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    • 9. 发明公开
    • PROCESS TO PREPARE CROSSLINKED CELLULOSE ETHERS, CROSSLINKED CELLULOSE ETHERS OBTAINABLE BY SUCH PROCESS AND THE USE THEREOF
    • 工艺生产交联纤维素醚,交联纤维素从这个过程及其用途
    • EP2268674A1
    • 2011-01-05
    • EP09732662.3
    • 2009-04-10
    • Akzo Nobel N.V.
    • DE WIT, Paulus Pieter
    • C08B15/00C08B5/00
    • C08B15/005C08B5/00
    • The invention relates to a dry or slurry process to prepare phosphate-crosslinked cellulose ethers from a cellulose starting material comprising the steps of adding an alkalizing agent to the cellulose starting material to achieve mercerization, adding an etherifying agent to the reaction mixture to achieve etherification of the cellulose, and adding a crosslinking agent to the reaction mixture to achieve crosslinking of the cellulose, wherein at least part of the alkalizing agent is added to the cellulose starting material before the etherification and/or crosslinking reactions take place to obtain alkalized cellulose; the crosslinking agent and the etherifying agent are added one after the other in random order or simultaneously; the crosslinking agent is an alkali metal thmetaphosphate; and the crosslinking and etherification steps are performed at an elevated temperature. Additionally, the invention relates to crosslinked cellulose ethers obtainable by the above process having a viscosity and/or water absorption capacity higher than their non-crosslinked equivalents and the use thereof.
    • 本发明涉及干法或淤浆法,以制备由纤维素磷酸盐交联的纤维素醚起始原料包括向碱化剂对纤维素原料,以实现丝光的步骤,增加了醚化剂到反应混合物中,以实现的醚化 纤维素,和添加交联剂到反应混合物中,以实现纤维素的交联,worin至少碱化剂的一部分被添加到所述纤维素醚化之前起始材料和/或交联反应发生,得到碱化的纤维素; 交联剂和醚化剂加入一个在另一个随机顺序或同时之后; 该交联剂是一种碱金属thmetaphosphate; 和交联化和醚化步骤是在在升高的温度下进行。 另外,本发明通过具有粘性和/或水吸收能力比它们的非交联的等同更高和其使用上述过程涉及交联的纤维素醚可获得的。