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    • 7. 发明公开
    • THERMOPLASTIC POLYMER COMPOSITION, AND MOUDLED ARTICLE
    • EP3196250A4
    • 2018-05-02
    • EP15836800
    • 2015-08-10
    • KURARAY CO
    • MINAMIDE ASAKOMASUDA MIKIOJOGO YOSUKE
    • C08L53/02B29C65/48C08L23/26C08L29/14C08L51/06C09J123/14C09J123/26C09J129/14C09J151/06C09J153/02
    • B29C65/48C08L23/26C08L51/06C08L53/02C08L53/025C09J123/14C09J123/26C09J151/06C09J153/02C09J153/025C08L29/14
    • To provide a thermoplastic polymer composition, which can be adhered to a synthetic resin, a ceramic or a metal without performing a primer treatment or the like, is able to be handled as a molded article, exhibits an excellent adhesive property in a broad temperature range from a low temperature to room temperature and flexibility, and has high thermal creep resistance, and a molded article using the thermoplastic polymer composition. A thermoplastic polymer composition, which contains from 10 to 100 parts by weight of a polar group-containing polypropylene-based resin (B) based on 100 parts by weight of a hydrogenated block copolymer (A) in which block copolymer containing a polymer block (S) including an aromatic vinyl compound unit and a polymer block (D) including a conjugated diene compound unit is hydrogenated, in which the hydrogenated block copolymer (A) is a mixture containing a hydrogenated block copolymer (A1) having at least one tan ´ local maximum value in a range from -60 to -40°C, in which a block copolymer represented by formula (i) or (ii) shown below is hydrogenated: €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(i)€ƒ€ƒ€ƒ€ƒ€ƒ(S-D) n €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(ii)€ƒ€ƒ€ƒ€ƒ€ƒ(D-S) n -D (in the formulae above, S is a polymer block including an aromatic vinyl compound unit, D is a polymer block including a conjugated diene compound unit, and n is an integer from 1 to 5); and a hydrogenated block copolymer (A2) in which a block copolymer represented by formula (iii) shown below is hydrogenated: €ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ€ƒ(iii)€ƒ€ƒ€ƒ€ƒ€ƒ(S-D) m -S (in the formula above, S is a polymer block including an aromatic vinyl compound unit, D is a polymer block including a conjugated diene compound unit, and m is an integer from 1 to 5); and a weight ratio of the hydrogenated block copolymer (A1) to the hydrogenated block copolymer (A2) is from 20:80 to 99:1.
    • 8. 发明公开
    • MULTILAYER FILM
    • 多层电影
    • EP3251840A1
    • 2017-12-06
    • EP16743471.1
    • 2016-01-28
    • Kuraray Co., Ltd.
    • KAWAKITA, HiroshiNAKANO,KirihiroTAKEDA, Hideaki
    • B32B27/00B29C51/10C09J7/02C09J123/10C09J129/14C09J153/02B29K33/00
    • B29C47/065B29C51/10B29C65/48B29K2009/00B29K2021/003B29K2023/12B29K2025/00B29L2009/00B32B27/00B32B27/08B32B27/308C09J7/20C09J7/24C09J123/10C09J129/14C09J153/02C09J153/025C09J2205/10C09J2433/006C09J2451/00C09J2453/00C09J2453/006
    • Provided are a multilayer film, a method for producing the multilayer film, and a method for producing a molded body using the multilayer film. The multilayer film: has an adhesive layer; has excellent three-dimensional overlaying formability and adhesiveness after being formed into a three-dimensional overlay; can easily be used when being bonded to an adherend; maintains adhesive strength without breaking or wrinkling in a wide range of range temperatures; and is suitable for forming a vacuum. Specifically, the multilayer film has: an adhesive layer comprising a thermoplastic polymer composition containing a thermoplastic elastomer (A) which is a block copolymer or a hydrogenated product thereof having a polymer block (a1) containing aromatic vinyl compound units and having a polymer block (a2) containing conjugated diene compound units; and a base layer comprising an amorphous resin which has a modulus of elasticity of 2 to 600 MPa at an arbitrary temperature of 110 to 160°C. The tensile elongation at break of the multilayer film at a temperature 5°C lower than the glass transition temperature of the amorphous resin is at least 160%.
    • 本发明提供一种多层膜,该多层膜的制造方法以及使用该多层膜的成型体的制造方法。 多层膜:具有粘合剂层; 在形成三维覆盖层之后具有优异的三维重叠成形性和粘附性; 在粘合到被粘物上时可以很容易地使用; 在宽范围温度范围内保持粘合强度而不破裂或起皱; 并适用于形成真空。 具体而言,多层膜具有:含有热塑性聚合物组合物的粘合剂层,该热塑性聚合物组合物含有作为嵌段共聚物的热塑性弹性体(A)或其氢化物,该热塑性弹性体(A)具有含芳香族乙烯基化合物单元的聚合物嵌段(a1) a2)含有共轭二烯化合物单元; 以及在110〜160℃的任意温度下具有2〜600MPa的弹性模量的无定形树脂的基底层。 在比无定形树脂的玻璃化转变温度低5℃的温度下多层膜的断裂拉伸伸长率至少为160%。