohol of formula R1R2N(CH2)nOH (R1 is H or 1-6C alkyl; R2 is 1-6C alkyl; n is 2-6). In the above reaction, an alkali metal carbonate selected from potassium carbonate, rubidium carbonate and cesium carbonate is continuously added to the reaction system at an amount of 0.01-2wt% based on the whole starting raw materials. The reaction is carried out under reduced pressure at 50-120 deg.C for 3.5-7hr to obtain the objective compound.

4. 发明专利

JPS635055A PRODUCTION OF HIGHER ALKYL ESTER OF ACRYLIC ACID OR METHACRYLIC ACID 失效
公开(公告)号：JPS635055A
公开(公告)日：1988-01-11
申请号：JP14805486
申请日：1986-06-26
申请人： MITSUI TOATSU CHEMICALS
发明人： ITOI AKIRA , YAMAUCHI ATSURO , MURANAKA HIDEKAZU
IPC分类号： B01J27/232 , B01J27/00 , C07B61/00 , C07C67/03 , C07C69/54
摘要： PURPOSE:To obtain the titled compound useful in a wide application range such as adhesive, textile processing agent, paper processing agent, paint, plasticizer, etc., in high purity suppressing the formation of by-product, by reacting methyl acrylate or methacrylate with a higher alcohol in the presence of a catalyst. CONSTITUTION:The objective compound can be produced by the ester interchange reaction of methyl acrylate or methyl methacrylate with a higher alcohol of formula R-OH (R is 2-20C alkyl or cycloalkyl) in the presence of a catalyst (e.g. potassium bicarbonate) at 50-120 deg.C under 100-760mmHg pressure. The amount of the methyl acrylate or methacrylate is 1.2-10mol per 1mol of the higher alcohol and that of the catalyst is 0.01-2wt% based on the sum of the ester and alcohol. Rubidium bicarbonate and cesium bicarbonate may be used as the catalyst.

5. 发明专利

JPS62187437A PRODUCTION OF POLYETHYLENEPOLYAMINE 失效
公开(公告)号：JPS62187437A
公开(公告)日：1987-08-15
申请号：JP2799486
申请日：1986-02-13
申请人： MITSUI TOATSU CHEMICALS
发明人： INOMATA MASASANE , MIYAMA KANEMITSU , YAMAUCHI ATSURO , TANAKA YOSHINORI
IPC分类号： C07B61/00 , B01J25/00 , C07C67/00 , C07C209/00 , C07C209/22 , C07C209/48 , C07C209/52 , C07C211/14
摘要： PURPOSE:The catalytic hydrogenation of iminodiacetonitrile is carried out in the presence of a nickel or cobalt catalyst under specific conditions to produce the titled compound with is used as an epoxy resin curing agent, inexpensively and in high yield. CONSTITUTION:The catalytic hydrogenation of iminodiacetonitrile is effected in the presence of a nickel catalyst such as Raney nickel or a cobalt catalyst such as Raney cobalt at a hydrogen partial pressure of 10-200kg/cm at 125-250 deg.C to give an acyclic polyethylenepolyamine. The catalyst is very easily prepared by treating the Raney nickel or cobalt catalyst with an organic acid. further, the process according to the present invention inhibits the formation of cyclic amines such as piperidine to produce the objective acyclic polyethylenepolyamine in high yield, inexpensively.

6. 发明专利

JPS6215543B2 失效
公开(公告)号：JPS6215543B2
公开(公告)日：1987-04-08
申请号：JP16403279
申请日：1979-12-19
申请人： MITSUI TOATSU CHEMICALS
发明人： ITOI AKIRA , KAWAMATA MOTOO , OONO TATSUYA , YAMAUCHI ATSURO , KARASAWA MINAHITO , SHIMIZU SHIGEO , FUKUMURA KUNIMITSU , TAKASE KOZO
IPC分类号： C07C67/26 , B01J23/00 , B01J23/22 , B01J27/00 , B01J27/02 , B01J27/10 , B01J31/00 , B01J31/12 , C07B61/00 , C07C69/54

