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1. 发明授权

EP0115818B1 Kationische Polyazofarbstoffe, ihre stabilen Lösungen, ihre Herstellung und ihre Verwendung 有权
标题翻译：阳离子聚氨酯，它们的稳定溶液，其制备和使用
公开(公告)号：EP0115818B1
公开(公告)日：1986-04-16
申请号：EP84100752.9
申请日：1984-01-21
申请人： BAYER AG
发明人： Raue, Roderich, Dr.
IPC分类号： C09B37/00 , C09B43/11 , C09B41/00 , C09B67/34
CPC分类号： C09B37/00 , C09B11/00 , C09B35/04 , C09B41/009 , C09B43/11 , C09B67/0076 , G01T1/20 , G01T1/202 , G01T3/06 , Y10S8/919 , Y10S534/01

3. 发明公开

EP3107977A1 MATERIALIEN FÜR ORGANISCHE ELEKTROLUMINESZENZVORRICHTUNGEN 有权
公开(公告)号：EP3107977A1
公开(公告)日：2016-12-28
申请号：EP15702630.3
申请日：2015-01-27
申请人： Merck Patent GmbH
发明人： JATSCH, Anja , GROSSMANN, Tobias , PARHAM, Amir Hossain , EBERLE, Thomas , PFLUMM, Christof , KROEBER, Jonas Valentin , STOESSEL, Philipp , MONTENEGRO, Elvira , LINGE, Rouven
IPC分类号： C09K11/06 , H01L51/00 , H01L31/00 , H01L33/00 , H05B33/20 , C07D209/00
CPC分类号： H01L51/0072 , C07D209/94 , C07D209/96 , C07D401/04 , C07D405/04 , C07D405/10 , C07D409/04 , C07D413/04 , C07D413/10 , C07D417/10 , C07D487/10 , C07D491/107 , C07D491/20 , C07D491/22 , C09B11/00 , C09B21/00 , C09B57/00 , C09B57/008 , C09K11/06 , C09K2211/185 , H01L51/0052 , H01L51/0059 , H01L51/0061 , H01L51/0071 , H01L51/0073 , H01L51/0074 , H01L51/5016 , H05B33/20 , Y02E10/549
摘要： The invention relates to compounds which are suitable for use in electronic devices, and electronic devices, in particular organic electroluminescent devices, containing said compounds.

4. 发明公开

EP1817382A2 ALKOXYLATED TRIPHENYLMETHANE DYES 有权
标题翻译：烷氧基化三苯基甲烷染料
公开(公告)号：EP1817382A2
公开(公告)日：2007-08-15
申请号：EP05851880.4
申请日：2005-11-18
申请人： Milliken & Company
发明人： STEPHENS, Eric B. , MOORE, Pat
IPC分类号： C09B69/10 , C09B11/00
CPC分类号： C09B11/12 , C07D405/14 , C08K5/0041 , C09B11/00 , C09B69/103 , C11D3/40
摘要： Colorant compositions are useful for a wide variety of product applications. For example, colorants are used in tinting of polymers, providing colors to aqueous solution(s), and affording color to solid or semi-solid products such as detergents. Disclosed herein are colorant compositions having a triphenylmethane ('TPM') structure having improved stability to alkaline conditions. Thus, the colorant compositions resist decolorization, even at relatively high pH levels.
摘要翻译：着色剂组合物可用于各种产品应用。例如，着色剂用于聚合物着色，为水溶液提供颜色，并为固体或半固体产品如洗涤剂提供颜色。本文公开了具有三苯基甲烷（'TPM'）结构的着色剂组合物，其对碱性条件具有改善的稳定性。因此，即使在较高的pH值下，着色剂组合物也能抵抗脱色。

5. 发明公开

EP3150643A1 TRIPHENYLMETHANE-BASED COLORED COMPOSITION 有权
标题翻译：基于三苯基甲烷的着色组合物
公开(公告)号：EP3150643A1
公开(公告)日：2017-04-05
申请号：EP15799081.3
申请日：2015-05-28
申请人： Wako Pure Chemical Industries, Ltd.
发明人： HORIE, Tomoaki , YANABA, Kosuke , HISHINUMA, Yusuke
IPC分类号： C08F20/02 , C08F220/02 , C09B11/00 , C09B11/20 , C09B67/20 , C09B69/10 , G02B5/20
CPC分类号： C08F220/18 , C08F20/02 , C08F220/02 , C09B11/00 , C09B11/14 , C09B11/18 , C09B11/20 , C09B69/06 , C09B69/10 , C09B69/103 , C09D11/107 , C09D11/30 , C09D133/10 , C09D133/12 , G02B5/20
摘要： Using the colored resin composition using a conventional triarylmethane derivative, heat resistance within a practical range has not been obtained. Therefore, it is an object of the present invention to provide a colored composition having higher heat resistance as compared with the conventional colored composition.
The present invention relates to a compound represented by the following general formula (1), and a polymer having a monomer unit derived from the compound, and the like.

