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1. 发明公开

EP3106472A1 LIVING RADICAL POLYMERIZATION CATALYST, AND POLYMER PRODUCTION METHOD USING SAME 审中-实审
标题翻译：高分子聚合物聚合物
公开(公告)号：EP3106472A1
公开(公告)日：2016-12-21
申请号：EP15748975.8
申请日：2015-02-10
申请人： Kyoto University
发明人： GOTO, Atsushi
IPC分类号： C08F4/40
CPC分类号： C08F4/08 , B01J27/138 , C08F4/04 , C08F112/08 , C08F120/14 , C08F2438/00 , C08F2438/01
摘要： An object of the present invention is to provide a living radical polymerization catalyst that is excellent in terms of safety and cost, and is applicable to various vinyl monomers, and to provide a method for producing a polymer using this living radical polymerization catalyst. The living radical polymerization catalyst contains at least one member selected from the group consisting of alkali metal halide compounds and alkaline earth metal halide compounds.
摘要翻译：本发明的目的是提供一种在安全性和成本方面优异并且可应用于各种乙烯基单体的活性自由基聚合催化剂，并提供使用该活性自由基聚合催化剂制备聚合物的方法。活性自由基聚合催化剂含有选自碱金属卤化物和碱土金属卤化物的至少一种。

2. 发明公开

EP2831128A1 PREPARATION OF FUNCTIONAL POLYMERS USING PHOSPHIDE INITIATORS 有权
标题翻译：制造具有PHOSPHIDINITIATOREN功能高分子学报
公开(公告)号：EP2831128A1
公开(公告)日：2015-02-04
申请号：EP13720627.2
申请日：2013-04-01
申请人： Bridgestone Corporation
发明人： HOGAN, Terrence E. , HERGENROTHER, William L. , ROGGEMAN, David M.
IPC分类号： C08F36/04 , C08F30/02 , C08F4/44 , C08F4/48 , C08F4/609 , C08F4/629 , C08F230/02 , C08F236/04 , C08F4/649
CPC分类号： C08F236/10 , C08F4/08 , C08F4/086 , C08F36/04 , C08F236/04 , C08L9/06
摘要： A method of preparing a polymer, the method comprising: metalating an organophosphine compound in the substantial absence of monomer to form a metalated organophosphine; and introducing the metalated organophosphine to monomer including conjugated diene monomer to form a reactive polymer.

3. 发明公开

EP2123687A4 CONJUGATED DIOLEFIN COPOLYMER RUBBER, METHOD FOR PRODUCING THE SAME, RUBBER COMPOSITION AND TIRE 有权
标题翻译：轮胎和THAT共轭二烯烃共聚橡胶，橡胶制品和合成方法
公开(公告)号：EP2123687A4
公开(公告)日：2010-11-24
申请号：EP08722220
申请日：2008-03-14
申请人： JSR CORP
发明人： TADAKI TOSHIHIRO , SHIBATA MASAHIRO , NAGAOKA TAMOTSU , SONE TAKUO
IPC分类号： C08F297/04 , B60C1/00 , C08K3/36 , C08L9/06 , C08L53/02 , C08L91/00
CPC分类号： C08L15/00 , B60C1/0016 , C08C19/44 , C08F36/04 , C08F297/04 , C08F297/044 , C08L7/00 , C08L19/006 , C08L53/02 , C08F4/08 , C08L2666/02

