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1. 发明授权

EP2762503B1 OPTICAL ELEMENT MATERIAL AND METHOD FOR PRODUCING SAME 有权
标题翻译：光学元件材料及其制造方法
公开(公告)号：EP2762503B1
公开(公告)日：2017-11-08
申请号：EP12835136.8
申请日：2012-09-25
申请人： Maruzen Petrochemical Co., Ltd.
发明人： HAYASHIDA, Yoshihisa , SATSUKA, Takuro , IKEDA, Teruyo
IPC分类号： C08F226/12 , C08F2/50 , C08F16/32 , C08F220/10 , G02B1/04 , G02B5/30
CPC分类号： C09D139/04 , C08F2/50 , C08F222/1006 , C08F226/12 , G02B1/04 , G02B1/10 , G02B1/12 , C08L39/00 , C08L45/00 , C08F2220/1883 , C08F2222/1026 , C08F226/08 , C08F2220/301

2. 发明公开

EP3045482A4 STAR-SHAPED VINYL ETHER POLYMER 有权
标题翻译： STERNFÖRMIGESVINYLETHERPOLYMER
公开(公告)号：EP3045482A4
公开(公告)日：2017-07-12
申请号：EP14842207
申请日：2014-09-02
申请人： MARUZEN PETROCHEM CO LTD
发明人： YOSHIDA NORIHIRO
IPC分类号： C08F16/32 , C08F2/42 , C08F8/30 , C08F216/14 , D06M15/347
CPC分类号： C08F261/06 , C08F2/42 , C08F8/30 , C08F116/14 , C08F216/125 , C08F216/1416 , C08F2800/10 , C08F2800/20 , C08F2810/50 , D06M15/347 , D06M2101/32 , D06M2200/11 , D06M2200/12 , C08F216/1458
摘要： Provided are a vinyl ether polymer which can exert temperature responsiveness even in the case of being supported on a highly hydrophobic fibrous substrate, an agent for controlling hydrophilicity and hydrophobicity containing the polymer, a method for controlling hydrophilicity and the hydrophobicity using the polymer, and a polymer-substrate composite having the polymer supported on a substrate. A star-shaped vinyl ether polymer which includes a central core and an arm portion bonded to the central core and in which the arm portion includes a repeating unit derived from a vinyl ether monomer and a structure represented by the following Formula (1) is included in the molecule: €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ-Y-Ar 1 -N=N-Ar 2 €ƒ€ƒ€ƒ€ƒ€ƒ(1) i in which Y represents an ether bond, a thioether bond, a group -NH-, or a group -OR 1 -* (R 1 represents an alkylene group, * represents a position bonded to Ar 1 in Formula (1)), Ar 1 represents a substituted or unsubstituted divalent aromatic hydrocarbon group, and Ar 2 represents a substituted or unsubstituted monovalent aromatic hydrocarbon group].
摘要翻译：本发明提供即使在高疏水性纤维基材上担载时也能够发挥温度响应性的乙烯基醚类聚合物，含有聚合物的亲水性和疏水性控制剂，使用该聚合物的亲水性和疏水性的控制方法，聚合物 - 基材复合物，其具有负载在基材上的聚合物。一种星形乙烯基醚聚合物，其包括中心核心和与中心核心键合的臂部分，其中臂部分包含衍生自乙烯基醚单体的重复单元和由下式（1）表示的结构在分子中：Y-Ar 1 -N = N-Ar 2（1）其中Y代表醚键，硫醚键，基团-NH-或基团-OR 1 - *（R 1表示亚烷基，*表示与式（1）中的Ar 1键合的位置），Ar 1表示取代基或未取代的二价芳族烃基，并且Ar 2表示取代或未取代的一价芳族烃基]。

