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1. 发明公开

EP1141170A1 RARE EARTH-ACTIVATED PHOSPHORS 审中-公开
标题翻译： MIT SELTENEN ERDEN AKTIVIERTE LEUCHTSTOFFE
公开(公告)号：EP1141170A1
公开(公告)日：2001-10-10
申请号：EP99962349.9
申请日：1999-12-17
申请人： ISIS INNOVATION LIMITED
发明人： DOBSON, Peter James,University of Oxford , WAKEFIELD, Gareth,University of Oxford
IPC分类号： C09K11/78 , C09K11/67 , C09K11/62
CPC分类号： C09K11/681 , C09K11/621 , C09K11/623 , C09K11/641 , C09K11/671 , C09K11/672 , C09K11/676 , C09K11/682 , C09K11/685 , C09K11/7701 , C09K11/7702 , C09K11/7706 , C09K11/7708 , C09K11/7717 , C09K11/7721 , C09K11/7729 , C09K11/773 , C09K11/7734 , C09K11/7744 , C09K11/7745 , C09K11/7749 , C09K11/776 , C09K11/7764 , C09K11/7767 , C09K11/7769 , C09K11/7774 , C09K11/7785 , C09K11/7787 , C09K11/7792 , Y10T428/2982 , Y10T428/2991
摘要： A process for preparing phosphor particles of a host oxide doped with a rare earth or manganese which comprises:preparing an aqueous solution of salts of the host ion and of the dopant ion and a water soluble compound which decomposes under the reaction conditions to convert said salts into hydroxycarbonate,heating the solution so as to cause said compound to decompose,recovering the resulting precipitate andcalcining it at a temperature of at least 500° C.Substantially monocrystalline particles can be obtained by this process.
摘要翻译：一种制备掺杂有稀土或锰的主体氧化物的荧光体颗粒的方法，包括：制备主体离子和掺杂离子的盐的水溶液和在反应条件下分解以转化所述盐的水溶性化合物加入溶液，使所述化合物分解，回收所得沉淀物并在至少500℃的温度下煅烧。可以通过该方法获得大部分单晶颗粒。

2. 发明公开

EP0836791A1 DOPED AMORPHOUS AND CRYSTALLINE GALLIUM OXIDES, ALKALINE EARTH GALLATES AND DOPED ZINC GERMANATE PHOSPHORS AS ELECTROLUMINESCENT MATERIALS 失效
标题翻译：掺杂质和结晶GALLIUMOXIDE，ERDALKALIGALLATE和掺杂ZINKGERMANAT磷作为电
公开(公告)号：EP0836791A1
公开(公告)日：1998-04-22
申请号：EP96920663.0
申请日：1996-07-04
申请人： Kitai, Adrian H.
发明人： XIAO, Tian , KITAI, Adrian H. , LIU, Guo
IPC分类号： C09K11 , H05B33
CPC分类号： H05B33/14 , C09K11/662 , C09K11/666 , C09K11/7701 , C09K11/7703 , C09K11/7729 , C09K11/7731 , C09K11/7744 , C09K11/7746 , C09K11/7767 , C09K11/7768 , C09K11/7784 , C09K11/7786 , H05B33/10
摘要： New oxide phosphors based on doped gallium oxides, alkaline earth gallates and germanates for electroluminescent display materials. Bright orange red electroluminescence has been obtained in amorphous and crystalline oxides Ga2O3:Eu for the first time. SrGa2O4 and SrGa4O9 doped with 1-8 mole % of Eu and Tb, CaGa2O4, Ca3Ga2O6 and CaGa4O7 doped with 1-4 mole % of Eu, Tb, Pr and Dy, BaGa2O4 doped with 1-2 mole % of Eu and Tb, have been prepared using RF magnetron sputtering onto ceramic dielectric substrates and annealed at 600 °C - 950 °C in air or Ar for 1-2 hours. Bright electroluminescent (EL) emission was obtained with wavelengths covering the visible sprectrum from 400 to 700 nm, and infrared emission above 700 nm with spectral peaks characteristic of rare earth transitions. The films of CaGa2O4 with 1 mole % Eu achieved 22 fL (75 cd/m2) at 60 Hz and had a maximum efficiency of 0.2 lm/w for red emission. An amorphous thin film of Ca¿3?Ga2O6 with 2 mole % Eu achieved 34 fL in red EL at 60 Hz when annealed at 600 °C. SrGa2O4 with 1 mole % Eu and 4 mole % Tb yielded 'white' phosphor having red, green and blue emission (13 fL at 60 Hz), and SrGa2O4 with 8 mole % Tb resulted in a blue and green phosphor measuring 30 fL at 60 Hz. Zn2Si0.5Ge0.5O4 containing Mn was sputtered using magnetron RF sputtering onto ceramic dielectric substrates and annealed at 700 °C for 1 hour in air or argon. Bright green (540 nm) emission was obtained in electroluminescence: 110 fL (377 cd/m?2¿) at 60 Hz with a maximum efficiency of 0.9 l/w. Moderately bright red emission (640 nm) was also obtained.