4. 发明公开

EP2123687A1 CONJUGATED DIOLEFIN COPOLYMER RUBBER, METHOD FOR PRODUCING THE SAME, RUBBER COMPOSITION AND TIRE 有权
标题翻译：轮胎和THAT共轭二烯烃共聚橡胶，橡胶制品和合成方法
公开(公告)号：EP2123687A1
公开(公告)日：2009-11-25
申请号：EP08722220.4
申请日：2008-03-14
申请人： JSR Corporation
发明人： TADAKI, Toshihiro , SHIBATA, Masahiro , NAGAOKA, Tamotsu , SONE, Takuo
IPC分类号： C08F297/04 , B60C1/00 , C08K3/36 , C08L9/06 , C08L53/02 , C08L91/00
CPC分类号： C08L15/00 , B60C1/0016 , C08C19/44 , C08F36/04 , C08F297/04 , C08F297/044 , C08L7/00 , C08L19/006 , C08L53/02 , C08F4/08 , C08L2666/02
摘要： A conjugated diolefin copolymer rubber is produced by copolymerization of a conjugated diolefin and an aromatic vinyl compound and has a primary amino group and an alkoxysilyl group bonded to the copolymer chain. The conjugated diolefin copolymer rubber contains the aromatic vinyl compound in an amount of 5 to 60 wt%. The aromatic vinyl compound is densely distributed in one terminal of the copolymer chain, and is scarcely distributed in the other terminal. The conjugated diolefin copolymer rubber has a temperature difference (ΔTg) of 25°C or more. The conjugated diolefin copolymer rubber has low hysteresis loss properties as well as improved abrasion resistance, rupture characteristics, and road grip characteristics without impairing wet skid characteristics. A method for producing the conjugated diolefin copolymer rubber is also disclosed.
摘要翻译：共轭二烯烃共聚物橡胶是通过在共轭二烯烃和芳香族乙烯基化合物的共聚得到并且具有伯氨基，并在结合到共聚物链烷氧基甲硅烷基。共轭二烯烃共聚物橡胶中含有以5〜60重量％的芳香族乙烯基化合物。作为芳香族乙烯基化合物密集地分布在共聚物链的一个末端，并且几乎不分布在另一端。共轭二烯烃共聚物橡胶具有25℃以上的温度差（“Tg）的。共轭二烯烃共聚物橡胶具有低滞后损失性能，以及改进的耐磨性，断裂特性和抓地力的特性而不损害湿滑特性。因此，一种用于制造共轭二烯烃共聚橡胶的方法是游离缺失盘。

5. 发明授权

EP3705500B1 METHOD FOR MANUFACTURING 2-CYANOETHYL GROUP-CONTAINING POLYMER 审中-实审
公开(公告)号：EP3705500B1
公开(公告)日：2024-05-29
申请号：EP19840417.0
申请日：2019-07-15
IPC分类号： C08F8/30 , C08F16/06 , C08F4/46 , C08F2/38 , C08F2/16 , C08F4/08
CPC分类号： C08F2/38 , C08F8/30 , C08F4/08 , C08F2/16 , Y02E60/10

6. 发明授权

EP1772466B1 Amine functionalized polymer 有权
标题翻译：胺官能化的聚合物
公开(公告)号：EP1772466B1
公开(公告)日：2010-05-05
申请号：EP06255111.4
申请日：2006-10-03
申请人： Bridgestone Corporation
发明人： Yuan-Yong, Yan
IPC分类号： C08F8/32 , C08F8/42 , C08C19/22 , C08C19/44 , C08C19/25 , C08L19/00
CPC分类号： C08L9/06 , C08C19/22 , C08C19/25 , C08C19/44 , C08F2/06 , C08F4/08 , C08F8/30 , C08F8/32 , C08F8/42 , C08F212/08 , C08F236/06 , C08F236/10 , C08K3/013 , C08K3/04 , C08K3/0033 , C08L15/00
摘要： A macromolecule includes a functional group including imine functionality bonded to a polymer chain. Where desired, the functional group also can contain additional (e.g., amine and/or silane) functionality. The material can be provided by reacting a polymer including carbonyl functionality with a compound including a primary amino group. The functional group can interact with particulate filler such as, e.g., carbon black and silica.

