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1. 发明授权

EP2764532B1 ANNULAR ION GUIDE 有权
标题翻译：环形离子导体
公开(公告)号：EP2764532B1
公开(公告)日：2017-04-19
申请号：EP12775836.5
申请日：2012-10-01
申请人： Micromass UK Limited
发明人： GREEN, Martin Raymond , LANGRIDGE, David J.
IPC分类号： H01J49/06
CPC分类号： H01J49/424 , H01J49/065 , H01J49/066 , H01J49/36

2. 发明公开

EP2951851A2 METHOD FOR MASS SPECTROMETRIC EXAMINATION OF GAS MIXTURES AND MASS SPECTROMETER THEREFOR 有权转让
标题翻译：气体混合和质谱仪方法质谱测试THEREOF
公开(公告)号：EP2951851A2
公开(公告)日：2015-12-09
申请号：EP14701405.4
申请日：2014-01-27
申请人： Carl Zeiss SMT GmbH , Carl Zeiss Microscopy GmbH
发明人： CHUNG, Hin Yiu Anthony , ALIMAN, Michel , FEDOSENKO, Gennady , RANCK, Albrecht
IPC分类号： H01J49/00 , H01J49/10 , H01J49/14 , C23C16/44 , C23C16/52
CPC分类号： H01J49/0031 , C23C16/4405 , C23C16/52 , H01J37/32862 , H01J49/009 , H01J49/105 , H01J49/107 , H01J49/145 , H01J49/424 , H01J2237/335
摘要： The invention relates to a method for mass spectrometric examination of a gas mixture (2), comprising the following method steps: parallel or serial ionization of the gas mixture (2) to be examined by activating of at least two ionization devices (9a, 9b, 9c) operating using different ionization procedures, and/or ionizing of the gas mixture (2) in a detector (10), to which the gas mixture (2) and ions and/or metastable particles (29) of an ionization gas (30), which are produced by an ionization device (9), are fed, and detecting of the ionized gas mixture (2) in the detector (10) for the mass spectrometric examination thereof. The invention also relates to a mass spectrometer (21 ) for mass spectrometric examination of gas mixtures (2), comprising: an ionization unit (22) for ionizing the gas mixture (2), and a detector (10) for detecting the ionized gas mixture (2). The ionization unit (22) comprises at least two ionization devices (9a, 9b, 9c), arranged in parallel or in series, for ionizing the gas mixture (2) by means of different ionization procedures, wherein the ionization devices (9a, 9b, 9c) alternatively can be activated individually or together, and/or the ionization unit (22) has an ionization device (9) configured to feed ions and/or metastable particles (29) of an ionization gas (30) to the detector (10) in order to ionize the gas mixture (2) in the detector (10).
摘要翻译：一种方法，包括气体混合物的并行或串行电离通过激活使用不同的离子化过程操作至少两个电离装置，和/或通过在一个检测器，气体混合物和离子和/或亚稳的电离的粒子电离气体混合物气体被供给。因此，该方法包括在检测器用于其质谱检查检测电离气体混合物。对于气体混合物的质谱检查一种质谱仪包括离子化单元，用于电离的气体混合物，和用于检测电离气体混合物的检测器。

3. 发明公开

EP2517223A4 APPARATUSES AND METHODS FOR PORTABLE MASS SPECTROMETRY 审中-公开
标题翻译： DEVICES AND METHOD FOR便携式大容量
公开(公告)号：EP2517223A4
公开(公告)日：2015-11-18
申请号：EP10840123
申请日：2010-12-22
申请人： ACADEMIA SINICA
发明人： CHEN CHUNG-HSUAN , LIN JUNG-LEE , CHU MING-LEE
IPC分类号： H01J49/42 , H01J49/00
CPC分类号： H01J49/0022 , H01J49/424 , H01J49/429

