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    • 4. 发明公开
    • TRANSPARENT LAMINATE
    • 透明薄膜
    • EP3176613A1
    • 2017-06-07
    • EP15827016.5
    • 2015-07-09
    • Dexerials Corporation
    • KAKINUMA, MasayasuTAKENOUCHI, MasakiOHTA, EijiKAWAMURA, SatoshiOGAWA, Maki
    • G02B1/118A61F9/02B32B3/30B32B27/30C08F2/46
    • A61F9/029A41D13/1184A61F9/02B32B3/30B32B27/30C08F2/46C08J3/24C08J7/047C08J2369/00C08J2433/06G02B1/118G02B1/18G02B27/0006
    • A transparent laminate including: transparent substrate; and structure layer which contains protrusion portions, depression portions, or both on a surface thereof, average distance between the protrusion portions adjacent or the depression portions adjacent being equal to or less than wavelength of visible light; the structure layer including polymerized product of active-energy-ray-curable resin composition including composition of (meth)acrylate-based-polymerizable compound; the composition including at least any of the following (A) and (B), and the following (C) and (D):
      (A) ester (meth)acrylate of trihydric alcohol having main and side chain each including alkyl chain;
      (B) ester di(meth)acrylate of ethylene-oxide-modified bisphenol A;
      (C) polyalkylene glycol di(meth)acrylate; and
      (D) ester di(meth)acrylate of dihydric alcohol having main chain including linear alkyl chain;
      water contact angle on the surface of the structure layer being 26° or more and 74° or less; and
      storage elastic modulus at 180°C of the structure layer being less than 0.5 GPa.
    • 透明层压体,包括:透明基材; 在其表面上包含突起部分,凹陷部分或两者的结构层,相邻的突出部分或相邻的凹陷部分之间的平均距离等于或小于可见光的波长; 所述结构层包括包含(甲基)丙烯酸酯基聚合性化合物的组合物的活性能量射线固化型树脂组合物的聚合物; 所述组合物包含以下(A)和(B)中的至少任一个,以及(C)和(D):(A)具有主链和侧链的三元醇的(甲基)丙烯酸酯各自包括烷基链; (B)环氧乙烷改性双酚A的二(甲基)丙烯酸酯; (C)聚亚烷基二醇二(甲基)丙烯酸酯; 和(D)具有主链包括直链烷基链的二元醇的二(甲基)丙烯酸酯; 结构层表面的水接触角为26°以上且74°以下; 并且结构层的180℃下的储能弹性模量小于0.5GPa。