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    • 4. 发明公开
    • BLENDS OF STYRENE-BUTADIENE COPOLYMERS
    • 苯乙烯 - 丁二烯共聚物的共混物
    • EP3189102A1
    • 2017-07-12
    • EP15759735.2
    • 2015-09-02
    • INEOS Styrolution Group GmbH
    • HAMILTON, MichaelCOCHRAN, Thomas W.NIESSNER, NorbertKNOLL, Konrad
    • C08L53/02
    • C08L53/02C08J5/18C08J2300/206C08J2353/02C08J2425/06C08J2453/02C08L2201/10C08L2203/16C08L2205/025C08L2205/035C08L25/06
    • Polymer blend comprising 95 to 100% of a component A) and 0 to 5% of additives, where A) is consisting of polymers A1) to A4): A1) 50 to 75% of a star shaped block copolymer A1 which comprises at least 2 terminal vinylaromatic hard blocks S and diene soft blocks B, where the proportion of the hard blocks S is from 65 to 90%, and Mn of block S is 35000 to 200000; A2) 5 to 15% of block copolymer A2 which comprises 2 terminal vinylaromatic hard blocks S1 and S2 and random copolymer blocks (B/S) consisting of 20 to 60% vinylaromatic monomers, and 80 to 40% dienes where the proportion of blocks S1 and S2 is 40 to 60%; and Mn of blocks S1 is 35000 to 200000, and Mn of blocks S2 is 5000 to 30000 and the molar S1/S2 ratio is 1:0.5 to 1:10; A3) 3 to 10% of an block copolymer A3 built up from vinylaromatic hard blocks S and from random soft blocks B/S consisting of 60 to 30% vinylaromatic monomers and 40 to 70% dienes, where the diene content is less than 50% and the proportion of the soft phase is at least 60%; and A4) 10 to 35% polystyrene A4; whereby the ratio of A1) to A2) to A3) is from 7 : [1.2 to 1.9] : [0.5 to 12], have particular mechanical properties.
    • 包含95至100%的组分A)和0至5%的添加剂的聚合物共混物,其中A)由聚合物A1)至A4)组成:A1)50至75%的星形嵌段共聚物A1,其至少包含 2个末端乙烯基芳香族硬质嵌段S和二烯烃软质嵌段B,硬质嵌段S的比例为65〜90%,嵌段S的Mn为35000〜200000。 A2)5-15%包含2个末端乙烯基芳族硬嵌段S1和S2的嵌段共聚物A2和由20-60%乙烯基芳族单体组成的无规共聚物嵌段(B / S)和80-40%二烯,其中嵌段S1的比例 S2为40〜60%。 块S1的Mn为35000〜200000,块S2的Mn为5000〜30000,S1 / S2的摩尔比为1:0.5〜1:10, A3)3至10%的由乙烯基芳族硬嵌段S和由60至30%乙烯基芳族单体和40至70%二烯组成的无规软嵌段B / S构建的嵌段共聚物A3,其中二烯含量小于50% 并且软相的比例至少为60%; 和A4)10-35%聚苯乙烯A4; 由此A1)与A2)与A3)之比为7:[1.2至1.9]:[0.5至12],具有特定的机械性能。