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1. 发明授权

EP3268433B1 HIGH OIL CONTENT WAXES FOR FOOD GRADE AND HIGH QUALITY USES AND THE METHODS OF MAKING THE SAME 有权
公开(公告)号：EP3268433B1
公开(公告)日：2024-08-21
申请号：EP16714618.2
申请日：2016-03-04
IPC分类号： C08L91/08 , C10G69/02 , C10M101/02
CPC分类号： C08L91/08 , C08L2205/0220130101 , C10G73/44

2. 发明公开

EP2931848A1 PROCESS FOR PREPARING A HYDROWAX 审中-公开
标题翻译：用于生产蜡油
公开(公告)号：EP2931848A1
公开(公告)日：2015-10-21
申请号：EP13820752.7
申请日：2013-12-17
申请人： Shell Internationale Research Maatschappij B.V.
发明人： BARIC, John Joseph , VAN DIJK, Nicolaas , HUVE, Laurent Georges
IPC分类号： C10G65/12 , B01J21/12 , B01J23/888 , B01J37/20 , B01J29/08 , C10G73/44
CPC分类号： C10M101/025 , B01J23/882 , B01J29/076 , B01J29/166 , C10G47/16 , C10G65/12 , C10G73/44 , C10G2300/301
摘要： The invention provides a process for preparing a hydrowax comprising the steps of: (a) providing a hydrocarbonaceous feedstock which contains more than 4% by weight of hydrocarbons boiling in the range of from 550 to 800 °C; (b) hydrotreating the hydrocarbonaceous feedstock with a hydrotreating catalyst in the presence of a hydrogen- containing gas under hydrotreating conditions to obtain a hydrotreated product; (c) hydrocracking at least part of the hydrotreated product as obtained in step (b) with a hydrocracking catalyst in the presence of a hydrogen-containing gas under hydrocracking conditions to obtain a hydrocracked product, which hydrocracking catalyst contains a zeolitic component which is present in an amount of at least 14 wt%, based on the total weight of the hydrocracking catalyst, and wherein the volume ratio of the hydrotreating catalyst as used in step (b) and the hydrocracking catalyst is more than 1; and (d) recovering from the hydrocracked product as obtained in step (c) the hydrowax.

3. 发明公开

EP2867344A1 PROCESS TO PREPARE MIDDLE DISTILLATES AND BASE OILS 审中-公开
标题翻译：用于生产中间馏分油和基础油
公开(公告)号：EP2867344A1
公开(公告)日：2015-05-06
申请号：EP13734030.3
申请日：2013-06-28
申请人： Shell Internationale Research Maatschappij B.V.
发明人： KIEFFER, Eduard Philip , RIGUTTO, Marcello Stefano , SIETSMA, Jelle Rudolf Anne
IPC分类号： C10G65/12 , C10G65/04 , C10G73/02 , C10G73/44 , C10G45/62 , C10G45/64 , C10L1/08
CPC分类号： C10G67/02 , C10G45/62 , C10G45/64 , C10G65/00 , C10G65/043 , C10G65/12 , C10G65/16 , C10G73/02 , C10G73/44 , C10G2300/1022 , C10G2300/301
摘要： The present invention provides a process to prepare a first middle distillates fraction, a second middle distillates fraction and one or more base oils, which process at least comprises the following steps: (a) providing a Fischer-Tropsch product stream; (b) separating the Fischer-Tropsch product stream of step (a), thereby obtaining at least a low boiling fraction, boiling below a temperature in the range of from 300 to 450°C, and a high boiling fraction, boiling above a temperature in the range of from 300 to 450°C; (c) subjecting the high boiling fraction of step (b) to a hydrocracking/hydroisomerization step to obtain an at least partially isomerised product stream; (d) separating the product stream of step (c), thereby obtaining a first middle distillates fraction and a residual fraction, wherein the residual fraction has a T10wt.% boiling point of between 200 and 450°C; (e) dewaxing the low boiling fraction of step (b) to obtain a second middle distillates fraction; and f) dewaxing the residual fraction of step (d) to obtain one or more base oils.

4. 发明授权

EP1409613B1 PROCESS FOR PREPARING A MICROCRYSTALLINE WAX 有权
标题翻译：用于生产微晶蜡
公开(公告)号：EP1409613B1
公开(公告)日：2006-09-13
申请号：EP02748783.4
申请日：2002-06-13
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： HOEK, Arend , SCHADENBERG, Hendrik
IPC分类号： C10G73/44
CPC分类号： C10G45/62 , C10G73/44 , C10G2300/1022 , C10G2300/301 , C10G2300/4018 , C10G2400/10
摘要： Process to prepare a microcrystalline wax by contacting under hydroisomerisation conditions a feed, comprising at least 80 wt % of normal-paraffins and having a congealing point of above 60 DEG C, with a catalyst comprising a noble metal and a porous silica-alumina carrier.