7. 发明公开

EP1772466A1 Amine functionalized polymer 有权
标题翻译： Aminfunktionalisierte Polymere
公开(公告)号：EP1772466A1
公开(公告)日：2007-04-11
申请号：EP06255111.4
申请日：2006-10-03
申请人： Bridgestone Corporation
发明人： Yuan-Yong, Yan
IPC分类号： C08F8/32 , C08F8/42 , C08C19/22 , C08C19/44 , C08C19/25 , C08L19/00
CPC分类号： C08L9/06 , C08C19/22 , C08C19/25 , C08C19/44 , C08F2/06 , C08F4/08 , C08F8/30 , C08F8/32 , C08F8/42 , C08F212/08 , C08F236/06 , C08F236/10 , C08K3/013 , C08K3/04 , C08K3/0033 , C08L15/00
摘要： A macromolecule includes a functional group including imine functionality bonded to a polymer chain. Where desired, the functional group also can contain additional (e.g., amine and/or silane) functionality. The material can be provided by reacting a polymer including carbonyl functionality with a compound including a primary amino group. The functional group can interact with particulate filler such as, e.g., carbon black and silica.
摘要翻译：大分子包括键合到聚合物链上的亚胺官能团的官能团。如果需要，官能团还可以含有另外的（例如胺和/或硅烷）官能团。该材料可以通过包括羰基官能团的聚合物与包含伯氨基的化合物反应来提供。官能团可以与颗粒填料例如炭黑和二氧化硅相互作用。

8. 发明公开

EP1199313A2 Diene polymers and copolymers having an alkoxysilane group 失效
标题翻译： Dienpolymere和Diencopolymere mit einer Alkoxysilangruppe
公开(公告)号：EP1199313A2
公开(公告)日：2002-04-24
申请号：EP01130207.2
申请日：1994-12-29
申请人： Bridgestone Corporation
发明人： Shimizu, Takashi
IPC分类号： C08C19/44
CPC分类号： C08L19/006 , C08C19/44 , C08F36/04 , C08F4/48 , C08F4/08
摘要： The present invention provides a process for preparing a conjugated diene/vinyl aromatic hydrocarbon random copolymer or intermediate random copolymer whose vinyl aromatic hydrocarbon units are between random and block distribution, characterized by the steps of:

(a) (co)polymerizing a conjugated diene hydrocarbon monomer and a vinyl aromatic hydrocarbon with an organic lithium initiator without a nitrogen atom, obtaining a conjugated diene/vinyl aromatic hydrocarbon copolymer having a lithium active end; and
(b) adding at least one silane compound selected from an alkoxysilane compound having an epoxy group, an aryloxysilane compound having an epoxy group, an aralkyloxysilane compound having an epoxy group, to the copolymer obtained in step (a).
摘要翻译：本发明提供一种制备共轭二烯/乙烯基芳族烃无规共聚物或中间无规共聚物的方法，其中乙烯基芳烃单元为无规和嵌段分布，其特征在于以下步骤：（a）（共）聚合共轭二烯烃单体和乙烯基芳烃与无氮原子的有机锂引发剂，得到具有锂活性末端的共轭二烯/乙烯基芳族烃共聚物; 和（b）在步骤（a）中得到的共聚物中加入至少一种选自具有环氧基的烷氧基硅烷化合物，具有环氧基的芳氧基硅烷化合物，具有环氧基的芳烷氧基硅烷化合物的硅烷化合物。

