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    • 3. 发明公开
    • Process for producing a heat shrinkable tube
    • Verfahren zur Herstellung von einem hitzschrumpfbarenRöhrenmaterial
    • EP2327751A1
    • 2011-06-01
    • EP10194235.7
    • 2004-07-14
    • Sumitomo Electric Fine Polymer, Inc.
    • Moriuchi, KiyoakiHayami, HiroshiNishikawa, Shinya
    • C09J151/00C09J11/06C08F259/08B32B1/08B32B27/30F16L58/10C09J151/06C08L51/00B32B27/16B29C61/06B29C61/08
    • C08L51/003B65D41/24C08F259/08C08L2666/02C08L2666/24C09J151/003C09J151/06Y10T428/1328
    • A process for producing a multi-layer heat shrinkable tube having an adhesive layer on an internal surface thereof, which comprises the following steps 1 to 4:
      (1) Step 1 of co-extruding a radiation-crosslinking composition comprising a fluorine-containing polymer and a polyfunctional monomer and a fluorine-containing polymer composition comprising 100 parts by weight of a fluorine-containing polymer and 2 to 30 parts by weight of an unsaturated compound containing at least one polar group selected from the group consisting of an epoxy group and a carboxyl group to form a tube-like formed product of a 2-layer structure having an outer layer composed of the radiation-crosslinking composition and an inner layer composed of the fluorine-containing polymer composition;
      (2) Step 2 of irradiating the tube-like formed product with ionizing radiation to crosslink the radiation-crosslinking composition of the outer layer and graft-modify the fluorine-containing polymer composition of the inner layer;
      (3) Step 3 of expanding the tube-like formed product in a radial direction thereof under heating; and
      (4) Step 4 of cooling the tube-like formed product to fix the form expanded in the radial direction.
    • 一种在其内表面上具有粘合剂层的多层热收缩管的制造方法,其包括以下步骤1至4:(1)将包含含氟聚合物的辐射交联组合物共挤出的步骤1 以及含有100重量份含氟聚合物和2〜30重量份含有至少一个极性基团的不饱和化合物的多官能单体和含氟聚合物组合物,所述极性基团选自环氧基和 羧基以形成具有由辐射交联组合物构成的外层和由含氟聚合物组合物构成的内层的2层结构的管状形成体; (2)使用电离辐射照射管状成形体的工序2,使外层的辐射交联组合物交联,并对内层的含氟聚合物组合物进行接枝改性; (3)使加热时的筒状成形体的径向膨胀的工序3; 和(4)冷却管状成形品的步骤4,以固定沿径向膨胀的形状。