3. 发明公开

EP2980059A1 VINYL-GROUP-CONTAINING FLUORENE COMPOUND 有权
标题翻译：含乙烯基的芴化合物
公开(公告)号：EP2980059A1
公开(公告)日：2016-02-03
申请号：EP14775291.9
申请日：2014-03-28
申请人： Tokyo Ohka Kogyo Co., Ltd. , Daicel Corporation
发明人： SHIOTA, Dai , NODA, Kunihiro , CHISAKA, Hiroki , AKAI, Yasuyuki , TAKASE, Ichiro , NARASAKI, Yoshiya , TANIDA, Daisuke , KITAO, Kyuhei
IPC分类号： C07C43/215 , C07C43/23 , C07C69/54 , C07C309/66 , C08F16/12 , C08F16/32 , G03F7/027
CPC分类号： C07C43/215 , C07C41/22 , C07C41/24 , C07C43/225 , C07C43/23 , C07C57/50 , C07C67/14 , C07C69/54 , C07C303/30 , C07C309/66 , C07C2603/18 , G03F7/027
摘要： Provided is a novel vinyl-group-containing fluorene compound and a method for producing the same, a polymerizable monomer and cross-linking agent comprising this compound, a leaving-group-containing fluorene compound, a monovinyl-group-containing fluorene compound, and methods for producing the same. This vinyl-group-containing fluorene compound is represented by formula (1) (In the formula, W 1 and W 2 represent a group represented by formula (2), a group represented by formula (4), a hydroxyl group, or a (meth)acryloyloxy group, R 3a and R 3b represent a cyano group, a halogen atom, or a monovalent hydrocarbon, and n1 and n2 are integers of 0-4. In formulas (2) and (4), a ring (Z) is an aromatic hydrocarbon ring, X is a single bond or a group represented by -S-, R 1 is a single bond or a C1-4 alkylene group, R 2 is a specific substituent group such as a monovalent hydrocarbon, and m is an integer of 0 or greater.).
摘要翻译：本发明提供一种含有乙烯基的新型芴化合物及其制造方法，含有该化合物的聚合性单体及交联剂，含有离去基团的芴化合物，含有单乙烯基的芴化合物及生产方法。该含乙烯基的芴化合物由式（1）表示（式中，W 1和W 2表示由式（2）表示的基团，由式（4）表示的基团，羟基或）丙烯酰氧基，R 3a和R 3b表示氰基，卤素原子或一价烃基，n 1和n 2为0-4的整数。式（2）和（4）中，环（Z）为芳香族烃环，X为单键或-S-所示的基团，R 1为单键或碳原子数1〜4的亚烷基，R 2为1价烃等特定的取代基，m为0或1的整数更大）。

4. 发明公开

EP1970407A4 FLUORINE-CONTAINING POLYMER AND FLUORINE-CONTAINING POLYMER COMPOSITION CONTAINING SAME 有权
标题翻译： FLUOR含氟聚合物和聚合物组合含氟含SO
公开(公告)号：EP1970407A4
公开(公告)日：2010-08-04
申请号：EP06834840
申请日：2006-12-15
申请人： ASAHI GLASS CO LTD
发明人： OTOZAWA NOBUYUKI , SHIMADA TOYOMICHI
IPC分类号： C08L27/12 , C08F16/32 , C08J3/09
CPC分类号： C08F214/18 , C08F14/18 , C08J3/093 , C08J2329/10 , C08K5/02 , C08K5/06 , C08F2/18 , C08L27/12
摘要： To provide an amorphous fluorinated polymer which is soluble in a fluorinated solvent having a boiling point of at most 70°C, and a fluorinated polymer composition containing it. An amorphous fluorinated polymer characterized by having a fluorine content of at least 50 mass% and an intrinsic viscosity of at least 0.03 g/dL and less than 0.05 g/dL as measured in perfluoro(2-butyltetrahydrofuran) at 30°C.

