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1. 发明公开

EP0340168A3 Photographische Innenbildemulsionen 失效
标题翻译：摄影内部图像乳液
公开(公告)号：EP0340168A3
公开(公告)日：1990-09-19
申请号：EP89810292.6
申请日：1989-04-18
申请人： ILFORD AG
发明人： Kriebel, Arnd, Dr.
IPC分类号： G03C1/485
CPC分类号： G03C1/035 , G03C1/48576 , G03C2001/03547
摘要： Photographische Innenbildemulsionen, bestehend aus Silberhalogenidkristallen mit einem jodidbeschichteten kubooktaedrischen Kern und einer Silberbromidhülle mit kubischen und/oder oktaedrischen Begrenzungsflächen.

2. 发明公开

EP0517901A1 PROCESS FOR MAKING A PRESSURE FOG-RESISTANT PHOTOGRAPHIC ELEMENT 失效
标题翻译：用于生产的BACKPRESSUREEXHAUST耐面纱摄影元件。
公开(公告)号：EP0517901A1
公开(公告)日：1992-12-16
申请号：EP92903683.0
申请日：1991-12-18
申请人： EASTMAN KODAK COMPANY
发明人： LUSHINGTON, Kenneth, J. c.o. Eastman Kodak Co. , TANDON, Sucheta c/o Eastman Kodak Co.
IPC分类号： G03C1
CPC分类号： G03C1/015 , G03C2001/03523 , G03C2001/03547 , G03C2001/03582
摘要： Procédé de prévention du voile causé par la pression dans une émulsion photographique de bromure d'argent, comprenant le traitement de surface des grains de bromure d'argent de l'émulsion au moyen d'un thiocyanate et d'un sel d'iodure. En particulier, l'invention décrit un procédé de fabrication d'une émulsion photographique résistant au voile causé par la pression et comprenant les étapes suivantes: constitution d'une émulsion photographique contenant des grains de bromure d'argent cubiques ou cubo-octahédriques; traitement de surface des grains de bromure d'argent avec un thiocyanate par addition dudit thiocyanate à l'émulsion; sensibilisation chimique de l'émulsion par maintien à une température et pendant une durée suffisantes pour permettre la réaction du thiocyanate et des surfaces des grains; traitement de surface des grains de bromure d'argent au moyen d'un sel d'iodure par addition dudit sel à l'émulsion en quantité et dans des conditions appropriées au remplissage des faces cubiques des grains de bromure d'argent. La dernière étape convertit les grains de bromure d'argent, totalement ou partiellement, en grains octahédriques. On peut ensuite fabriquer un élément photographique en recouvrant une base appropriée avec l'émulsion.

3. 发明公开

EP1111449A3 Improved performance of high speed emulsions for color film 有权
标题翻译：对于彩色胶片高度敏感乳液的性能改进
公开(公告)号：EP1111449A3
公开(公告)日：2003-01-29
申请号：EP00204391.7
申请日：2000-12-08
申请人： EASTMAN KODAK COMPANY
发明人： Eikenberry, Jon Nathan, c/o Eastman Kodak Company , Southby, David Thomas, c/o Eastman Kodak Company
IPC分类号： G03C1/10 , G03C7/392 , G03C7/305 , G03C1/035
CPC分类号： G03C1/10 , G03C1/035 , G03C1/12 , G03C7/3003 , G03C7/3022 , G03C7/30547 , G03C7/39208 , G03C2001/0055 , G03C2001/03541 , G03C2001/03547 , G03C2001/03558 , G03C2001/03594 , G03C2007/325 , G03C2200/11 , G03C2200/24 , Y10S430/156
摘要： A photographic element comprises a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises a) an emulsion with 3D, core/shell grains of at least 0.40 µm average diameter having a high iodide content in the core of the grain with a shell containing a lesser amount of iodide, b) a one-equivalent image-dye forming coupler, and c) a fragmentable electron donating compound of the formula: X-Y' or a compound which contains a moiety of the formula -X-Y'; wherein X is an electron donor moiety, Y' is a leaving proton H or a leaving group Y, with the proviso that if Y' is a proton, a base, β - , is covalently linked directly or indirectly to X, and wherein: 1) X-Y' has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X-Y' undergoes a bond cleavage reaction to give the radical X• and the leaving fragment Y'; and, optionally, 3) the radical X• has an oxidation potential ≤-0.7V (that is, equal to or more negative than about -0.7V).