5. 发明公开

EP1409613A2 PROCESS FOR PREPARING A MICROCRYSTALLINE WAX 有权
标题翻译：用于生产微晶蜡
公开(公告)号：EP1409613A2
公开(公告)日：2004-04-21
申请号：EP02748783.4
申请日：2002-06-13
申请人： SHELL INTERNATIONALE RESEARCHMAATSCHAPPIJ B.V.
发明人： HOEK, Arend , SCHADENBERG, Hendrik
IPC分类号： C10G73/44
CPC分类号： C10G45/62 , C10G73/44 , C10G2300/1022 , C10G2300/301 , C10G2300/4018 , C10G2400/10
摘要： Process to prepare a microcrystalline wax by contacting under hydroisomerisation conditions a feed, comprising at least 80 wt % of normal-paraffins and having a congealing point of above 60 °C, with a catalyst comprising a noble metal and a porous silica-alumina carrier.

6. 发明公开

EP3240873A1 PROCESS TO PREPARE PARAFFIN WAX 有权转让
标题翻译：制备石蜡的过程
公开(公告)号：EP3240873A1
公开(公告)日：2017-11-08
申请号：EP15817900.2
申请日：2015-12-29
申请人： Shell Internationale Research Maatschappij B.V.
发明人： HOEK, Arend , ROOVERS, Antonius, Adrianus, Maria , MAJUMDER, Kaushik , TOLEDANO, Hélène
IPC分类号： C10G45/02 , C10G65/04 , C10G73/36 , C10G73/44 , C10G2/00 , C08L91/08
CPC分类号： C10G73/44 , C08L91/08 , C10G2/32 , C10G45/02 , C10G65/04 , C10G73/36 , C10G2300/1022 , C10G2300/30
摘要： The present invention provides a process to prepare paraffins and waxes, the process at least comprising the following steps: (a) providing a Fischer-Tropsch product stream comprising paraffins having from 10 to 300 carbon atoms; (b) subjecting the Fischer-Tropsch product stream of step (a) to a hydrogenation step, thereby obtaining a hydrogenated Fischer-Tropsch product stream comprising 10 to 300 carbon atoms; (c) separating the hydrogenated Fischer-Tropsch product stream of step (b), thereby obtaining at least a fraction comprising 10 to 17 carbon atoms and a fraction comprising 18 to 300 carbon atoms; (d) separating the hydrogenated fraction comprising 18 to 300 carbon atoms of step (c), thereby obtaining one or more first light waxes having a congealing point in the range of 30 to 75°C and a second heavy wax having a congealing point in the range of 75 to 120°C; e) hydrofinishing one or more wax fractions having a congealing point in the range of 30 to 75°C of step (d) thereby obtaining one or more hydrofinished wax fractions having a congealing point in the range of 30 to 75°C.

7. 发明公开

EP3040403A1 Process to prepare a paraffin wax 审中-公开
标题翻译：制备石蜡的方法
公开(公告)号：EP3040403A1
公开(公告)日：2016-07-06
申请号：EP14200720.2
申请日：2014-12-31
申请人： Shell Internationale Research Maatschappij B.V.
发明人： Toledano, Hélène , Hoek, Arend
IPC分类号： C10G45/02 , C10G65/04 , C10G73/36 , C10G73/44 , C10G2/00 , C08L91/08
CPC分类号： C10G45/02 , C08L91/08 , C10G2/32 , C10G65/04 , C10G73/36 , C10G73/44 , C10G2300/1022
摘要： The present invention provides a process to prepare paraffins and waxes, the process at least comprising the following steps:
(a) providing a Fischer-Tropsch product stream comprising paraffins having from 10 to 300 carbon atoms;
(b) separating the Fischer-Tropsch product stream of step (a), thereby obtaining at least a fraction comprising 10 to 17 carbon atoms and a fraction comprising 18 to 300 carbon atoms;
(c) subjecting the fraction comprising 10 to 17 carbon atoms of step (b) to a hydrogenation step, thereby obtaining hydrogenated paraffins comprising 10 to 17 carbon atoms;
(d) subjecting the fraction comprising 18 to 300 carbon atoms of step (b) to a hydrogenation step, thereby obtaining a hydrogenated fraction comprising 18 to 300 carbon atoms;
(e) separating the hydrogenated fraction comprising 18 to 300 carbon atoms of step (d), thereby obtaining one or more first light waxes having a congealing point in the range of 30 to 75°C and a second heavy wax having a congealing point in the range of 75 to 120°C;
f) hydrofinishing one or more wax fractions having a congealing point in the range of 30 to 75°C of step (e) thereby obtaining one or more hydrofinished wax fractions having a congealing point in the range of 30 to 75°C.
摘要翻译：本发明提供了制备石蜡和蜡的方法，所述方法至少包括以下步骤：（a）提供包含具有10-300个碳原子的石蜡的费 - 托产品物流; （b）分离步骤（a）的费 - 托产物流，由此获得至少一个包含10至17个碳原子的部分和包含18至300个碳原子的部分; （c）将步骤（b）的包含10-17个碳原子的馏分进行氢化步骤，从而获得包含10-17个碳原子的氢化链烷烃; （d）将步骤（b）的包含18至300个碳原子的馏分进行氢化步骤，从而获得包含18至300个碳原子的氢化馏分; （e）分离步骤（d）中包含18至300个碳原子的氢化馏分，从而获得一种或多种凝固点在30至75℃范围内的第一轻质蜡和凝固点为 75至120°C的范围; f）加热精制步骤（e）的凝固点在30-75℃范围内的一种或多种蜡馏分，从而获得凝固点在30-75℃范围内的一种或多种加氢蜡馏分。