(wherein R 1 to R 4 each independently represent an alkyl group or the like; R 5 to R 7 each independently represent a hydrogen atom or a methyl group; n pieces of R 8 each independently represent a halogen atom, an alkyl group, an aryl group, a hydroxy group, a nitro group, a sulfo group, an alkoxy group, or the like; and n represents an integer of 0 to 4. A 1 represents an alkylene group, or the like; A 2 represents -NH- or -O-. An - represents an anion containing an aryl group having an electron-withdrawing substituent, a sulfonyl group having an electron-withdrawing substituent, or a halogenated alkyl group.)
摘要翻译：使用使用常规三芳基甲烷衍生物的着色树脂组合物，尚未获得实用范围内的耐热性。因此，本发明的目的是提供与常规着色组合物相比具有更高耐热性的着色组合物。本发明涉及下述通式（1）所示的化合物和具有来自该化合物的单体单元的聚合物等。（式中，R 1〜R 4分别独立地表示烷基等; R 5〜R 7分别独立地表示氢原子或甲基; n个R 8分别独立地表示卤素原子，烷基，芳基，羟基硝基，磺基，烷氧基等; n表示0〜4的整数; A 1表示亚烷基等; A 2表示-NH-或-O-; An- 表示含有具有吸电子取代基的芳基，具有吸电子取代基的磺酰基或卤代烷基的阴离子。）

6. 发明授权

EP1817382B1 ALKOXYLATED TRIPHENYLMETHANE DYES 有权
标题翻译：烷基二甲基三苯基甲烷
公开(公告)号：EP1817382B1
公开(公告)日：2009-01-14
申请号：EP05851880.4
申请日：2005-11-18
申请人： Milliken & Company
发明人： STEPHENS, Eric B. , MOORE, Pat
IPC分类号： C09B69/10 , C09B11/00
CPC分类号： C09B11/12 , C07D405/14 , C08K5/0041 , C09B11/00 , C09B69/103 , C11D3/40
摘要： Colorant compositions are useful for a wide variety of product applications. For example, colorants are used in tinting of polymers, providing colors to aqueous solution(s), and affording color to solid or semi-solid products such as detergents. Disclosed herein are colorant compositions having a triphenylmethane ('TPM') structure having improved stability to alkaline conditions. Thus, the colorant compositions resist decolorization, even at relatively high pH levels.

7. 发明公开

EP0853647A1 FLUORINATED XANTHENE DERIVATIVES 失效
标题翻译：氟化呫吨
公开(公告)号：EP0853647A1
公开(公告)日：1998-07-22
申请号：EP97922299.0
申请日：1997-04-11
申请人： Molecular Probes Inc.
发明人： GEE, Kyle, R. , POOT, Martin , KLAUBERT, Dieter, H. , SUN, Wei-Chuan , HAUGLAND, Richard, P. , MAO, Fei
IPC分类号： G01N33 , C07B61 , C07C37 , C07C39 , C07C205 , C07C209 , C07C213 , C07C217 , C07C245 , C07D311 , C07D493 , C07F9 , C07K1 , C07K16 , C09B11 , G01N1 , G01N21
CPC分类号： C09B11/00 , C07C37/055 , C07C41/18 , C07C201/08 , C07C201/12 , C07C205/26 , C07C205/37 , C07C209/10 , C07C213/02 , C07C213/08 , C07C245/20 , C07D311/82 , C09B11/24 , G01N1/30 , Y10S430/116 , Y10S430/126 , C07C39/245 , C07C211/52 , C07C217/84 , C07C215/76 , C07C43/225
摘要： The family of dyes of the invention are fluoresceins and rhodols that are directly substituted on one or more aromatic carbons by fluorine. These fluorine-substituted fluorescent dyes possess greater photostability and have lower sensitivity to pH changes in the physiological range of 6-8 than do non-fluorinated dyes, exhibit less quenching when conjugated to a substance, and possess additional advantages. The dyes of the invention are useful as detectable tracers and for preparing conjugates of organic and inorganic substances.

8. 发明公开

EP0115818A2 Kationische Polyazofarbstoffe, ihre stabilen Lösungen, ihre Herstellung und ihre Verwendung 有权
标题翻译：阳离子染料偶氮，其稳定的解决方案和其制备及其用途。
公开(公告)号：EP0115818A2
公开(公告)日：1984-08-15
申请号：EP84100752.9
申请日：1984-01-21
申请人： BAYER AG
发明人： Raue, Roderich, Dr.
IPC分类号： C09B37/00 , C09B43/11 , C09B41/00 , C09B67/34
CPC分类号： C09B37/00 , C09B11/00 , C09B35/04 , C09B41/009 , C09B43/11 , C09B67/0076 , G01T1/20 , G01T1/202 , G01T3/06 , Y10S8/919 , Y10S534/01
摘要： Kationische Polyazofarbstoffe, die durch Umsetzung von Diaminobenzol-Derivaten der allgemeinen Formel
worin

