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    • 2. 发明公开
    • RESIN MATERIAL AND RESIN FILM
    • HARZMATERIAL UND HARZFOLIE
    • EP3085722A4
    • 2017-08-16
    • EP14872800
    • 2014-12-19
    • ZEON CORP
    • MIYAZAWA SHINSUKE
    • C08G61/08B32B15/085C08F2/44C08J5/18C09J165/00
    • B32B15/08B32B27/20B32B2307/704B32B2439/70B32B2439/80C08G61/08C08G2261/135C08G2261/3325C08G2261/418C08G2261/724C08G2261/76C08J5/18C08J2345/00C08J2365/00C08J2445/00C08J2465/00C08L65/00C08L2205/02C09J165/00
    • The present invention is a resin material comprising a hydrogenated crystalline polar group-containing dicyclopentadiene ring-opening polymer and a hydrogenated crystalline non-polar dicyclopentadiene ring-opening polymer in a weight ratio (hydrogenated crystalline polar group-containing dicyclopentadiene ring-opening polymer:hydrogenated crystalline non-polar dicyclopentadiene ring-opening polymer) of 100:0 to 1:99, the hydrogenated crystalline polar group-containing dicyclopentadiene ring-opening polymer being obtained by melt-mixing a hydrogenated crystalline non-polar dicyclopentadiene ring-opening polymer, a radical initiator, and a polar group-containing compound that includes an ethylenically unsaturated bond, the resin material comprising a structural unit derived from the polar group-containing compound that includes an ethylenically unsaturated bond in a ratio of 0.05 to 3.0 parts by weight based on 100 parts by weight of the hydrogenated crystalline polar group-containing dicyclopentadiene ring-opening polymer and the hydrogenated crystalline non-polar dicyclopentadiene ring-opening polymer in total; and a resin film comprising the resin material; and a laminate film comprising the resin film.
    • 本发明是一种树脂材料,其包含含氢化结晶极性基团的二环戊二烯开环聚合物和氢化结晶非极性二环戊二烯开环聚合物(氢化结晶极性基团的二环戊二烯开环聚合物:氢化 结晶性非极性二环戊二烯开环聚合物)为100:0至1:99,所述含氢化结晶极性基团的二环戊二烯开环聚合物通过熔融混合氢化结晶非极性二环戊二烯开环聚合物, 自由基引发剂和包含烯属不饱和键的含极性基团的化合物,所述树脂材料包含衍生自包含烯属不饱和键的含极性基团的化合物的结构单元,所述结构单元的比例为0.05-3.0重量份,基于 100重量份的含氢化结晶极性基团的二 环戊二烯开环聚合物和氢化结晶非极性双环戊二烯开环聚合物; 和包含该树脂材料的树脂膜; 以及包含该树脂膜的层压膜。
    • 4. 发明公开
    • Glass Fiber Sizing Compositions, Sized Glass Fibers, And Polyolefin Composites
    • 玻璃纤维上浆组合物,大小玻璃纤维和聚烯烃复合材料
    • EP3177577A1
    • 2017-06-14
    • EP15763439.5
    • 2015-08-06
    • PPG Industries Ohio, Inc.
    • DIJT, Jacob CorneliusVAN DER WOUDE, Jacobus Hendricus AntoniusPENNING, John TheoMATUSIAK, Renata Drozdzak
    • C03C25/10C03C25/28C03C25/40C08J5/08
    • C08J5/08C03C25/28C03C25/40C08J2345/00C08J2447/00C08K5/5425C08L83/00C09D147/00
    • The present invention relates to sizing compositions, to glass fibers at least partially coated with such sizing compositions, to a variety of fiber glass products at least partially coated with such sizing compositions, and to composites formed from cycloolefins and reinforced with glass fibers at least partially coated with sizing compositions of the present invention. In one non-limiting embodiment, a sizing composition for glass fibers comprises a film-former comprising a polymer, wherein the repeating unit of the polymer comprises at least four carbon atoms and at least one carbon-carbon double bond, and a silane. A sizing composition for glass fibers, in another non-limiting embodiment, comprises a film-former comprising a polymer, wherein the repeating unit of the polymer comprises four to six carbon atoms and one carbon-carbon double bond, in an amount between about 60 and about 90 weight percent on a total solids basis, and a silane comprising a terminal vinyl group in an amount between about 5 and about 25 weight percent on a total solids basis.