9. 发明公开

EP0773231A2 Diene polymers and copolymers having an alkoxysilane group 失效
标题翻译：具有烷氧基硅烷基团的二烯聚合物和共聚物
公开(公告)号：EP0773231A2
公开(公告)日：1997-05-14
申请号：EP97100466.8
申请日：1994-12-29
申请人： Bridgestone Corporation
发明人： Shimizu, Takashi
IPC分类号： C08C19/44
CPC分类号： C08L19/006 , C08C19/44 , C08F36/04 , C08F4/48 , C08F4/08
摘要： A functionalized polymer includes a diene-type polymer having an alkoxysilane group, wherein the functionalized polymer has a molecular structure represented by at least one of the following formula (1), formula (2), and formula (3):
Further, an elastomeric composition is provided which includes a rubber material containing the functionalized polymer, and a filler such as white carbon. The functional polymer and the elastomeric composition exhibit excellent fracture properties, abrasion resistance, and low hysteresis (low rolling resistance and low fuel consumption).
摘要翻译：官能化聚合物包括具有烷氧基硅烷基团的二烯型聚合物，其中官能化聚合物具有由以下式（1），式（2）和式（3）中的至少一个表示的分子结构：此外，弹性体提供包含含有官能化聚合物的橡胶材料和填料例如白炭黑的组合物。功能聚合物和弹性体组合物表现出优异的断裂性能，耐磨性和低滞后性（低滚动阻力和低燃料消耗）。

10. 发明公开

EP3309181A1 CONJUGATED DIENE POLYMER AND METHOD FOR PRODUCTION CONJUGATED DIENE POLYMER 审中-公开
标题翻译：共轭二烯聚合物和生产共轭二烯聚合物的方法
公开(公告)号：EP3309181A1
公开(公告)日：2018-04-18
申请号：EP16807548.9
申请日：2016-06-09
申请人： Zeon Corporation
发明人： SAKURAI, Takuro , NISHIMURA, Saki , IIZUKA, Takashi
IPC分类号： C08C19/25 , B60C1/00 , C08F4/08
CPC分类号： C08F8/42 , B60C1/00 , B60C1/0016 , C08C19/25 , C08F4/08 , C08F236/04 , C08K3/36 , C08L9/00
摘要： A conjugated diene polymer represented by the following formula (1) is provided:

(wherein, in the formula (1), the "polymer" represents a polymer chain containing conjugated diene monomer units, X 1 represents a functional group selected from a hydrocarbyloxy group, halogen group, and hydroxyl group, R 1 represents a substituted or unsubstituted hydrocarbon group, R 2 and R 3 respectively represent a substituted or unsubstituted hydrocarbon group, R 2 and R 3 may bond with each other to form a ring structure together with the nitrogen atom to which they are bound, when forming the ring structure they may form a ring structure together with a hetero atom other than the nitrogen atom to which they are bound in addition to the nitrogen atom to which they are bound, R 4 and R 5 respectively represent a hydrogen atom, alkyl group, cycloalkyl group, aryl group, aralkyl group, a protecting group for amino group, or a group which produces a hydroxyl group when hydrolyzed, R 4 and R 5 may bond with each other to form a ring structure together with the nitrogen atom to which they are bound, when forming the ring structure they may form a ring structure together with a hetero atom other than the nitrogen atom to which they are bound in addition to the nitrogen atom to which they are bound, "n" is an integer of 1 to 3, "m" is an integer of 0 to 2, "p" is an integer of 0 to 2, and n+m+p = 3.)
摘要翻译：（1）表示的共轭二烯聚合物：（式（1）中，“聚合物”表示含有共轭二烯单体单元的聚合物链，X 1表示选自烃氧基，卤素基团和羟基，R 1表示取代或未取代的烃基，R 2和R 3分别表示取代或未取代的烃基，R 2和R 3可以彼此键合以与它们所连接的氮原子一起形成环结构当形成环结构时，它们可以与除它们所键合的氮原子之外的与其结合的氮原子以外的杂原子一起形成环结构，R4和R5分别表示氢原子，烷基环烷基，芳基，芳烷基，氨基的保护基或水解时产生羟基的基团，R 4和R 5可以分别与其它与它们所键合的氮原子一起形成环结构，当形成环结构时，它们可以与除了它们所连接的氮原子以外的杂原子一起形成环结构，除了氮原子之外还与 “n”是1〜3的整数，“m”是0〜2的整数，“p”是0〜2的整数，n + m + p = 3）

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