5. 发明授权

EP1285905B1 NOVEL FLUORINE COMPOUND, PROCESS FOR PRODUCING THE SAME, AND POLYMER THEREOF 有权
标题翻译：新FLUOR化合物，制备方法及其聚合物
公开(公告)号：EP1285905B1
公开(公告)日：2006-10-18
申请号：EP01934402.7
申请日：2001-05-30
申请人： ASAHI GLASS COMPANY LTD.
发明人： KASHIWAGI, Kimiaki c/o Asahi Glass Company, Ltd. , OGAWA, Gen c/o Asahi Glass Company, Ltd. , SATO, Masakuni c/o Asahi Glass Company, Ltd. , OHARU, Kazuya c/o Asahi Glass Company, Ltd. , KANEKO, Isamu c/o Asahi Glass Company, Ltd. , SUGIYAMA, Norihide c/o Asahi Glass Company, Ltd. , TATEMATSU, Shin c/o Asahi Glass Company, Ltd.
IPC分类号： C07C43/17 , C07C41/24 , C08F16/12 , G02B6/00 , C08F16/32 , C08G77/00 , G02B6/02
CPC分类号： C07C43/17 , C08F16/32 , C08G77/00 , G02B6/02033
摘要： A novel polymer useful as an optical resin material having excellent heat resistance; and a novel monomer for obtaining the polymer. The monomer is a fluorinated diene represented by CF2=CF(CF2)nC(CF3)ROCF=CF2 (wherein R represents fluorine or trifluoromethyl and n is an integer of 1 to 3).

6. 发明公开

EP1440961A4 FLUORINE-CONTAINING DIENE COMPOUNDS, FLUOROPOLYMERS AND PROCESSES FOR PRODUCTION OF BOTH 有权
标题翻译： FLUOR含DIEN含氟化合物及其制备方法的化合物和聚合物
公开(公告)号：EP1440961A4
公开(公告)日：2006-03-08
申请号：EP02778017
申请日：2002-10-30
申请人： ASAHI GLASS CO LTD
发明人： KASHIWAGI KIMIAKI , OGAWA GEN , OKAZOE TAKASHI , WATANABE KUNIO , MUROTANI EISUKE , OHARU KAZUYA
IPC分类号： C07C43/17 , C08F16/32 , C08F214/18 , G02B1/04 , C07C41/24 , C08F216/12 , C08L29/10 , G02B6/00
CPC分类号： G02B6/02038 , C07C43/17 , C08F16/32 , C08F214/18 , G02B1/046 , G02B6/02033 , C08L29/10
摘要： The invention provides novel fluoropolymers capable of forming optical elements having low refractive indexes and excellent heat resistance; novel fluorine-containing diene compounds having two unsaturated bonds capable of giving the above fluoropolymers; and light transmitters and plastic optical fibers made by using the fluoropolymers, which exhibit high performance by virtue of the low refractive indexes and excellent heat resistance, specifically, fluorine-containing diene compounds represented by the general formula: CF2=CFCF(ORf)CF2OCF=CF2 [wherein Rf is perfluoroalkyl such as trifluoromethyl]; fluoropolymers of the diene compounds; light transmitters made by using the fluoropolymers; and plastic optical fibers wherein the core is made of a composition comprising a fluoropolymer described above and a low-molecular fluorine compound serving to enhance the refractive index.

7. 发明公开

EP1462435A1 PROCESS FOR PRODUCING DIENE COMPOUND 有权
标题翻译：生产二烯化合物的方法
公开(公告)号：EP1462435A1
公开(公告)日：2004-09-29
申请号：EP02790732.8
申请日：2002-12-12
申请人： ASAHI GLASS COMPANY LTD.
发明人： IWAYA, Masao,c/o Asahi Glass Company, Limited , OKAMOTO, Hidekazu,c/o Asahi Glass Company, Limited , OHARU, Kazuya,c/o Asahi Glass Company, Limited
IPC分类号： C07C41/44 , C07C43/17 , C07C45/51 , C07C49/227 , C07C17/361 , C07C21/19 , C08F16/32
CPC分类号： C08F36/20 , C07C17/361 , C07C41/44 , C07C51/58 , C08F16/32 , C07C21/18 , C07C57/76 , C07C57/66 , C07C43/17
摘要： It is an object to obtain from a mixture of a specific diene compound (1) and a compound (2) with the same molecular weight and molecular formula hard to separate by distillation, the diene compound (1) in high purity without using any special reagent or complicated technique.
Namely, the present invention provides a method of inducing the Claisen rearrangement reaction of the compound (2) in a mixture containing

