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    • 5. 发明公开
    • REACTIVE DYES, THEIR PREPARATION AND THEIR USE
    • 风靡一时的FARBSTOFFE SOWIE IHRE HERSTELLUNG UND VERWENDUNG
    • EP2855597A1
    • 2015-04-08
    • EP13723425.8
    • 2013-04-25
    • Huntsman Advanced Materials (Switzerland) GmbH
    • MUELLER, AlexanderPLATTNER, KurtSCHOEHN, DamienHILDEBRAND, Rainer
    • C09B62/44D06P1/38D06P3/24
    • C09B62/095C07F11/005C09B62/4416D06P1/38D06P1/384D06P3/248D06P3/66D06P5/30
    • Reactive dyes of formula (1), wherein Me is chromium, cobalt or iron, R
      1 is hydrogen or unsubstituted or substituted C
      1 -C
      4 alkyl, E is a bivalent radical of formula (1a), (1b) or (1c) wherein X denotes chlorine or fluorine, T es a fibre-reactive radical of formula (2a), (2b), (2c), (2d), (2e), or (2f), (R3)0-2 denotes from 0 to 2 identical or different substituents from the group halogen, C
      1 -C
      4 alkyl, C
      1 -C
      4 alkoxy and sulfo, Z is vinyl or a -CH
      2 -CH
      2 -U radical and U is a group that is removable under alkaline conditions, Q is a -CH(Hal)-CH
      2 -Hal or -C(Hal)=CH
      2 group, q is the number 0 or 1, G is a bivalent radical of formula (1d) or (1e) wherein (R
      2 )s denotes s identical or different substituents from the group halogen, nitro, unsubstituted or halo-substituted C
      1 -C
      4 alkyl, C
      2 -C
      4 alkanoylamino, C
      1 -C
      4 alkylsulfonyl, carbamoyl, sulfamoyl, sulfo and -E-T, wherein E and T are as defined above, s is the number 0, 1, 2 or 3, A denotes a bivalent radical of formula (3a), (3b) or (3c), wherein R
      1 , R
      2 , X, T, q and s are as defined above, R
      4 and R
      7 denote hydrogen, C
      1 -C
      4 alkyl, -COOH or -COO- C
      1 -C
      4 alkyl, R
      5 and R
      6 represent, each independently of the other, identical or different substituents from the group hydroxyl, halogen, nitro, unsubstituted or halo-substituted C
      1 -C
      4 alkyl, C
      1 -C
      4 alkoxy, C
      2 -C
      4 alkanoylamino, C
      1 -C
      4 alkylsulfonyl, carbamoyl, sulfamoyl and sulfo, and t and u are each independently of the other the number 0, 1, 2 or 3, are especially suitable for dyeing synthetic polyamide fibre materials and yield dyeings or prints having good wet-fastness properties.
    • 特别适用于染色合成聚酰胺纤维材料并且产生具有良好耐湿性的染色或印花的式(101)的活性染料及其制备方法。