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    • 10. 发明授权
    • ADDITIVE FOR SILICA REINFORCED RUBBER FORMULATIONS
    • 硅橡胶增强橡胶配方添加剂
    • EP3045493B1
    • 2017-09-13
    • EP16151572.1
    • 2016-01-15
    • Flow Polymers LLC
    • PUHALA, Aaron S.ADEPETUN, Adeyemi A.
    • C08K3/36C08K5/00B60C1/00C08K5/057
    • C08K5/057B60C1/0016B60C9/02B60C11/0008B60C15/00C08K3/36C08K5/0025C08L21/00
    • This invention is based upon the discovery that the silica compounding additives of this invention can be included in silica reinforced rubber formulations to increase the low strain dynamic stiffness exhibited by the rubber composition without a substantial increase in the cured compound hysteresis. This increase in stiffness allows for use of process aids that would otherwise result in an unacceptable further reduction in low strain dynamic stiffness. The present invention specifically discloses a rubber formulation which is comprised of (1) a rubbery polymer, (2) a reinforcing silica, and (3) a silica compounding additive of the structural formula: wherein M represents a divalent metal, and wherein R 1 and R 2 can be the same or different and are selected from the group consisting of hydrogen atoms, alkyl groups, alkylene groups, hydroxyl substituted alkyl or alkylene groups, amine substituted alkyl or alkylene groups and thiol substituted alkyl or alkylene groups.
    • 本发明基于这样的发现:本发明的二氧化硅配混添加剂可以包含在二氧化硅增强的橡胶配方中以增加橡胶组合物表现出的低应变动态硬挺度,而固化的化合物滞后却基本上没有增加。 硬度的这种增加允许使用加工助剂,否则会导致低应变动态硬度的不可接受的进一步降低。 本发明具体公开了一种由(1)橡胶状聚合物,(2)增强二氧化硅和(3)下式结构式的二氧化硅配合添加剂组成的橡胶配方:其中M代表二价金属,并且其中R 1 R 2可以相同或不同,选自氢原子,烷基,亚烷基,羟基取代的烷基或亚烷基,胺取代的烷基或亚烷基和硫醇取代的烷基或亚烷基。