4. 发明授权

EP2113129B1 MASS SPECTROMETER 失效转让
公开(公告)号：EP2113129B1
公开(公告)日：2015-04-29
申请号：EP08709499.1
申请日：2008-02-21
申请人： Micromass UK Limited
发明人： BATEMAN, Robert, Harold , GREEN, Martin , WILDGOOSE, Jason, Lee
IPC分类号： H01J49/42
CPC分类号： H01J49/0095 , H01J49/423 , H01J49/424

5. 发明公开

EP2309531A4 MASS ANALYZER 失效转让
标题翻译： MASSENANALYSATOR
公开(公告)号：EP2309531A4
公开(公告)日：2013-11-20
申请号：EP08764185
申请日：2008-06-20
申请人： SHIMADZU CORP
发明人： TANIGUCHI JUNICHI
IPC分类号： H01J49/42 , H01J49/04 , H01J49/40
CPC分类号： H01J49/36 , H01J49/004 , H01J49/0481 , H01J49/40 , H01J49/424 , H01J49/426 , H01J49/427
摘要： In performing an isolation of specific ions or performing a dissociation operation by CID, ions are captured by applying a radio-frequency high voltage to a ring electrode 31 as before. In a cooling operation which is performed immediately before target ions are ejected toward a TOFMS unit 4 with the ions stored in an ion trap 3, a radio-frequency high voltage is not applied to the ring electrode 31 but to end cap electrodes 32 and 34 to capture the ions. In this operation, the frequency thereof is set to be higher than that of the voltage applied to the ring electrode 31 and the amplitude is also increased in order to assure a large pseudopotential and keep the low mass cutoff (LMC), This narrows the spatial distribution of the cooled ions, reducing the variation of the initial positions of the ions at the point in time when they are ejected, which increases the mass resolution. In addition, since an isolation of ions having a large m/z can be performed with a great q z value as is conventionally done, a high mass selectivity can be assured.
摘要翻译：在执行特定离子的分离或通过CID进行解离操作时，如前所述通过向环形电极31施加射频高电压来捕获离子。在将离子存储在离子阱3内的目标离子朝向TOFMS单元4喷射之前进行的冷却运转中，射频高压不施加到环形电极31而是端盖电极32和34 捕获离子。在该操作中，其频率被设定为高于施加到环形电极31的电压的频率，并且为了确保大的伪电位并保持低质量截止（LMC），振幅也增加。这缩小了空间冷却的离子的分布，减少离子在它们被喷射的时间点的初始位置的变化，这增加了质量分辨率。此外，由于如以往那样以大的q z值进行具有大m / z的离子的分离，因此可以确保高的质量选择性。

6. 发明授权

EP1302973B1 Mass spectrometer and measurement system and method for time-of-flight mass spectrometry 有权
标题翻译：质谱仪和测量系统和飞行质谱方法
公开(公告)号：EP1302973B1
公开(公告)日：2012-09-12
申请号：EP02011538.2
申请日：2002-05-23
申请人： Hitachi High-Technologies Corporation
发明人： Okumura, Akihiko , Hirabayashi, Atsumu , Waki, Izumi
IPC分类号： H01J49/40 , H01J49/42
CPC分类号： H01J49/401 , H01J49/424

7. 发明授权

EP1369901B1 Ion trap mass spectrometer 有权
标题翻译： Ionenfallemassenspektrometer
公开(公告)号：EP1369901B1
公开(公告)日：2011-12-07
申请号：EP03011348.4
申请日：2003-05-19
申请人： Shimadzu Corporation
发明人： Umemura, Yoshikatsu
IPC分类号： H01J49/42
CPC分类号： H01J49/424 , H01J49/428