7. 发明专利

JPS61151171A PRODUCTION OF INDOLE 失效
公开(公告)号：JPS61151171A
公开(公告)日：1986-07-09
申请号：JP27274884
申请日：1984-12-26
申请人： MITSUI TOATSU CHEMICALS
发明人： YAMAUCHI ATSURO , IGUCHI SEIYA , ONO YUZO , KIMURA HIROSHI , MORITA SATOSHI
IPC分类号： C07D209/04 , C07D209/08
摘要： PURPOSE:To obtain high-purity indole by a simple process, by subjecting aniline and ethylene glycol to gaseous-phase contact reaction in the presence of a catalyst, separating and removing previously a high-boiling impurity, etc. from the prepared reaction product, and carrying out rectification. CONSTITUTION:Aniline which is previously vaporized by an evaporator is brought into contact with ethylene glycol in the presence of a solid acid catalyst or a metallic catalyst (supported on a carrier) at 0.01-10hr10 liquid space velocity (LHSV) at 200-600 deg.C at 1.1X10 -1.0X10 Pa pressure to give a reaction product, from which a high-boiling impurity and an nonvolatile substance are separated and removed, and rectification is carried out to give high-purity indole. EFFECT:In rectification of indole, a high-boiling impurity and a nonvolatile substance which remain in a rectification column after distillation of aniline and produce aniline gradually by thermal decomposition are previously removed, so occurrence of aniline is prevented, and purification is easily carried out. USE:An industrial raw material for perfume, dye, etc., a raw material for synthesizing amino acid, etc.

8. 发明专利

JPS5914013B2 JPS5914013B2 - 失效
公开(公告)号：JPS5914013B2
公开(公告)日：1984-04-02
申请号：JP12776976
申请日：1976-10-26
申请人： Mitsui Toatsu Chemicals
发明人： NOGUCHI YOSHIAKI , YAMAUCHI ATSURO , SEKIDO MASAJI , TANABE KAZUNORI
IPC分类号： C08K5/00 , C07C41/00 , C07C43/29 , C07C67/00 , C08K5/06 , C08L23/00 , C08L101/00 , C09K21/08

9. 发明专利

JPH0747568B2 失效
公开(公告)号：JPH0747568B2
公开(公告)日：1995-05-24
申请号：JP25839386
申请日：1986-10-31
申请人： MITSUI TOATSU CHEMICALS
发明人： MURANAKA HIDEKAZU , YAMAUCHI ATSURO , ITOI AKIRA
IPC分类号： C07B61/00 , B01J27/232 , C07C67/00 , C07C213/00 , C07C213/06 , C07C219/08

10. 发明专利

JPH0222255A PRODUCTION OF METHACRYLAMIDE 失效
公开(公告)号：JPH0222255A
公开(公告)日：1990-01-25
申请号：JP17101588
申请日：1988-07-11
申请人： MITSUI TOATSU CHEMICALS
发明人： INOMATA MASASANE , ITOI AKIRA , YAMAUCHI ATSURO
IPC分类号： B01J27/24 , C07B61/00 , C07C231/02 , C07C233/09
摘要： PURPOSE:To prevent methacrylamide, etc., from polymerizing and readily and industrially obtain the subject compound in high yield by amidating methyl methacrylate in the liquid phase with ammonia in the presence of a readily available and inexpensive specific ammonium salt. CONSTITUTION:Methyl methacrylate (hereinafter abbreviated to MMA) is reacted with ammonia, preferably aqueous ammonia in the liquid phase in the presence of one or more ammonium salts selected from ammonium salts of mineral acids, such as ammonium sulfate, NH4NO3 and NH4Cl, or ammonium halides, such as ammonium fluoride, preferably in the coexistence of a polymerization inhibitor, such as a quinone compound, e.g., preferably p-methoxyphenol, at 0-50 deg.C for 1.5-20hr to afford the objective compound useful as a paper processing agent, resin modifier for emulsion raw materials, etc. The above- mentioned ammonium salts are used in an amount of 0.1-5 molar ratio based on the MMA and the ammonia is used in an amount of 2-50 molar ratio based on the MMA.

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