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    • 9. 发明公开
    • WATERBORNE COATING COMPOSITION
    • 水性涂​​料组合物
    • EP2655450A1
    • 2013-10-30
    • EP12712249.7
    • 2012-03-26
    • Nuplex Resins B.V.
    • AKKERMAN, Jaap, MichielMESTACH, Dirk, Emiel, PaulaPILASZEK, Wincenty, Lambertus, StanislawADOLPHS, Rob
    • C08F220/06C08F220/26C08L33/02C08L33/14C09D133/02C09D133/14C08F2/24C08F2/38C09D5/02C09D175/14C08F220/28C08F265/06C09D167/08
    • C09D133/12C08F220/18C08F220/28C08F283/002C08G18/0823C08G18/348C08G18/6254C08G18/69C08G18/755C09D133/14C09D151/08C09D175/14C08L67/08C08F220/00C08F2220/1825C08F220/14C08F2220/286C08F220/06C08F2220/283C08L75/14C08L33/14C08L33/08
    • The invention relates to an aqueous dispersion for use as open time improver in a coating composition which aqueous polymer dispersion comprises a first polymer having a number average molecular weight (Mn) of from 2,000 to 120,000 (determined by gel permeation chromatography using a mixture of tetrahydrofurane and acetic acid as eluent), an acid value of from 30 to 150 mg KOH/g, and an ethylene-oxide wt % (on total solid polymer) of from 1 to 20 wt %, said first polymer dispersion being obtainable by free radical polymerization of a monomer mixture in the presence of at least one free-radical initiator and at least one surfactant, said monomer mixture comprising : a) 5 to 20 wt %, preferably 7 to 10 wt %, acid functional ethylenically unsaturated monomers or precursors thereof or ethylenically unsaturated monomers comprising ionic group precursors; b) 5 to 25 wt %, preferably 7 to 20 wt %, ethylenically unsaturated monomers containing polyethylene oxide, polyethylene glycol or mono-alkoxypolyethylene glycol moeity c) up to 90 wt % of non-ionic ethylenically unsaturated monomers other than a) or b); d) 0 to 10 wt % ethylenically unsaturated monomers with a functional group for cross-linking e) 0 to 10 wt % of chain transfer agents; f) up to 90 wt % non-ionic ethylenically unsaturated monomers other than c), wherein 30 to 90 wt %, more preferably 60 to 80 wt % comprise crosslinkable groups or precursors thereof; wherein the sum of a) through f) is 100 wt %. The invention further relates to a method for making the first polymer dispersion, the use of said aqueous dispersion as an open time improver in a coating composition, to aqueous coating compositions comprising a blend of at least a first aqueous polymer dispersion and a second aqueous polymer dispersion comprising a film-forming second polymer and to a method for making said coating composition.
    • 本发明涉及一种在涂料组合物中用作开放时间改进剂的水分散体,该聚合物水分散体包含数均分子量(Mn)为2,000至120,000的第一聚合物(通过凝胶渗透色谱法使用四氢呋喃 和乙酸作为洗脱剂),30-150mg KOH / g的酸值和1-20wt%的环氧乙烷重量%(在全部固体聚合物上),所述第一聚合物分散体可通过自由基 在至少一种自由基引发剂和至少一种表面活性剂存在下聚合单体混合物,所述单体混合物包含:a)5-20wt%,优选7-10wt%的酸官能的烯属不饱和单体或其前体,或 包含离子基团前体的烯键式不饱和单体; b)5至25重量%,优选7至20重量%的含聚环氧乙烷,聚乙二醇或单烷氧基聚乙二醇部分的烯属不饱和单体c)至多90重量%的除a)或b)之外的非离子烯键式不饱和单体 ); d)0-10wt%具有用于交联的官能团的烯属不饱和单体,e)0-10wt%链转移剂, f)除c)以外的至多90重量%的非离子烯键式不饱和单体,其中30-90重量%,更优选60-80重量%包含可交联基团或其前体; 其中a)至f)的总和为100重量%。 本发明还涉及制备第一聚合物分散体的方法,所述水分散体作为涂料组合物中的开放时间改进剂的用途,涉及包含至少第一聚合物水分散体和第二聚合物水分散体的共混物的水性涂料组合物 包含成膜第二聚合物的分散体以及制备所述涂料组合物的方法。