3. 发明授权

EP0381233B1 Phosphor composition and process of phosphor preparation 失效
标题翻译：磷光体组合物和用于生产磷光体的方法。
公开(公告)号：EP0381233B1
公开(公告)日：1994-06-29
申请号：EP90102098.2
申请日：1990-02-02
申请人： EASTMAN KODAK COMPANY
发明人： Bryan, Philip Steven, c/o EASTMAN KODAK COMPANY , Lambert, Patrick Maddock, c/o EASTMAN KODAK COMPAN , Towers, Christine May, c/o EASTMAN KODAK COMPAN , Jarrold, Gregory Scott, c/o EASTMAN KODAK COMPAN
IPC分类号： C09K11/67 , G21K4/00
CPC分类号： C09K11/7701 , C09K11/671 , C09K11/7716 , C09K11/7729 , C09K11/7744 , C09K11/7756 , C09K11/776 , G21K4/00

4. 发明公开

EP0381233A3 Phosphor composition and process of phosphor preparation 失效
标题翻译：磷化合物的制备及其制备方法
公开(公告)号：EP0381233A3
公开(公告)日：1990-12-19
申请号：EP90102098.2
申请日：1990-02-02
申请人： EASTMAN KODAK COMPANY
发明人： Bryan, Philip Steven, c/o EASTMAN KODAK COMPANY , Lambert, Patrick Maddock, c/o EASTMAN KODAK COMPAN , Towers, Christine May, c/o EASTMAN KODAK COMPAN , Jarrold, Gregory Scott, c/o EASTMAN KODAK COMPAN
IPC分类号： C09K11/67 , G21K4/00
CPC分类号： C09K11/7701 , C09K11/671 , C09K11/7716 , C09K11/7729 , C09K11/7744 , C09K11/7756 , C09K11/776 , G21K4/00
摘要： A phosphor is disclosed having hafnia host containing at least one alkali metal and zirconia in concentrations higher than those found in optical grade hafnia. The phosphor can include as an activator titanium or rare earth ions. Phosphor preparation processes are also disclosed.

5. 发明公开

EP0381233A2 Phosphor composition and process of phosphor preparation 失效
标题翻译： Leuchtstoffzusammensetzung sowie Verfahren zur Leuchtstoffherstellung。
公开(公告)号：EP0381233A2
公开(公告)日：1990-08-08
申请号：EP90102098.2
申请日：1990-02-02
申请人： EASTMAN KODAK COMPANY
发明人： Bryan, Philip Steven, c/o EASTMAN KODAK COMPANY , Lambert, Patrick Maddock, c/o EASTMAN KODAK COMPAN , Towers, Christine May, c/o EASTMAN KODAK COMPAN , Jarrold, Gregory Scott, c/o EASTMAN KODAK COMPAN
IPC分类号： C09K11/67 , G21K4/00
CPC分类号： C09K11/7701 , C09K11/671 , C09K11/7716 , C09K11/7729 , C09K11/7744 , C09K11/7756 , C09K11/776 , G21K4/00
摘要： A phosphor is disclosed having hafnia host containing at least one alkali metal and zirconia in concentrations higher than those found in optical grade hafnia. The phosphor can include as an activator titanium or rare earth ions. Phosphor preparation processes are also disclosed.
摘要翻译：公开了一种具有含有至少一种碱金属和氧化锆的铪原子的磷光体，其浓度高于光学级hafnia中发现的浓度。磷光体可以包括作为活化剂的钛或稀土离子。还公开了磷光体制备方法。

