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    • 9. 发明公开
    • Low-sulfur reforming prosesses
    • Reverierungsverfahren unter niedrigen Schwefelbedingungen
    • EP0845521A1
    • 1998-06-03
    • EP98100396.5
    • 1992-03-06
    • CHEVRON CHEMICAL COMPANY
    • Heyse, John V.Hise, Robert L.Mulaskey, Bernard F.Trumbull, Steven E.Innes, Robert A.Hagewiesche, Daniel P.Hubred, Gale L.Moore, Steven C.Bryan, Paul F.
    • C10G35/00C10G35/04C10G35/095
    • C10G35/00C10G35/04C10G35/095
    • There is disclosed a catalytic reforming method in which hydrocarbons are treated in a reactor system to produce an aromatics enriched product, said reactor system comprising:

      (a) a series of reactors (10,20,30), containing a catalyst bed comprising a sulfur sensitive zeolite reforming catalyst, and each being associated with
      (b) a respective furnace (11,21,31) each comprising a plurality of furnace tubes for heating hydrocarbons to an elevated temperature in the range of from 850 to 1025 F suitable for reforming,
      (c) a heat exchanger (12); and
      (d) a separator (13) for separating an aromatics enriched product from effluent gas;
         said method comprising passing hydrocarbons through said reactor system to contact the hydrocarbons with the reforming catalyst in said reactors and separating said aromatics enriched product from said effluent gas;
         wherein:

      (i) hydrocarbons are reformed in each of said reactors under low sulfur reforming conditions of less than 50ppb sulfur; and
      (ii) at least the furnace tubes of the reactor system are protected from carburization and metal dusting.


      Apparatus for carrying out the process is also described.
    • 公开了一种催化重整方法,其中在反应器系统中处理烃以产生富含芳烃的产物,所述反应器系统包括:(a)一系列反应器(10,20,30),其包含含有硫的催化剂床 敏感的沸石重整催化剂,并且各自与(b)相应的炉子(11,21,31)相关联,每个炉子包括多个用于将烃加热至适于重整的850至1025°F范围内的高温的多个炉管, (c)热交换器(12); 和(d)用于将富含芳烃的产物与流出气体分离的分离器(13); 所述方法包括使烃通过所述反应器系统以使烃与所述反应器中的重整催化剂接触,并将富含芳烃的产物与所述废气分离; 其中:(i)在低于50ppb硫的低硫重整条件下,在每个所述反应器中重整碳氢化合物; 和(ii)至少保护反应器系统的炉管免受渗碳和金属粉尘的侵害。 还描述了用于执行该过程的装置。