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    • 4. 发明公开
    • SECONDARY BATTERY SYSTEM
    • 二次电池系统
    • EP3252860A1
    • 2017-12-06
    • EP17174352.9
    • 2017-06-02
    • Toyota Jidosha Kabushiki KaishaKyoto University
    • MIKI, HidenoriOGUMI, ZempachiUCHIMOTO, Yoshiharu
    • H01M10/054
    • H01M4/1315H01M4/136H01M4/483H01M4/485H01M4/505H01M4/525H01M4/582H01M4/62H01M4/625H01M6/183H01M10/05H01M10/054H01M10/0562H01M10/44H01M2300/008
    • An object of the present disclosure is to provide a secondary battery system that functions at high voltage. The present disclosure attains the object by providing a secondary battery system comprising: a fluoride ion battery including a cathode active material layer, an anode active material layer, and an electrolyte layer formed between the cathode active material layer and the anode active material layer; and a controlling portion that controls charging and discharging of the fluoride ion battery; characterized in that the cathode active material layer contains a cathode active material with a crystal phase that has a Perovskite layered structnre and is represented by A n+1 B n O δn+1-α F x (A comprises at least one of an alkali earth metal element and a rare earth element; B comprises at least one of Mn, Co, Ti, Cr, Fe, Cu, Zn, V, Ni, Zr, Nb, Mo, Ru, Pd, W, Re, Bi, and Sb; "n" is 1 or 2; "α" satisfies 0 ≤ α ≤ 3.5; and "x" satisfies 0 ≤ x ≤ 5.5) ; and the controlling portion controls charging so that a value of F/B in the cathode active material becomes more than 2/n that is in an over-charged state,
    • 本公开的目的是提供一种在高电压下起作用的二次电池系统。 本发明的目的在于提供一种二次电池系统,其包括:氟离子电池,其包括阴极活性材料层,阳极活性材料层以及形成在阴极活性材料层和阳极活性材料层之间的电解质层; 以及控制所述氟离子电池的充电和放电的控制部分; 其特征在于,所述正极活性材料层含有具有钙钛矿分层结构的结晶相的正极活性材料,并且由An +1BnOδn+ 1-αFx表示(A包含碱土金属元素和稀土元素中的至少一种 元素; B包含Mn,Co,Ti,Cr,Fe,Cu,Zn,V,Ni,Zr,Nb,Mo,Ru,Pd,W,Re,Bi和Sb中的至少一种;“n”为1 或2;“α”满足0≤α≤3.5;“x”满足0≤x≤5.5); 并且控制部分控制充电,使得正极活性材料中的F / B的值变得大于处于过充电状态的2 / n,