CR 1 R 2 =CR 3 CFR 4 CR 5 R 6 OCR 7 =CR 8 R 9 (1)

and

CFR 1 R 2 CR 3 =CR 4 CR 5 R 6 OCR 7 =CR 8 R 9 (2),

and separating the diene compound (1) from a Claisen rearrangement reaction product; or converting the Claisen rearrangement reaction product into a derivative and then separating the diene compound (1) from the derivative of the Claisen rearrangement reaction product. Wherein, R 1 to R 9 each represent a fluorine atom or the like.
摘要翻译：其目的是从具有相同分子量和分子式的特定二烯化合物（1）和化合物（2）的混合物中通过蒸馏分离出高纯度的二烯化合物（1）而不使用任何特殊试剂或复杂的技术。即，本发明提供了在含有CR1R2 = CR3CFR4CR5R6OCR7 = CR8R9（1）和CFR1R2CR3 = CR4CR5R6OCR7 = CR8R9（2）的混合物中诱导化合物（2）的克莱森重排反应并分离二烯化合物（1）来自克莱森重排反应产物; 或将克莱森重排反应产物转化成衍生物，然后将二烯化合物（1）与克莱森重排反应产物的衍生物分离。其中，R1至R9各自表示氟原子等。

8. 发明授权

EP1341827B1 HIGH MOLECULAR WEIGHT PERFLUOROCYCLOBUTANE POLYMERS AND METHOD OF MAKING 有权
标题翻译：随着高分子量和方法的全氟聚合物方面的
公开(公告)号：EP1341827B1
公开(公告)日：2004-08-25
申请号：EP01946511.1
申请日：2001-06-19
申请人： 3M Innovative Properties Company
发明人： MAO, Shane, S. , SIEDLE, Allen, R.
IPC分类号： C08F16/32
CPC分类号： C08F16/32 , C08F114/185
摘要： This invention relates to high molecular weight perfluorocyclobutane polymers and methods of polymerizing trifluorovinyl monomers to form high molecular weight perfluorocyclobutane polymers in the presence of a catalyst or initiator.

9. 发明公开

EP1341827A1 HIGH MOLECULAR WEIGHT PERFLUOROCYCLOBUTANE POLYMERS AND METHOD OF MAKING 有权
标题翻译：随着高分子量和方法的全氟聚合物方面的
公开(公告)号：EP1341827A1
公开(公告)日：2003-09-10
申请号：EP01946511.1
申请日：2001-06-19
申请人： 3M Innovative Properties Company
发明人： MAO, Shane, S. , SIEDLE, Allen, R.
IPC分类号： C08F16/32
CPC分类号： C08F16/32 , C08F114/185
摘要： This invention relates to high molecular weight perfluorocyclobutane polymers and methods of polymerizing trifluorovinyl monomers to form high molecular weight perfluorocyclobutane polymers in the presence of a catalyst or initiator.

10. 发明授权

EP0463862B1 Aromatic vinyl ether compounds and compositions, and method of making the same 失效
标题翻译：芳族乙烯基醚化合物和组合物以及它们的制备方法。
公开(公告)号：EP0463862B1
公开(公告)日：1995-08-09
申请号：EP91305747.7
申请日：1991-06-25
申请人： LOCTITE CORPORATION
发明人： Klemarczyk, Philip T. , Okamoto, Yoshihisa
IPC分类号： C07C43/215 , C07C43/315 , C07C41/16 , C08F16/12 , C08F16/32
CPC分类号： C07C43/00 , C07C43/215 , C07C43/315 , C07C69/92 , C08F16/32

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