R für Wasserstoff, C,- bis C 4 -Alkyl, C 1 -bis C 4 -Alkoxy oder Halogen steht,
gegebenenfalls in Mischung mit bis zu 30% aromatischen Monoaminen der Formel
worin
R 2 für Wasserstoff, C 1 - bis C 4 -Alkyl, C,- bis C 4 -Alkoxy, Halogen oder C 1 - bis C 4 -Acylamino und
n für 1 bis 3 stehen,
mit 0,5 bis 0,75 mol eines Salzes oder Esters der salpetrigen Säure pro mol Diamin und anschliessend mit 1 bis 4 mol eines Alkylenoxides der Formel
worin
R 3 für Wasserstoff oder einen gegebenenfalls durch Hydroxy, Alkoxy oder Halogen substituierten C 1 - bis C 4 -Alkylrest steht, erhältlich sind,

werden - bevorzugt in Form ihrer Lösungen -zum Färben von Papier, Leder und anionisch modifizierten Synthesefasern verwendet.
摘要翻译：阳离子多偶氮染料其中R是氢，C1代表由通式1至C 4烷基的二氨基苯衍生物的反应，C1至C4烷氧基或卤素，以混合物与下式的高达30个％的一元胺的芳族任选其中R是氢，C1-C4烷基，C1至C4是烷氧基，卤素，或C1-C4酰氨基，n为1至3，用从0.5至0.75摩尔盐或每摩尔二胺亚硝酸的酯，然后用1的式其中R是氢或由羟基，烷氧基或卤素取代或未取代的烯化氧的反应，如图4所示，C1至C4烷基，买，是 - 优选他们的解决方案的形式使用 - 用于染色纸，皮革和阴离子改性的合成纤维。

9. 发明公开

EP2686684A1 MULTISIGNAL LABELING REAGENTS AND PROCESSES AND USES THEREFOR 审中-公开
标题翻译：多重信号标记试剂和方法和用途
公开(公告)号：EP2686684A1
公开(公告)日：2014-01-22
申请号：EP12709208.8
申请日：2012-02-28
申请人： Enzo Life Sciences, Inc.
发明人： COLEMAN, Jack , RABBANI, Elazar , STAVRIANOPOULOS, Jannis , PANDE, Praveen
IPC分类号： G01N33/58 , C12Q1/68 , C07D219/08 , C09B11/00 , C09B57/02 , G01N33/533
CPC分类号： C07H21/00 , C07D219/08 , C07D405/14 , C07D491/22 , C07H21/04 , C09B11/00 , C09B11/08 , C09B11/24 , C09B57/02 , C12Q1/68 , C12Q1/6818 , G01N33/533 , G01N33/582
摘要： Provided are compounds comprising two DNA supramolecular binding molecules covalently joined by a linker group. Also provided are multisignal labeling reagents comprising (i) an oligomer of nucleotides or nucleotide analogs; (ii) a DNA supramolecular binding molecule noncovalently bound to the oligomer; and (iii) a first reactive group or a first partner of a first binding pair covalently bound to the oligomer. Additionally provided are methods of producing multisignal labeling reagents.

10. 发明授权

EP0853647B2 FLUORINATED XANTHENE DERIVATIVES 失效
标题翻译：氟化呫吨
公开(公告)号：EP0853647B2
公开(公告)日：2011-06-15
申请号：EP97922299.9
申请日：1997-04-11
申请人： Molecular Probes, Inc.
发明人： GEE, Kyle, R. , POOT, Martin , KLAUBERT, Dieter, H. , SUN, Wei-Chuan , HAUGLAND, Richard, P. , MAO, Fei
IPC分类号： C09B11/00 , C09B11/24 , G01N1/30 , C07C209/36 , C07C245/20 , C07C37/00
CPC分类号： C09B11/00 , C07C37/055 , C07C41/18 , C07C201/08 , C07C201/12 , C07C205/26 , C07C205/37 , C07C209/10 , C07C213/02 , C07C213/08 , C07C245/20 , C07D311/82 , C09B11/24 , G01N1/30 , Y10S430/116 , Y10S430/126 , C07C39/245 , C07C211/52 , C07C217/84 , C07C215/76 , C07C43/225
摘要： The family of dyes of the invention are fluoresceins and rhodols that are directly substituted on one or more aromatic carbons by fluorine. These fluorine-substituted fluorescent dyes possess greater photostability and have lower sensitivity to pH changes in the physiological range of 6-8 than do non-fluorinated dyes, exhibit less quenching when conjugated to a substance, and possess additional advantages. The dyes of the invention are useful as detectable tracers and for preparing conjugates of organic and inorganic substances.

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