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    • 7. 发明公开
    • NOVEL AROMATIC COMPOUND, AND POLYARYLENE COPOLYMER HAVING NITROGEN-CONTAINING HETEROCYCLIC RING CONTAINING SULFONIC ACID GROUP IN SIDE CHAIN
    • NEER AROMATISCHE VERBINDUNG UND POLYARYLENCOPOLYMER MIT STICKSTOFFHALTIGEM HETEROCYCLISCHEM RING MITSULFONSÄUREGRUPPEIN DER SEITENKETTE
    • EP2154173A1
    • 2010-02-17
    • EP08752886.5
    • 2008-05-16
    • JSR Corporation
    • KADOTA, ToshiakiYAMAKAWA, Yoshitaka
    • C08G61/00H01B1/06H01B1/12H01M8/02H01M8/10
    • H01M8/1067C08G61/10C08G61/12C08G65/4006C08G65/4025C08G65/4037C08G65/4056C08G2261/126C08G2261/1452C08G2261/3442C08G2261/35C08G2261/516H01B1/122H01M8/1027H01M8/1032
    • Provided is a solid polymer electrolyte having increased heat resistance and high proton conductivity and a proton conductive membrane composed of the electrolyte. Also provided is a copolymer having a sulfonic acid group. The copolymer includes a repeating unit represented by Formula (1):

      (in the formula, Y denotes at least one kind of structure selected from the group consisting of -CO-, -SO 2 -, -SO-, - CONH-, -COO-, -(CF 2 ) 1 - (1 is an integer of 1 to 10), and - C(CF 3 ) 2 -; W denotes at least one kind of structure selected from the group consisting of a direct bond, -CO-, -SO 2 -, -SO-, -CONH-, -COO-, -(CF 2 ) 1 - (l is an integer of 1 to 10), - C(CF 3 ) 2 -, -O-, and -S-; Z denotes a direct bond or at least one kind of structure selected from the group consisting of - (CH 2 ) 1 - (1 is an integer of 1 to 10), -C(CH 3 ) 2 -, -O-, -S-, - CO-, and -SO 2 -; R 30 denotes a nitrogen-containing aromatic ring having a substituent represented by -SO 3 H, -O(CH 2 ) h SO 3 H, or -O(CF 2 ) h SO 3 H (h is an integer of 1 to 12); p is an integer of 0 to 10; q is an integer of 0 to 10; r is an integer of 1 to 5; and k is an integer of 0 to 4).
    • 提供了具有增加的耐热性和高质子传导性的固体聚合物电解质和由电解质组成的质子传导膜。 还提供了具有磺酸基的共聚物。 共聚物包括由式(1)表示的重复单元:(式中,Y表示选自-CO - , - SO 2 - , - SO - , - CONH - , - COO-, - (CF 2)1 - (1为1〜10的整数)和-C(CF 3)2 - ; W表示选自直链, CO - , - SO 2 - , - SO - , - CONH - , - CO-, - (CF 2)1 - (1为1〜10的整数), - C(CF 3)2 - 和-S-; Z表示直接键或至少一种选自 - (CH 2)1 - (1为1〜10的整数),-C(CH 3)2 - ,-O - , - S - , - CO-和-SO 2 - ; R 30表示具有由-SO 3 H,-O(CH 2)h SO 3 H表示的取代基的含氮芳香环,或 -O(CF 2)h SO 3 H(h为1〜12的整数); p为0〜10的整数,q为0〜10的整数,r为1〜5的整数,k为 是0〜4的整数)。