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    • 2. 发明公开
    • VERFAHREN UND ANORDNUNG ZUR IDENTIFIKATION KRISTALLINER PHASEN SOWIE EIN ENTSPRECHENDES COMPUTERPROGRAMM UND EIN ENTSPRECHENDES COMPUTERLESBARES SPEICHERMEDIUM
    • 方法和系统识别晶相和相应的计算机程序和相应的计算机可读存储介质
    • EP3137885A1
    • 2017-03-08
    • EP15713482.6
    • 2015-03-31
    • Bruker Nano GmbH
    • SCHWAGER, Thomas
    • G01N23/203G01N23/22G01N23/225
    • G01N23/2206G01N23/203G01N23/2076G01N23/2252G01N2223/605
    • The invention relates to a method for identifying crystalline phases in a polycrystalline sample, comprising the method steps: a) for each crystal structure that is suspected in the sample, determining a normalized vector p(i) for the chemical composition of the crystal structure, wherein the basis of the vector represents elements and/or compounds and thus the coordinates of the vector comprise details about the concentration of the elements and/or compounds inside the crystal structure; b) at each measurement point of the sample, (i) recording of a spectrum by means of energy-dispersive X-ray spectroscopy (EDX spectrum) and determining of the chemical composition and (ii) recording of an electron diffraction image and determining of the diffraction bands; c) determining of a normalized vector v for the chemical composition at the measurement point, the coordinates whereof comprise details about the concentration of the elements and/or compounds at the measurement point; d) comparison of the normalized vector v for the chemical composition at the measurement point with each of the normalized vectors p(i) of the suspected crystal structures by issuing an evaluation factor s(i) for correlating each vector; e) comparison of the diffraction bands determined at the measurement point with the diffraction bands of the suspected crystal structures by issuing an evaluation factor n(i) for correlating the diffraction bands; and f) determining an overall quality from the two evaluation factors s(i) and n(i) and attributing the crystal structure with the highest overall quality to the measurement point.
    • 本发明涉及一种用于确定多晶样品中的结晶相的方法,包括步骤:a)为每个晶体结构没有样品的,确定性的采矿归一化的向量p(i)以用于晶体结构的化学组成被怀疑, worin向量darstellt元素和/或化合物,因此矢量的坐标包括关于元素和/或晶体结构内化合物的浓度细节的基础; b)在所述样品的各测量点,(i)在能量色散型X射线光谱(EDX谱)和化学组成的确定性采矿和(ii)的电子衍射图像的记录和确定性采矿手段的光谱的记录 衍射带; c)为测量点的化学组成的归一化矢量v的确定性采矿,WHEREOF包含约在测量点处的元件和/或化合物的浓度细节的坐标; D)通过用于相关每个向量的评估因子序列s(i)发出用于在与每个疑似晶体结构的归一化矢量P(i)的测量点的化学组成的归一化矢量v的比较; e)通过用于相关的衍射带的评估因子n(I)的发出在与疑似晶体结构的衍射带的测定点开采的衍射带的确定性比较; 和f)在整体质量N(I)确定的采矿来自两个评价因子S(i)和具有最高总体质量测量点归因晶体结构。
    • 5. 发明公开
    • X-RAY SPECTROMETRY DETECTOR DEVICE
    • DETEKTORVORRICHTUNGFÜRDIERÖNTGENSPEKTROMETRIE
    • EP2772752A1
    • 2014-09-03
    • EP12844011.2
    • 2012-08-21
    • Hamamatsu Photonics K.K.
    • SOEJIMA Hiroyoshi
    • G01N23/223G01N23/225
    • G01N23/2076G01N23/223G01N2223/076
    • An X-ray spectrometric detection device 1A includes a dispersive crystal 20 and a two-dimensional X-ray detector 30, spectrally resolves characteristic X-rays 2 emitted from a micro analysis spot P having a diameter of 100 µm or less on a surface of a sample 10 irradiated with X-rays or an electron beam, and detects the resolved X-rays by wavelength. The dispersive crystal 20 has a flat diffractive reflection surface 20a for receiving the characteristic X-rays 2 emitted from the micro analysis spot P and diffracts and reflects a wavelength component corresponding to an incident angle to the diffractive reflection surface 20a in wavelength components included in the characteristic X-rays 2, so as to spectrally resolve the characteristic X-rays 2 by wavelength. The detector 30 has a light-receiving surface 30a for receiving the characteristic X-rays 2 diffracted and reflected by the dispersive crystal 20, and generates data concerning an incident position and intensity of the characteristic X-rays 2 incident on the light-receiving surface 30a.
    • X射线光谱检测装置1A包括分散晶体20和二维X射线检测器30,对从直径为100μm以下的微分析点P发出的特征X射线2进行光谱分解, 用X射线或电子束照射的样品10,并通过波长检测分辨的X射线。 分散晶体20具有平坦的衍射反射表面20a,用于接收从微分析点P发射的特征X射线2,并将与衍射反射表面20a的入射角相对应的波长成分衍射并反射到包含在 特征X射线2,以便通过波长对特征X射线2进行光谱分解。 检测器30具有用于接收由分散晶体20衍射和反射的特征X射线2的光接收表面30a,并且生成关于入射在受光面上的特征X射线2的入射位置和强度的数据 30A。