8. 发明公开

EP1498469A2 Process for preparing a microcrystalline wax 有权
标题翻译： Ein mikrokristallines Wachs
公开(公告)号：EP1498469A2
公开(公告)日：2005-01-19
申请号：EP04102821.8
申请日：2002-06-13
申请人： SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V.
发明人： Hoek, Arend , Schadenberg, Hendrik
IPC分类号： C10L1/08 , C10G73/44
CPC分类号： C10G45/62 , C10G73/44 , C10G2300/1022 , C10G2300/301 , C10G2300/4018 , C10G2400/10
摘要： Microcrystalline wax having a congealing point of between 85 and 120 °C and a PEN at 43 °C as determined by IP 376 of more than 0.8 mm. Process to prepare a microcrystalline wax by contacting under hydroisomerisation conditions a feed, comprising at least 80 wt% of normal-paraffins and having a congealing point of above 60 °C, with a catalyst comprising a noble metal and a porous silica-alumina carrier.
摘要翻译：凝结点在85和120℃之间的微晶蜡和通过IP 376确定的43℃下PEN大于0.8mm的微晶蜡。通过在加氢异构化条件下使包含至少80重量％的正链烷烃并且具有高于60℃的凝固点的进料与包含贵金属和多孔二氧化硅 - 氧化铝载体的催化剂接触来制备微晶蜡的方法。

9. 发明授权

EP1268712B1 PROCESS FOR SOFTENING FISCHER-TROPSCH WAX WITH MILD HYDROTREATING 有权
标题翻译： WEICHMACHUNGSVERFAHREN费 - TROPSCHWACHSEN BY加氢处理在温和条件下
公开(公告)号：EP1268712B1
公开(公告)日：2004-08-11
申请号：EP01927411.7
申请日：2001-03-16
申请人： ExxonMobil Research and Engineering Company
发明人： WITTENBRINK, Robert, Jay , RILEY, Daniel, Francis
IPC分类号： C10G45/58 , C10G2/00 , C10G73/44
CPC分类号： C10G73/44

10. 发明公开

EP1268712A2 PROCESS FOR SOFTENING FISCHER-TROPSCH WAX WITH MILD HYDROTREATING 有权
标题翻译： WEICHMACHUNGSVERFAHREN费 - TROPSCHWACHSEN BY加氢处理在温和条件下
公开(公告)号：EP1268712A2
公开(公告)日：2003-01-02
申请号：EP01927411.7
申请日：2001-03-16
申请人： ExxonMobil Research and Engineering Company
发明人： WITTENBRINK, Robert, Jay , RILEY, Daniel, Francis
IPC分类号： C10G45/58 , C10G2/00 , C10G73/44
CPC分类号： C10G73/44
摘要： A novel process for forming hydrocarbon waxes from synthesis gas is disclosed. This invention teaches a process whereby a Fischer-Tropsch wax can be formulated such that the wax softness as defined by ASTM Standard Test Method for Needle Penetration of waxes (ASTM D- 1321) can be adjusted to within a region most preferred for end use applications while simultaneously removing undesirable impurities, such as oxygenates (e.g., primary alcohols), olefins, and trace levels of aromatics. In a Fischer-Tropsch reactor, Fischer-Tropsch wax is formed from synthesis gas in a catalyzed reaction. The Fischer-Tropsch wax is then subjected to a relatively mild hydroprocessing over a hydroisomerization catalyst under conditions such that essentially no boiling point conversion is obtained, but yet chemical conversions (e.g., hydrogenation and mild isomerization) occur yielding a high purity, hydrocarbon wax product of reduced hardness.

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