4. 发明授权

EP0517901B1 PROCESS FOR MAKING A PRESSURE FOG-RESISTANT PHOTOGRAPHIC ELEMENT 失效
标题翻译：用于生产的BACKPRESSUREEXHAUST耐面纱摄影元件
公开(公告)号：EP0517901B1
公开(公告)日：1997-03-12
申请号：EP92903683.8
申请日：1991-12-18
申请人： EASTMAN KODAK COMPANY
发明人： LUSHINGTON, Kenneth, J. c.o. Eastman Kodak Co. , TANDON, Sucheta c/o Eastman Kodak Co.
IPC分类号： G03C1/015
CPC分类号： G03C1/015 , G03C2001/03523 , G03C2001/03547 , G03C2001/03582
摘要： A method for controlling pressure-induced fog in a silver bromide photographic material involves surface treatment of the emulsion AgBr grains with thiocyanate and an iodide salt. In particular, a process for making a pressure fog-resistant photographic emulsion includes steps of forming a photographic emulsion containing cubic or cubooctahedral silver bromide grains, surface-treating the AgBr grains with a thiocyanate by adding the thiocyanate to the emulsion, chemically sensitizing the emulsion, maintaining the emulsion at a temperature and for a time sufficient to allow the thiocyanate to react with the grain surfaces, and then surface-treating the AgBr gains with an iodide salt by adding the salt to the emulsion in an amount and under conditions effective to fill in cubic faces of the AgBr grains. The latter step partially or fully converts the AgBr grains to octahedral grains. A photographic element can then be made by coating the emulsion on a suitable base.

5. 发明公开

EP1111449A2 Improved performance of high speed emulsions for color film 有权
标题翻译： Verbesserte Leistung hochempfindlicher EmulsionenfürFarbfilme
公开(公告)号：EP1111449A2
公开(公告)日：2001-06-27
申请号：EP00204391.7
申请日：2000-12-08
申请人： EASTMAN TECHNOLOGY, INC.
发明人： Eikenberry, Jon Nathan, c/o Eastman Kodak Company , Southby, David Thomas, c/o Eastman Kodak Company
IPC分类号： G03C1/10 , G03C7/392 , G03C7/305 , G03C1/035
CPC分类号： G03C1/10 , G03C1/035 , G03C1/12 , G03C7/3003 , G03C7/3022 , G03C7/30547 , G03C7/39208 , G03C2001/0055 , G03C2001/03541 , G03C2001/03547 , G03C2001/03558 , G03C2001/03594 , G03C2007/325 , G03C2200/11 , G03C2200/24 , Y10S430/156
摘要： A photographic element comprises a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises

a) an emulsion with 3D, core/shell grains of at least 0.40 µm average diameter having a high iodide content in the core of the grain with a shell containing a lesser amount of iodide,
b) a one-equivalent image-dye forming coupler, and
c) a fragmentable electron donating compound of the formula: X-Y' or a compound which contains a moiety of the formula -X-Y';
wherein
X is an electron donor moiety, Y' is a leaving proton H or a leaving group Y, with the proviso that if Y' is a proton, a base, β - , is covalently linked directly or indirectly to X, and wherein:

1) X-Y' has an oxidation potential between 0 and about 1.4 V; and
2) the oxidized form of X-Y' undergoes a bond cleavage reaction to give the radical X • and the leaving fragment Y; and, optionally,
3) the radical X • has an oxidation potential ≤-0.7V (that is, equal to or more negative than about -0.7V).
摘要翻译：照相材料包括载体，其载有青色染料影像形成单元，其包括至少一种与其相关联的至少一种形成青色染料的成色剂的感红卤化银乳剂层，品红色染料影像形成单元包括至少一种绿色染料成像单元，感光卤化银乳剂层，其具有与其相关的至少一种品红色染料形成成色剂，黄色染料成像单元，其包含至少一种感蓝卤化银乳剂层，其具有至少一种形成黄色染料的成色剂，其中至少所述乳剂层中的一个包括a）具有三维，具有至少0.40μm平均直径的芯/壳颗粒的乳液，其颗粒核中具有高碘含量，壳含有较少量的碘化物，b）一个 - 等同的图像 - 染料形成成色剂，和c）下式的可裂解供电子化合物：XY'或含有式-X-Y'部分的化合物; 其中X是电子给体部分，Y'是离开质子H或离去基团Y，条件是如果Y'是质子，则基团β - 直接或间接地共价连接到X和其中：1）XY'具有介于0和约1.4V之间的氧化电位; 和2）X-Y'的氧化形式经历键断裂反应，得到基团X 1和离去的片段Y; 和任选地，3）基团X 1具有≤-0.7V的氧化电位（即，等于或大于约-0.7V的负值）。