8. 发明公开

EP2309531A1 MASS ANALYZER 失效转让
标题翻译：质量分析仪
公开(公告)号：EP2309531A1
公开(公告)日：2011-04-13
申请号：EP08764185.8
申请日：2008-06-20
申请人： Shimadzu Corporation
发明人： TANIGUCHI, Junichi
IPC分类号： H01J49/42 , G01N27/62
CPC分类号： H01J49/36 , H01J49/004 , H01J49/0481 , H01J49/40 , H01J49/424 , H01J49/426 , H01J49/427
摘要： In performing an isolation of specific ions or performing a dissociation operation by CID, ions are captured by applying a radio-frequency high voltage to a ring electrode 31 as before. In a cooling operation which is performed immediately before target ions are ejected toward a TOFMS unit 4 with the ions stored in an ion trap 3, a radio-frequency high voltage is not applied to the ring electrode 31 but to end cap electrodes 32 and 34 to capture the ions. In this operation, the frequency thereof is set to be higher than that of the voltage applied to the ring electrode 31 and the amplitude is also increased in order to assure a large pseudopotential and keep the low mass cutoff (LMC), This narrows the spatial distribution of the cooled ions, reducing the variation of the initial positions of the ions at the point in time when they are ejected, which increases the mass resolution. In addition, since an isolation of ions having a large m/z can be performed with a great q z value as is conventionally done, a high mass selectivity can be assured.
摘要翻译：在执行特定离子的隔离或通过CID执行解离操作时，通过如前所述向环形电极31施加射频高电压来捕获离子。在离子存储在离子阱3中的离子朝向TOFMS单元4喷射之前立即进行的冷却操作中，射频高电压不施加到环形电极31，而是施加到端部电极32和34 捕捉离子。在该操作中，其频率被设置为高于施加到环形电极31的电压的频率，并且振幅也被增大以确保较大的赝势并保持低质量截止（LMC）。这使得空间冷却离子的分布，减少离子在它们被喷射时的初始位置的变化，这增加了质量分辨率。另外，由于可以按照常规方式以很高的qz值进行具有大m / z的离子的分离，所以可以确保高质量选择性。

9. 发明公开

EP1801847A3 Ion fragmentation parameter selection systems and methods 审中-公开
标题翻译：系统和用于在离子碎裂选择参数的方法
公开(公告)号：EP1801847A3
公开(公告)日：2010-04-14
申请号：EP06026093.2
申请日：2006-12-15
申请人： Varian, Inc.
发明人： Specht, August , Wells, Gregory J.
IPC分类号： H01J49/42
CPC分类号： H01J49/424 , H01J49/0045
摘要： In some embodiments, a tandem (MS/MS) mass spectrometry method includes selecting a collision-induced dissociation (CID) voltage amplitude and a q -parameter value for a quadrupole ion trap to optimize a daughter ion fragmentation process for a given parent ion mass-to-charge (m/z) ratio. The q and CID voltage values may be selected according to a look-up table and/or using approximate analytical expressions. The correspondence between m/z values and (q, CID) value pairs may be established by pre-measurement calibration. A fragmentation-optimized q value may be computed according to m/z, and a CID voltage value may be determined according to the computed q value. A user may also force q to another value, for example in order to facilitate trapping of a desired daughter ion mass range, and the controller computes a CID voltage value according to the forced q value.

10. 发明公开

EP2126959A2 COAXIAL HYBRID RADIO FREQUENCY ION TRAP MASS ANALYZER 审中-公开
标题翻译：离子阱质谱分析UNIT FOR同轴电缆混合无线电频率
公开(公告)号：EP2126959A2
公开(公告)日：2009-12-02
申请号：EP08726092.3
申请日：2008-02-25
申请人： Brigham Young University
发明人： TOLLEY, Samuel, E. , AUSTIN, Daniel, E. , HAWKINS, Aaron, R. , LEE, Edgar, D.
IPC分类号： H01J49/22
CPC分类号： H01J49/424 , H01J49/4235
摘要： A coaxial hybrid ion trap (20) that uses two substantially planar opposing plates (22, 24) to generate electrical focusing fields that simultaneously generate at least two different types or shapes of trapping regions, wherein a first trapping region is a quadrupole trapping region (40) disposed coaxially with respect to the opposing plates (22, 24), and wherein a second trapping region is a toroidal ion trap having a toroidal trapping region (43) that is simultaneously created around the quadrupole trapping region (40).

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