6. 发明公开

EP0381232A2 X-ray intensifying screen 失效
标题翻译： Röntgenstrahlenverstärkungsschirm。
公开(公告)号：EP0381232A2
公开(公告)日：1990-08-08
申请号：EP90102097.4
申请日：1990-02-02
申请人： EASTMAN KODAK COMPANY
发明人： Bryan, Philip Steven,c/o Eastman Kodak Company, , Lambert, Patrick Maddock, Eastman Kodak Company , Towers, Christine May, Eastman Kodak Company , Jarrold, Gregory Scott, Eastman Kodak Company
IPC分类号： C09K11/67 , C09K11/78 , G21K4/00
CPC分类号： C09K11/7701 , C09K11/671 , C09K11/7716 , C09K11/7729 , C09K11/7744 , C09K11/7756 , C09K11/776 , G21K4/00
摘要： An intensifying screen for producing a latent image in a silver halide radiographic element when imagewise exposed to X-radiation is disclosed. The screen contains a phosphor having a hafnia host containing zirconia in concentrations higher than those found in optical grade hafnia. The phosphor can include as an activator one or a combination of titanium, rare earth, and alkali metal ions. Phosphor preparation processes are also disclosed.
摘要翻译：公开了一种用于在成像暴露于X辐射时在卤化银放射线照相元件中产生潜像的增强屏幕。屏幕中含有一种含有铪原子的磷光体，其含有氧化锆的浓度高于光学级的铪。磷光体可以包括作为活化剂的一种或钛，稀土和碱金属离子的组合。还公开了磷光体制备方法。

7. 发明公开

EP1997866A1 Radiation image phosphor or scintillator panel 审中-公开
标题翻译： Strahlungsbildleuchtschirm oder Szintillatorschirm
公开(公告)号：EP1997866A1
公开(公告)日：2008-12-03
申请号：EP07108598.9
申请日：2007-05-22
申请人： Agfa HealthCare NV
发明人： Tahon, Jean-Pierre, c/o Agfa HealthCare NV , Uyttendaele, Carlo, c/o Agfa HealthCare NV
IPC分类号： C09K11/84 , C09K11/85 , G21K4/00
CPC分类号： C09K11/7733 , C09K11/7744 , G21K4/00
摘要： In favour of adhesion between phosphor layer and support in a radiation image phosphor or scintillator panel comprising as an arrangement of layers, in consecutive order, a support, a precoat layer and a phosphor or scintillator layer having needle-shaped phosphor or scintillator crystals, said precoat layer comprises an organic non-cross-linkable polymer binder and a pigment in a weight ratio of pigment to binder in the range from 1/5 to 50/1.
摘要翻译：有利于在辐射图像荧光体或闪烁体面板中的荧光体层和支撑体之间的粘附，所述辐射图像荧光体或闪烁体面板以连续的顺序包括支撑体，预涂层和具有针状荧光体或闪烁体晶体的荧光体或闪烁体层的布置，所述预涂层包含有机非交联聚合物粘合剂和颜料与粘合剂的重量比在1/5至50/1范围内的颜料。