6. 发明公开

EP0340168A2 Photographische Innenbildemulsionen 失效
标题翻译：照相内部图像乳剂。
公开(公告)号：EP0340168A2
公开(公告)日：1989-11-02
申请号：EP89810292.6
申请日：1989-04-18
申请人： ILFORD AG
发明人： Kriebel, Arnd, Dr.
IPC分类号： G03C1/485
CPC分类号： G03C1/035 , G03C1/48576 , G03C2001/03547
摘要： Photographische Innenbildemulsionen, bestehend aus Silberhalogenidkristallen mit einem jodidbeschichteten kubooktaedrischen Kern und einer Silberbromidhülle mit kubischen und/oder oktaedrischen Begrenzungsflächen.
摘要翻译：照相内部图像乳剂包括具有jodidbeschichteten cubooctahedral溴化银核和立方和/或八面体的边界表面的卤化银晶体。

7. 发明授权

EP1111449B1 Improved performance of high speed emulsions for color film 有权
标题翻译：对于彩色胶片高度敏感乳液的性能改进
公开(公告)号：EP1111449B1
公开(公告)日：2005-04-20
申请号：EP00204391.7
申请日：2000-12-08
申请人： EASTMAN KODAK COMPANY
发明人： Eikenberry, Jon Nathan, c/o Eastman Kodak Company , Southby, David Thomas, c/o Eastman Kodak Company
IPC分类号： G03C1/10 , G03C7/392 , G03C7/305 , G03C1/035
CPC分类号： G03C1/10 , G03C1/035 , G03C1/12 , G03C7/3003 , G03C7/3022 , G03C7/30547 , G03C7/39208 , G03C2001/0055 , G03C2001/03541 , G03C2001/03547 , G03C2001/03558 , G03C2001/03594 , G03C2007/325 , G03C2200/11 , G03C2200/24 , Y10S430/156
摘要： A photographic element comprises a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises a) an emulsion with 3D, core/shell grains of at least 0.40 mu m average diameter having a high iodide content in the core of the grain with a shell containing a lesser amount of iodide, b) a one-equivalent image-dye forming coupler, and c) a fragmentable electron donating compound of the formula: X-Y' or a compound which contains a moiety of the formula -X-Y'; wherein X is an electron donor moiety, Y' is a leaving proton H or a leaving group Y, with the proviso that if Y' is a proton, a base, beta , is covalently linked directly or indirectly to X, and wherein: 1) X-Y' has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X-Y' undergoes a bond cleavage reaction to give the radical X and the leaving fragment Y; and, optionally, 3) the radical X has an oxidation potential ≤-0.7V (that is, equal to or more negative than about -0.7V).

8. 发明公开

EP1111449A8 Improved performance of high speed emulsions for color film 有权
标题翻译：对于彩色胶片高度敏感乳液的性能改进
公开(公告)号：EP1111449A8
公开(公告)日：2001-08-16
申请号：EP00204391
申请日：2000-12-08
申请人： EASTMAN KODAK CO
发明人： EIKENBERRY JON NATHAN , SOUTHBY DAVID THOMAS
IPC分类号： G03C7/32 , G03C1/035 , G03C1/08 , G03C1/10 , G03C1/12 , G03C7/30 , G03C7/305 , G03C7/392
CPC分类号： G03C1/10 , G03C1/035 , G03C1/12 , G03C7/3003 , G03C7/3022 , G03C7/30547 , G03C7/39208 , G03C2001/0055 , G03C2001/03541 , G03C2001/03547 , G03C2001/03558 , G03C2001/03594 , G03C2007/325 , G03C2200/11 , G03C2200/24 , Y10S430/156
摘要： A photographic element comprises a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said emulsion layers comprises a) an emulsion with 3D, core/shell grains of at least 0.40 mu m average diameter having a high iodide content in the core of the grain with a shell containing a lesser amount of iodide, b) a one-equivalent image-dye forming coupler, and c) a fragmentable electron donating compound of the formula: X-Y' or a compound which contains a moiety of the formula -X-Y'; wherein X is an electron donor moiety, Y' is a leaving proton H or a leaving group Y, with the proviso that if Y' is a proton, a base, beta , is covalently linked directly or indirectly to X, and wherein: 1) X-Y' has an oxidation potential between 0 and about 1.4 V; and 2) the oxidized form of X-Y' undergoes a bond cleavage reaction to give the radical X and the leaving fragment Y; and, optionally, 3) the radical X has an oxidation potential ≤-0.7V (that is, equal to or more negative than about -0.7V).

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