    • 本发明涉及施胶组合物,涉及至少部分地用这种施胶组合物涂布的玻璃纤维,至少部分涂布有这种施胶组合物的各种玻璃纤维产品,以及由环烯烃形成并用玻璃纤维至少部分地增强的复合材料 用本发明的施胶组合物涂布。 在一个非限制性实施方案中,用于玻璃纤维的上浆组合物包含含有聚合物的成膜剂和硅烷,其中聚合物的重复单元包含至少四个碳原子和至少一个碳 - 碳双键。 在另一个非限制性实施方案中,用于玻璃纤维的施胶组合物包含含有聚合物的成膜剂,其中聚合物的重复单元包含4-6个碳原子和一个碳 - 碳双键,用量为约60 和基于全部固体的约90重量%,并且基于全部固体,包含约5至约25重量%的量的末端乙烯基的硅烷。
    • 5. 发明公开
    • METHOD FOR PRODUCING COMPOSITE MOLDED ARTICLE
    • VERFAHREN ZUR HERSTELLUNG EINES ZUSAMMARCHETZTENFORMKÖRPERS
    • EP3088449A1
    • 2016-11-02
    • EP14875625.7
    • 2014-12-17
    • Rimtec Corporation
    • TAKEUCHI, Masaki
    • C08J5/24C08G61/08
    • C08J5/043C08F283/14C08G61/08C08G2261/418C08J5/24C08J2323/18C08J2323/20C08J2345/00C08L65/00
    • The present invention relates to a method for producing a composite molded article having a flexural modulus at 150°C of 25% or more of a flexural modulus at 23°C, including the steps of (1) placing glass fibers in a mold; (2) impregnating glass fibers with a polymerizable composition containing a cycloolefin monomer, a metathesis polymerization catalyst, a radical generator, and a compound represented by the general formula (I); (3) subjecting the above polymerizable composition with which the glass fibers are impregnated to a bulk polymerization to provide a composite molded article; and (4) demolding the composite molded article; and a composite molded article obtained by the above method. According to the method of the present invention, a composite molded article containing glass fibers, the composite molded article having excellent mechanical strength can be produced.
    • 本发明涉及在150℃下的弯曲弹性模量在23℃下的弯曲弹性模量为25%以上的复合成形体的制造方法,包括(1)将玻璃纤维置于模具中的工序; (2)用含有环烯烃单体,易位聚合催化剂,自由基发生剂和由通式(I)表示的化合物的聚合性组合物浸渍玻璃纤维; (3)对浸渍了玻璃纤维的上述聚合性组合物进行本体聚合,得到复合成形品; 和(4)使复合成型体脱模; 和通过上述方法得到的复合成型体。 根据本发明的方法,可以制造含有玻璃纤维的复合成型体,该复合成形体具有优异的机械强度。
    • 6. 发明公开
    • RESIN MATERIAL AND RESIN FILM
    • HARZFTERIAL UND HARZFOLIE
    • EP3085722A1
    • 2016-10-26
    • EP14872800.9
    • 2014-12-19
    • Zeon Corporation
    • MIYAZAWA Shinsuke
    • C08G61/08B32B15/085C08F2/44C08J5/18
    • B32B15/08B32B27/20B32B2307/704B32B2439/70B32B2439/80C08F277/00C08G61/08C08G2261/135C08G2261/3325C08G2261/418C08G2261/724C08G2261/76C08J5/18C08J2345/00C08J2365/00C08J2445/00C08J2465/00C08L65/00C08L2205/02C09J165/00
    • The present invention is a resin material comprising a hydrogenated crystalline polar group-containing dicyclopentadiene ring-opening polymer and a hydrogenated crystalline non-polar dicyclopentadiene ring-opening polymer in a weight ratio (hydrogenated crystalline polar group-containing dicyclopentadiene ring-opening polymer:hydrogenated crystalline non-polar dicyclopentadiene ring-opening polymer) of 100:0 to 1:99, the hydrogenated crystalline polar group-containing dicyclopentadiene ring-opening polymer being obtained by melt-mixing a hydrogenated crystalline non-polar dicyclopentadiene ring-opening polymer, a radical initiator, and a polar group-containing compound that includes an ethylenically unsaturated bond,
      the resin material comprising a structural unit derived from the polar group-containing compound that includes an ethylenically unsaturated bond in a ratio of 0.05 to 3.0 parts by weight based on 100 parts by weight of the hydrogenated crystalline polar group-containing dicyclopentadiene ring-opening polymer and the hydrogenated crystalline non-polar dicyclopentadiene ring-opening polymer in total; and a resin film comprising the resin material; and a laminate film comprising the resin film.
    • 本发明是一种含氢化结晶极性基团的二环戊二烯开环聚合物和氢化结晶非极性二环戊二烯开环聚合物的树脂材料,其重量比(含氢化结晶极性基团的二环戊二烯开环聚合物:氢化 结晶非极性二环戊二烯开环聚合物)为100:0〜1:99,氢化结晶极性基团的二环戊二烯开环聚合物是通过将氢化结晶非极性二环戊二烯开环聚合物, 自由基引发剂和含有烯键式不饱和键的含极性基团的化合物,所述树脂材料包含衍生自含极性基团的化合物的结构单元,所述结构单元包含烯属不饱和键,其比例为0.05-3.0重量份,基于 100重量份的含氢结晶极性基团的二 环戊二烯开环聚合物和氢化结晶非极性二环戊二烯开环聚合物; 以及包含树脂材料的树脂膜; 以及包含树脂膜的层压膜。