8. 发明公开

EP1901262A1 PHOSPHORESCENT MATERIAL, PROCESS FOR PRODUCING THE SAME, AND PHOSPHORESCENT DISPLAY ELEMENT 审中-公开
标题翻译：磷光体材料，紫色ZE SEINER HERSTELLUNG UND PHOSPHORESZIERENDES显示元件
公开(公告)号：EP1901262A1
公开(公告)日：2008-03-19
申请号：EP06756535.8
申请日：2006-05-24
申请人： Japan Science and Technology Agency
发明人： YAMANAKA, Akio , OKA, Kenji , YOSHIDA, Norifumi , HORIUCHI, Hiroshi
IPC分类号： G09F13/20
CPC分类号： G09F13/20 , C09K11/7744 , C09K11/7769 , C09K11/7787 , C30B13/24 , C30B29/16
摘要： A novel phosphorescent material is provided which has a narrow afterglow spectrum width, a choosable afterglow wavelength, a high moisture resistance, a high thermal resistance, and no optical anisotropy.
It comprises a single crystal made of scandium oxide and a rare earth element substituting scandium of said single crystal, and generates the afterglow having a wavelength and spectrum width based on 4f-4f transition of the rare earth ion by irradiating ultraviolet light of the energy corresponding to the energy gap between 5d orbital of the rare earth ion and 2p orbital of oxygen of scandium oxide, or the energy gap between 4f excited orbital of the rare earth ion and 2p orbital of oxygen of scandium oxide. By choosing a rare earth element, the afterglow wavelength can be chosen. Since the host crystal is scandium oxide, it has the thermal resistance of 1000°C or higher. Since the crystal structure of scandium oxide is cubic, there is no double refraction.
摘要翻译：提供了具有窄的余辉光谱宽度，可选择的余辉波长，高耐湿性，高耐热性和无光学各向异性的新型磷光材料。它包括由氧化钪制成的单晶和用所述单晶的钪取代的稀土元素，并且通过照射相应的能量的紫外光产生具有基于稀土离子的4f-4f跃迁的波长和光谱宽度的余辉到稀土离子的5d轨道和氧化钪的2p轨道之间的能隙，或稀土离子的4f激发轨道和氧化钪氧2p轨道之间的能隙。通过选择稀土元素，可以选择余辉波长。由于主晶体是氧化钪，所以其热阻为1000℃以上。由于氧化钪的晶体结构为立方体，因此不存在双重折射。

9. 发明公开

EP0597311A3 Method for recording and reproducing a radiation image, apparatus using said method, panel for storing the radiation image and photostimulable Phosphor 失效
标题翻译：用于记录和再现辐射图像的方法，使用方法的装置，用于存储辐射图像和可光化磷光体的面板。
公开(公告)号：EP0597311A3
公开(公告)日：1994-06-15
申请号：EP93117307.4
申请日：1993-10-26
申请人： MINNESOTA MINING AND MANUFACTURING COMPANY
发明人： Morlotti, Romano
IPC分类号： G21K4/00 , C09K11/78 , C09K11/80
CPC分类号： G21K4/00 , C09K11/7744 , C09K11/7746 , C09K11/7768 , C09K11/7769 , G21K2004/06
摘要： The present invention relates to new phosphors for use in panels, apparatus and methods for recording and reproducing a high energy radiation image, including the steps of stimulating a phosphor image-wise exposed to radiation and detecting the fluorescent light emitted by said phosphor upon stimulation, said phosphor being a green emitting terbium activated alkali metal tantalate, doped with at least one element selected in the group consisting of Mg, Ca, Sr, Ba, Al, Ga, Ge, Pb, Bi, transition elements and lanthanides.

10. 发明公开

EP0381234A3 X-ray intensifying screen and phosphor composition 失效
标题翻译： X射线增强屏幕和磷光体组成
公开(公告)号：EP0381234A3
公开(公告)日：1990-12-19
申请号：EP90102100.6
申请日：1990-02-02
申请人： EASTMAN KODAK COMPANY
发明人： Bryan, Philip Steven c/o Eastman Kodak Comp. , Lambert, Patrick Maddock c/o Eastman Kodak Comp. , Towers, Christine May c/o Eastman Kodak Comp. , Jarrold, Gregory Scott c/o Eastman Kodak Comp.
IPC分类号： C09K11/78 , G21K4/00
CPC分类号： G21K4/00 , C09K11/671 , C09K11/7701 , C09K11/7716 , C09K11/7729 , C09K11/7744 , C09K11/7756 , C09K11/776 , C09K11/7769 , C09K11/7787
摘要： An intensifying screen is disclosed containing a phosphor composition comprised of monoclinic crystals of a titanium activated hafnia phosphor host containing neodymium ions to reduce afterglow. A phosphor composition in which zirconia is at least partially substituted for hafnia is also disclosed.

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