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    • 1. 发明公开
    • Ethylene polymerization process
    • Verfahren zur乙烯聚合。
    • EP0589472A2
    • 1994-03-30
    • EP93115438.9
    • 1993-09-24
    • PHILLIPS PETROLEUM COMPANY
    • Benham, Elizabeth AnnMcDaniel, Max Paul
    • C08F10/00C08F4/628
    • C08F10/02C08F4/69C08F4/025C08F210/16C08F210/14C08F2500/18
    • A process to produce a polyethylene composition that has less than 2 weight percent fines, based on the weight of said polyethylene composition, and a fluff bulk density greater than 25 pounds per cubic foot, said process comprising polymerizing ethylene in the presence of a trialkylaluminum compound, and a diluent that is essentially saturated with ethylene under slurry polymerization conditions that comprise a polymerization temperature from 104°C to 116°C, with an activated catalyst system comprising (a) a catalyst support that comprises a silica compound, wherein said catalyst support has a pore volume less than 2 cubic centimeters per gram, (b) a catalyst that comprises a chromium compound, wherein the amount of chromium in said catalyst system is from about 0.1 to about 20 weight percent, wherein said weight percent is based on the total weight of said catalyst and catalyst support, and (c) a fluorine compound, wherein the amount of fluorine used is from about 0.1 to about 20 weight percent, wherein said weight percent is based on the total weight of said catalyst support.
    • 一种制备基于所述聚乙烯组合物的重量小于2重量%的细粉和大于25磅/立方英尺的绒毛体积密度的聚乙烯组合物的方法,所述方法包括在三烷基铝化合物存在下聚合乙烯 和在包含聚合温度为104℃至116℃的淤浆聚合条件下基本上用乙烯饱和的稀释剂,其中活化的催化剂体系包含(a)包含二氧化硅化合物的催化剂载体,其中所述催化剂载体 具有小于2立方厘米/克的孔体积,(b)包含铬化合物的催化剂,其中所述催化剂体系中的铬的量为约0.1至约20重量%,其中所述重量百分比基于 所述催化剂和催化剂载体的总重量,和(c)氟化合物,其中使用的氟量为约0.1至约 t 20重量%,其中所述重量百分数是基于所述催化剂载体的总重量。